An HZDR research team has developed methods for breaking down “forever chemicals.”
The carbon-fluorine bonds inside PFAS are among the strongest in chemistry, allowing these industrial pollutants to persist in water for years. Researchers at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR) are testing two ways to break those bonds: hydrodynamic cavitation and cold atmospheric plasma combined with gas dispersion.
Analyses by experts at the Helmholtz Centre for Environmental Research (UFZ) confirmed that both processes degraded per-and polyfluoroalkyl substances (PFAS) and released fluoride. If developed into practical industrial systems, the methods could help limit the amount of these highly persistent chemicals entering rivers, lakes and oceans.
If scientists could find a material that acts as a superconductor—that is, one that transmits energy with zero resistance—at normal pressures and relatively high temperatures, it would open up a vast number of possibilities. These include medical imaging, quantum computing and numerous other fields. So, yes, it would be a big deal.
“Right now, almost 50% of the energy in transmission is just heat in copper wires,” said Shomeek Mukhopadhyay. “If you can transmit electricity through wires without dissipating energy, that’s a huge economic benefit. I would say it’s equivalent to having thermonuclear fusion.”
Mukhopadhyay, a research scientist in Chemical & Environmental Engineering, is on the third floor of the Kline Geology Laboratory. Nearby, Natalia Nevskaya, a postdoctoral associate in Earth & Planetary Sciences, prepares a massive device called the Kawai multi-anvil press.
Fluorescent dyes have long been used in biological research to identify and visualize structures within living cells. Although effective, they have several drawbacks, including altering the cells under study, limiting the number of structures that can be examined at once and reducing measurement accuracy.
A team led by University at Buffalo researchers has developed a new method that draws on advances in artificial intelligence and Raman spectroscopy to overcome the limitations of dye-based imaging.
The approach combines AI with “Ramanomics,” a UB-pioneered optical technology that measures the biochemical makeup of cells without altering them. Rather than relying on fluorescent labels, which are dyes that bind to specific cellular components and glow under specialized lighting, it identifies cellular structures by their unique biochemical signatures.
All chemistry starts with a push from electrons. In the early moments of a chemical reaction, it’s the movement of electrons that initiates the breaking of old chemical bonds and forging of new ones, transforming one molecule into another.
When an electron is removed from a molecule faster than the molecule can react—called “impulsive ionization”—the other electrons in the molecule enter excited quantum states that evolve on ultrafast timescales. Scientists have long sought to map the ultrasmall, ultrafast electronic motions behind chemical reactions on their natural timescales.
Now, researchers at the Department of Energy’s SLAC National Accelerator Laboratory have created a movie of early electron motion in an impulsively excited molecule. Each frame captures changes happening in mere attoseconds, just billionths of a billionth of a second.
et al. used an innovative series of screening and directed evolution steps to produce a new enzyme (CMLase) which can remove a pernicious form of advanced glycation end product (AGE) linkage from proteins. AGEs contribute to biological aging, so CMLase may possess therapeutic potential to combat parts of the aging process.
Advanced glycation end products (AGEs) in proteins, a hallmark of aging, are considered irreversible. Here, authors report the development of CMLase — an enzyme that specifically oxidizes Nε-carboxymethyl-lysine (CML) and restores the native lysine residues in vitro and in human tissue samples.
Scientists from Rice University in the U.S. have developed a way to precisely tune the temperature inside a trapped-ion simulator. The breakthrough means they will be able to run quantum simulations at precise temperatures that better reflect real-world conditions.
Trapped-ion simulators are quantum devices that isolate charged particles inside a sealed vacuum chamber, using electric fields to hold them in place. They mimic and study complex quantum systems, such as chemical reactions or exotic materials, that are too difficult for ordinary computers to calculate.
Temperatures inside these devices are typically kept as close as possible to absolute zero so that thermal motion does not disrupt calculations or cause errors. But researchers lacked a suitable way to set the temperature without accidentally changing how fast the system loses energy. This meant that studies were mostly stuck using absolute zero or uncontrolled high temperatures.
One of the most famous and intriguing results of quantum mechanics is the finding that fundamental particles, such as electrons, cannot be pinned down to one single location. Instead, a particle is described by its “wavefunction,” which allows researchers to derive probability distributions—a sort of mathematical map that shows the possibilities—of fundamental properties such as its position and momentum. In particular, the electron wavefunctions within a molecule, known as “molecular orbitals,” carry information about how the molecule interacts with its surroundings. For example, they show how it may absorb light or how a chemical reaction might take place.
As a consequence, knowledge of the complete three-dimensional wavefunction is highly desirable, but imaging the wavefunction has proven to be a major experimental challenge. An interdisciplinary research team at the University of Göttingen has now managed to image the three-dimensional wavefunction of a nanometer-sized organic molecule. They overcame the limitations by combining state-of-the-art photoelectron spectroscopy with powerful mathematical algorithms. The results are published in Nature Communications.