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Category: chemistry – Page 16

New method for making graphene turns defects into improvements

Recent research has found a new way to make graphene that adds structural defects to improve the performance of the material that could have benefits across a range of applications—from sensors and batteries, to electronics.

Scientists from the University of Nottingham’s School of Chemistry, University of Warwick and Diamond Light Source developed a single-step process to grow -like films using a molecule, Azupyrene, whose shape mimics that of the desired defect. The research has been published today in Chemical Science.

David Duncan, Associate Professor at the University of Nottingham and one of the study’s lead authors, explains, “Our study explores a new way to make graphene, this super-thin, super-strong material is made of carbon atoms, and while perfect graphene is remarkable, it is sometimes too perfect. It interacts weakly with other materials and lacks crucial electronic properties required in the semiconductor industry.”

18-member Nanoring Pushes The Boundaries of Global Aromaticity

Pushing the limits of size constraints in chemistry, an 8-nanometer 18-porphyrin nanoring (c-P18) becomes the largest known cyclic molecule to exhibit detectable global aromaticity. This phenomenon, where π-electrons are delocalized not just over individual aromatic units but around the entire macrocyclic ring, is mostly seen in smaller aromatic molecules but rarely found in macrocyclic entities.

Researchers from the University of Oxford and the University of Nottingham confirm that the c-P18 nanoring carries a circuit of 242 π-electrons, setting the current upper size limit for global aromaticity in butadiyne-linked systems. Using highly sensitive Fluorine-19 NMR spectroscopy, they tracked ring currents while charging the nanoring via oxidation.

The experiments uncovered faint magnetic shoulder signals—the telltale signature of electrons flowing globally between aromatic and antiaromatic states. This pushes beyond the benchmark set by the 12-member porphyrin nanoring, which had previously been the largest in this class, to show clear global aromaticity.

Boron replaces metal by forming complexes with olefins, reducing toxicity and cost

When it comes to eliminating toxic and expensive heavy metals in the chemical industry, a new study from the University of Würzburg points the way forward.

The team led by chemistry professor Holger Braunschweig at the University of Würzburg is investigating the “metal-mimetic” properties of main group elements such as boron. They have shown that under certain conditions, boron can mimic the reaction behavior of metals without being toxic or as expensive as metals.

The article published in Nature Chemistry shows that boron can also form so-called π complexes with , which are similar in their properties and behavior to the complexes of transition metals with olefins. The latter compounds are intermediates in many large-scale catalytic processes in industry.

Shape-shifting material could transform future of implantable and ingestible medical devices

Researchers led by Rice University’s Yong Lin Kong have developed a soft but strong metamaterial that can be controlled remotely to rapidly transform its size and shape.

The invention, published in Science Advances, represents a significant advancement that can potentially transform ingestible and .

Metamaterials are synthetic constructs that exhibit unusual properties not typically found in . Instead of relying solely on , the effective behavior of these materials is primarily determined by the physical structure, i.e., the specific shape, arrangement and scale of their building blocks.

Chemists create light-switchable magnets that remain active for hours

A research team from the University of Chemistry and Technology, Prague (UCT Prague) and the Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences (IOCB Prague) has created and described a new type of photoswitch. The molecule, a thienyl-based acylhydrazone, undergoes an unprecedented “closed-to-open-shell” transformation, where light converts it into a stable diradical.

While previously published lifetimes of such triplet states are a few milliseconds, this ’s switched state has a half-life of over six hours. This revolutionary innovation opens the way for optimizing , developing new and spintronic devices, and targeted elimination of antibiotic-resistant pathogens. The work is published in the Journal of Materials Chemistry C.

Photoswitches are molecules that change between two states under the influence of light. This new switch is unique because it transitions from a stable, non-magnetic (closed-shell) state to an exceptionally long-lived magnetic (open-shell triplet) state. In this triplet state, two electrons have parallel spins, making the molecule paramagnetic and highly reactive. This state is crucial for many photochemical processes, including the generation of .

Novel catalyst design could make green hydrogen production more efficient and durable

A new type of catalyst—a material that speeds up chemical reactions—that could make the production of clean hydrogen fuel more efficient and long-lasting has been developed by a team led by City University of Hong Kong, including researchers from Hong Kong, mainland China, and Japan.

This breakthrough uses high-density single atoms of iridium (a rare metal) to greatly improve the process of splitting water into and , which is key to like hydrogen fuel cells and large-scale energy storage.

The researchers created a highly stable and active by placing single iridium atoms on ultra-thin sheets made of cobalt and cerium compounds. Called CoCe–O–IrSA, the final product performs exceptionally well in the water-splitting process. It requires very little extra energy (just 187 mV of overpotential at 100 mA cm-2) to drive the oxygen evolution reaction at a high rate, and it stays stable for more than 1,000 hours under demanding conditions.

Physicists create new electrically controlled silicon-based quantum device

A team of scientists at Simon Fraser University’s Quantum Technology Lab and leading Canada-based quantum company Photonic Inc. have created a new type of silicon-based quantum device controlled both optically and electrically, marking the latest breakthrough in the global quantum computing race.

The research, published in the journal Nature Photonics, reveals new diode nanocavity devices for electrical control over silicon color center qubits.

The devices have achieved the first-ever demonstration of an electrically-injected single-photon source in silicon. The breakthrough clears another hurdle toward building a quantum computer—which has enormous potential to provide computing power well beyond that of today’s supercomputers and advance fields like chemistry, materials science, medicine and cybersecurity.

Differences in brain chemistry shape two common movement disorders

Researchers have identified a neurochemical signature that sets Parkinson’s disease apart from essential tremor — two of the most common movement disorders, but each linked to distinct changes in the brain.

In a new study in Nature Communications, scientists identified unique chemical signaling patterns of two key neurotransmitters — dopamine and serotonin — that distinguish these two disorders.

“This study builds on decades of work,” said a co-senior author, who with colleagues developed the multi-faceted technologies and the theoretical constructs for the work over their 15 years at the research institute.

Solar breakthrough — hotter panels mean better storage

Scientists have uncovered a surprising advantage in next-generation solar technology—the hotter it gets, the better it can store energy. Traditionally, heat has been seen as the enemy of solar power. Standard solar panels lose efficiency as temperatures rise.

But a new study, published in The Journal of Chemical Physics, shows that in special “solar-plus-storage” devices, heat can actually boost performance by speeding up the internal chemical reactions that store energy.

The team studied photoelectrochemical (PEC) flow cells—an emerging technology that combines the sunlight-harvesting ability of a solar panel with the storage power of a battery.

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