Since the 1980s, researchers have sought to use laser light to control chemical reactions relevant to photochemistry, catalysis and light-responsive materials. But this technique, known as coherent control, has a blind spot: There has been no way to directly see the molecules in these reactions as their structures rearrange.
Now, researchers at the Department of Energy’s SLAC National Accelerator Laboratory have imaged a coherently controlled chemical reaction for the first time. Their work, published in Physical Review A, uses ultrafast X-rays from the Linac Coherent Light Source (LCLS) to show in real time how atoms move in a molecule that was excited and manipulated with laser light.
“There are many challenges with controlling chemical reactions, but seeing is believing,” said study lead author Tom Hopper, assistant professor at the University of Central Florida who was a postdoctoral researcher at SLAC at the time of the study. “If you can see something directly, it opens up a new level of control.”






