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Computationally accelerated organic synthesis: Optimal ligand prediction for generating reactive alkyl ketone radicals

Because ketones are widespread in organic molecules, chemists are eager to develop new reactions that use them to form chemical bonds. One challenging reaction is the one-electron reduction of ketones to generate ketyl radicals.

Ketyl radicals are reactive intermediates used in natural product synthesis and pharmaceutical chemistry; however, most methodologies are optimized for aryl while simple alkyl ketones remain challenging for chemists. Alkyl ketones are considerably more abundant but intrinsically more difficult to reduce than aryl ketones.

To this end, a team of specialized organic chemists and computational chemists from WPI-ICReDD at Hokkaido University has developed a new catalytic method for generating alkyl ketyl radicals.

Chronic traumatic encephalopathy caused by more than just head trauma, study finds

Chronic traumatic encephalopathy (CTE)—most often found in athletes playing contact sports—is known to share similarities with Alzheimer’s disease (AD), namely the buildup of a protein called tau in the brain.

New research published in Science finds even more commonalities between the two at the genetic level, showing CTE (like AD) is linked to damage to the genome and not just caused by repeated head impact (RHI).

The research team, a collaboration between Boston Children’s Hospital, Mass General Brigham, and Boston University, used single-cell genomic sequencing to identify somatic genetic mutations (changes in DNA that occur after conception and are not hereditary).

Scientists create new type of semiconductor that holds superconducting promise

Scientists have long sought to make semiconductors—vital components in computer chips and solar cells—that are also superconducting, thereby enhancing their speed and energy efficiency and enabling new quantum technologies. However, achieving superconductivity in semiconductor materials such as silicon and germanium has proved challenging due to difficulty in maintaining an optimal atomic structure with the desired conduction behavior.

In a paper published in the journal Nature Nanotechnology, an international team of scientists reports producing a form of that is superconducting—able to conduct electricity with , which allows currents to flow indefinitely without , resulting in greater operational speed that requires less energy.

“Establishing superconductivity in germanium, which is already widely used in computer chips and , can potentially revolutionize scores of consumer products and industrial technologies,” says New York University physicist Javad Shabani, director of NYU’s Center of Quantum Information Physics and the university’s newly established Quantum Institute, one of the paper’s authors.

‘Singing’ electrons synchronize in Kagome crystals, revealing geometry-driven quantum coherence

Physicists at the Max Planck Institute for the Structure and Dynamics of Matter (MPSD) in Hamburg have discovered a striking new form of quantum behavior. In star-shaped Kagome crystals—named after a traditional Japanese bamboo-basket woven pattern—electrons that usually act like a noisy crowd suddenly synchronize, forming a collective “song” that evolves with the crystal’s shape. The study, published in Nature, reveals that geometry itself can tune quantum coherence, opening new possibilities to develop materials where form defines function.

Quantum coherence—the ability of particles to move in synchrony like overlapping waves—is usually limited to exotic states such as superconductivity, where pair up and flow coherently. In ordinary metals, collisions quickly destroy such coherence.

But in the Kagome metal CsV₃Sb₅, after sculpting tiny crystalline pillars just a few micrometers across and applying magnetic fields, the MPSD team observed Aharonov–Bohm-like oscillations in electrical resistance. Thus showing that electrons were interfering collectively, remaining coherent far beyond what single-particle physics would allow.

A new dimension for spin qubits in diamond

The path toward realizing practical quantum technologies begins with understanding the fundamental physics that govern quantum behavior—and how those phenomena can be harnessed in real materials.

In the lab of Ania Jayich, Bruker Endowed Chair in Science and Engineering, Elings Chair in Quantum Science, and co-director of UC Santa Barbara’s National Science Foundation Quantum Foundry, that material of choice is laboratory-grown diamond.

Working at the intersection of materials science and quantum physics, Jayich and her team explore how engineered defects in diamond—known as spin qubits—can be used for quantum sensing. Among the lab’s standout researchers, Lillian Hughes, who recently earned her Ph.D. and will soon begin postdoctoral work at the California Institute of Technology, has achieved a major advance in this effort.

Spectral shaper sculpts 10,000 laser comb lines for exoplanet detection and beyond

Researchers have developed a new technology that can shape the spectrum of light emitted from a laser frequency comb across the visible and near-infrared wavelengths with more precision than previously possible. This advance could provide an important new tool in the hunt for Earth-like planets outside our solar system.

When searching for exoplanets, astronomers use high-precision spectroscopy to detect tiny shifts in starlight that reveal a star’s subtle “wobble” due to an orbiting planet. But for Earth-sized planets, these wavelength changes are smaller than the spectrograph’s natural instabilities, so laser frequency combs—lasers that emit thousands of evenly spaced —are needed to provide a reference, acting like precise wavelength rulers.

“For astronomers, the big prize would be to find a planet with a mass similar to Earth and orbiting a star similar to our sun,” said research team leader Derryck T. Reid, from Heriot-Watt University in the U.K. “Our spectral shaper can make the lines on a more uniform, which allows the spectrograph to detect smaller stellar motions, such as those from Earth-like planets, that would otherwise be hidden in the noise.”

Research confirms Meissner effect in high-pressure nickelate superconductor

A research team led by Prof. Liu Xiaodi from the Hefei Institute of Physical Science of the Chinese Academy of Sciences, together with researchers from Jilin University and Sun Yat-sen University, has achieved simultaneous detection of zero electrical resistance and the Meissner effect in lanthanum nickelate (La3Ni2O7−δ) single crystals under high pressure.

The researchers combined diamond nitrogen-vacancy (NV) center quantum sensing with electronic transport measurements to provide unambiguous evidence of high-temperature superconductivity in this nickelate system. The results are published in Physical Review Letters.

Superconductivity in La3Ni2O7−δ was first reported in 2023 through transport measurements, which revealed zero resistance around 80 K. However, confirming superconductivity requires detecting diamagnetism, or the expulsion of magnetic fields—the Meissner effect—which had remained elusive due to associated with high-pressure environments and small superconducting volume fractions.

Creepy Science That’s Changing the World in Surprising Ways

From mini-brains and spider-inspired gloves to edible wolf apple coatings and microplastic-filled retinas, scientists are transforming creepy concepts into life-improving innovations. Lab-grown brain organoids could replace animal testing, web-slinging gloves can spin instant wound dressings, and wolf apple starch may keep veggies fresh longer. Meanwhile, the discovery of microplastics in human eyes reveals a haunting truth about our environment’s reach inside us.

Lab-Grown “Mini-Brains” Offer New Insight into the Human Mind

Scientists writing in ACS Sensors have successfully grown a small brain organoid in a petri dish, creating a powerful new tool for studying how nerve cells interact without the use of animal testing. Over two years, human nerve cells multiplied and organized themselves into a three-dimensional “mini-brain” that displayed electrical activity similar to real brain tissue. Researchers say this breakthrough could help scientists better understand how the human brain communicates and functions—or, as they joke, provide “a lab-grown lunch option for zombies.”

The Sun’s Fiery Secret Waves Discovered After 80 Years of Searching

Scientists have finally observed long-sought twisting magnetic waves, known as torsional Alfvén waves, in the Sun’s corona—ending an eight-decade search that began in the 1940s.

Using the powerful Daniel K. Inouye Solar Telescope in Hawaii, researchers captured the first direct evidence of these small, constant waves, which may be responsible for heating the Sun’s outer atmosphere to millions of degrees.

Hidden Solar Magnetic Waves Revealed

Corollary Discharge Dysfunction to Inner Speech and its Relationship to Auditory Verbal Hallucinations in Patients with Schizophrenia Spectrum Disorders

Auditory-verbal hallucinations (AVH)—the experience of hearing voices in the absence of auditory stimulation—are a cardinal psychotic feature of schizophrenia-spectrum disorders. It has long been suggested that some AVH may reflect the misperception of inner speech as external voices due to a failure of corollary-discharge-related mechanisms. We aimed to test this hypothesis with an electrophysiological marker of inner speech.

Study Design.

Participants produced an inner syllable at a precisely specified time, when an audible syllable was concurrently presented. The inner syllable either matched or mismatched the content of the audible syllable. In the passive condition, participants did not produce an inner syllable. We compared the amplitude of the N1, P2, and P3-components of the auditory-evoked potential between: schizophrenia-spectrum patients with current AVH (SZAVH+, n = 55), schizophrenia-spectrum patients without current AVH (SZAVH−, n = 44), healthy controls (HC, n = 43).

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