An experiment with a charged molecule of bismuth and carbon reveals how effects from Albert Einstein’s special relativity reshape the standard understanding of chemical bonds
Category: chemistry – Page 25
Discovery helps explain why solid-state batteries often fail
Exactly how those dendrites form is still up for debate. While the interface between the battery’s electrolyte and electrodes has been the focus of most research, another culprit is the boundary where two grains of electrolyte in a solid material meet. Researchers know these boundaries can seed dendrites within electrolytes, although the effects have been difficult to study.
Now researchers at MIT and the Technical University of Munich have uncovered why such boundaries can lead to dendrites: Hidden electrical imbalances across the boundaries affect how the electrolyte conducts electrical charges, which influences how the ions and electrons move through the material during battery operation. In a paper published today in Nature Nanotechnology, the researchers characterized the electrical and chemical behavior of the boundaries and showed that adjusting how the electrolyte is processed enhances the movement of ions while reducing electron leakage. This adjustment can increase critical current density by more than 300 percent, which could enable solid-state batteries that charge faster and last longer.
Light-powered chip harvests energy, computes and senses chemicals in one stack
Most contemporary portable electronics, including laptops, smartphones and smart watches, are powered by batteries that need to be recharged daily or every few days. Over the past decade, however, some engineers have been exploring the possibility of developing battery-free electronic devices that autonomously derive electricity from renewable sources, such as sunlight, indoor lighting or heat.
A research team at Penn State University recently developed a compact integrated circuit (IC) that harvests energy solely from ambient light, using this energy to run computations and sense chemicals in its surroundings. This new chip, introduced in a paper published in Nature Electronics, could enable the development of devices that never require charging and thus continue working uninterrupted even in environments where replacement batteries and electrical sockets are not available.
“This work grew out of a broader question we have been asking in my group: Can we build electronic systems that do not simply sense information, but also process that information locally and power themselves from their environment?” Saptarshi Das, senior author of the paper, told Tech Xplore. “Many future Internet of Things (IoT) and edge-computing systems will need to operate in remote or hard-to-access locations, where replacing batteries is impractical. We wanted to demonstrate a compact, fully integrated chip that combines energy harvesting, sensing and computation in a single monolithic three-dimensional architecture.”
A Tiny Chemical Trick Could Lead to Much More Powerful Computer Chips
A new plasma chemistry breakthrough could help manufacturers build the next generation of smaller, faster, and more powerful computer chips.
Baseline tool could separate alien life signals from geology on ocean worlds
When it comes to the search for life elsewhere in the universe, methane and other chemical compounds are seen as signs of biology because they are often produced by living microbes. However, scientists can be misled because certain geological processes can produce chemical signatures identical to those of living organisms.
To help identify true biological signals and reduce the risk of false detections, researchers have developed a framework that models what a planet’s chemistry looks like without life.
Their research is published in the journal Nature Astronomy.
Saturn-ring-like laser emission from chiral polymeric microspheres
Controlling light within microscopic spaces is crucial for next-generation optical devices such as photonic integrated circuits and localized sensors. Microspheres formed of luminescent π-conjugated polymers act as optical resonators that confine and amplify light via whispering gallery modes (WGMs), and they are promising candidates for microscale organic lasers and photonic applications. However, conventional microsphere resonators are geometrically isotropic and emit isotropic light, making directional control of emissions challenging.
In a new study published in the Journal of the American Chemical Society, researchers from the University of Tsukuba show that microspheres formed through the self-assembly of chiral π-conjugated polymers possess a characteristic twisted bipolar molecular configuration, enabling angle-selective optical resonance and laser oscillation with distinct azimuthal directionality. Using polarization-dependent photoluminescence imaging, the research team directly visualized a vortex-like (swirling) arrangement formed by the polymer main chains on the spherical surface.
Furthermore, this vortex-like surface molecular orientation induces an azimuth-dependent refractive-index distribution along the light propagation path, resulting in angle-dependent WGM resonance wavelengths and spatially localized emission. Consequently, the microspheres exhibit directional laser oscillation, preferentially emitting amplified light along a specific azimuthal direction. The resulting emission pattern is analogous to Saturn’s rings.
Quantum computers model nine fusion fuel material configurations for first time
A team of scientists from Oak Ridge National Laboratory, Cleveland Clinic and IBM has calculated nine molecular configurations of a promising material to produce fuel for fusion energy—the first known instance of such computations on quantum computers.
Such calculations, demonstrated in a new paper published on the arXiv preprint server, are computationally challenging for classical computers to scale when working alone. They are a fundamental step toward optimizing the production and extraction of tritium—an extremely rare material in nature that is necessary to produce fusion energy with most of the proposed machines. Ensuring adequate supplies of tritium has long been a barrier to realizing the promise of clean, abundant energy from fusion power plants, and solving this issue is a key objective of the U.S. Department of Energy’s Genesis Mission.
Quantum computers are well-suited to computing the atomic-level chemistry of a liquid salt that contains fluorine, lithium and beryllium (FLiBe), one of the leading candidate materials for extracting tritium fuel in fusion reactors. To compute different configurations of clusters of FLiBe, the team used the same quantum-centric supercomputing techniques now being applied to 12,635-atom protein simulations with Cleveland Clinic. These methods can calculate the quantum behavior of electrons in complex materials, complementing and enhancing the capabilities of classical supercomputers and algorithms.
Quantum vacuum could help break molecular bonds with less energy, simulations suggest
A team of researchers led by Felipe Herrera, a professor at the University of Santiago and a researcher at the Millennium Institute for Research in Optics (MIRO), has identified a quantum phenomenon that enables chemical bonds to be broken using significantly less energy than is normally required.
The findings, published in Physical Review Letters under the title “Enhancing Infrared-Laser Dissociation of Molecules with the Electromagnetic Vacuum,” demonstrate that by using infrared light, the natural fluctuations present in the electromagnetic vacuum can promote molecular dissociation when molecules are confined within specially designed nanometer-scale structures known as nanocavities.
Although we often think of a vacuum as completely empty space, quantum physics shows that it is filled with tiny energy fluctuations. The researchers discovered that these fluctuations can be amplified inside a nanocavity, altering molecular vibrations and making it easier for an infrared laser to break chemical bonds.
New biobased polymers exhibit excellent tensile properties beyond polyolefins
The research group of Professor Kotohiro Nomura, Tokyo Metropolitan University, in cooperation with the research groups of Senior Researcher Hiroshi Hirano and Director Seiji Higashi of the Osaka Research Institute of Industrial Science and Technology, and Associate Professor Hiroki Takeshita of The University of Shiga Prefecture, has developed biobased poly(ester amide)s from inedible biorenewables that can be easily chemically recycled and exhibit better mechanical (tensile) properties in film than commodity plastics.
The work has been published in JACS Au.
The development of biobased polymers that are readily chemically recyclable and derived from nonedible renewable resources has been recognized as a promising sustainable material in the circular economy. However, there have been few examples of materials with mechanical properties (e.g. tensile strength and elongation at break) that exceed those of conventional polymers such as polyethylene and polypropylene.