In the past, chemists have used temperature, pressure, light, and other chemical ways to speed up or slow down chemical reactions. Now, researchers at the University of Rochester have developed a theory that explains a different way to control chemical reactions—one that doesn’t rely on heat or light but instead on the quantum environment surrounding the molecules.

In a paper published in the Journal of the American Chemical Society, the researchers—including Frank Huo, the Dean and Laura Marvin Endowed Professor in Physical Chemistry in Rochester’s Department of Chemistry and graduate students Sebastian Montillo and Wenxiang Ying—argue that traditional theories used to predict how fast chemical reactions occur may not fully capture what happens under certain quantum light-matter interaction conditions.

To address this, they developed a new theory showing how quantum effects —specifically, an effect called vibrational strong coupling (VSC)—can influence chemical reactions.

With a suite of reimagined instruments at SLAC’s LCLS facility, researchers see massive improvement in data quality and take up scientific inquiries that were out of reach just one year ago.

Some of science’s biggest mysteries unfold at the smallest scales. Researchers investigating super small phenomena—from the quantum nature of superconductivity to the mechanics that drive photosynthesis—come to the Department of Energy’s SLAC National Accelerator Laboratory to use the Linac Coherent Light Source (LCLS).

Like a giant microscope, LCLS sends pulses of ultrabright X-rays to a suite of specialized scientific instruments. With these tools, scientists take crisp pictures of atomic motions, watch chemical reactions unfold, probe the properties of materials and explore fundamental processes in living things.