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Category: chemistry – Page 45

Scientists Create the Impossible: New Compound Challenges Fundamental Principle of Chemistry

Once thought unlikely, this new finding in coordination chemistry could lead to promising advances in catalysis and materials science.

For more than 100 years, the widely accepted 18-electron rule has been a foundational guideline in organometallic chemistry. Now, researchers at the Okinawa Institute of Science and Technology (OIST) have synthesized a new organometallic compound that challenges this principle. They developed a stable 20-electron version of ferrocene, an iron-based metal-organic complex, which could open new directions in chemical research.

“For many transition metal complexes, they are most stable when surrounded by 18 formal valence electrons. This is a chemical rule of thumb on which many key discoveries in catalysis and materials science are based,” said Dr. Satoshi Takebayashi, lead author of the paper published in Nature Communications.

New AI tool deciphers mysteries of nanoparticle motion in liquid environments

Nanoparticles—the tiniest building blocks of our world—are constantly in motion, bouncing, shifting, and drifting in unpredictable paths shaped by invisible forces and random environmental fluctuations.

Better understanding their movements is key to developing better medicines, materials, and sensors. But observing and interpreting their motion at the atomic scale has presented scientists with major challenges.

Researchers in Georgia Tech’s School of Chemical and Biomolecular Engineering (ChBE) have developed an (AI) model that learns the underlying physics governing those movements.

How paper planes could provide sustainable solutions to space debris

Space junk is a huge problem. The surge in satellite launches in recent years is leaving low Earth orbit (LEO) cluttered with debris such as discarded rocket bodies, broken parts and defunct satellites. Beyond the risk of debris colliding with working satellites that are vital for navigation, communication and weather forecasting, large pieces could come crashing back down to Earth.

Space junk may also be a threat to the environment. Old rockets and satellites burn up when they re-enter the atmosphere, leaving a trail of chemicals behind that could damage the ozone layer. The more we launch, the messier LEO gets, and the bigger the problems become.

Space agencies and private companies are looking at ways to clear up the litter we leave behind, but they’re also exploring how to build more sustainable rockets and satellites, using organic polymers instead of metals. In a new study, published in Acta Astronautica, researchers turned to origami, the ancient Japanese art of paper folding, to find a sustainable alternative.

Chinese team says carbon dioxide can be turned into sugar

“Artificial conversion of carbon dioxide into food and chemicals offers a promising strategy to address both environmental and population-related challenges while contributing to carbon neutrality,” the team said in a paper published in the peer-reviewed journal Science Bulletin in May.

Reducing carbon dioxide to less complex molecules has proven successful, though the researchers said that generating long-chain carbohydrates – the most abundant substances in nature – has proven to be a challenge for scientists.

“In vitro biotransformation (ivBT) has emerged as a highly promising platform for sustainable biomanufacturing,” the team from the Chinese Academy of Sciences’ Tianjin Institute of Industrial Biotechnology wrote.

Ultrathin clay membrane layers offer low-cost alternative for extracting lithium from water

Lithium, the lightest metal on the periodic table, plays a pivotal role in modern life. Its low weight and high energy density make it ideal for electric vehicles, cellphones, laptops and military technologies where every ounce counts. As demand for lithium skyrockets, concerns about supply and reliability are growing.

To help meet surging demand and possible supply chain problems, scientists at the U.S. Department of Energy’s (DOE) Argonne National Laboratory have developed an innovative technology that efficiently extracts lithium from water. Several team members also hold joint appointments with the Pritzker School of Molecular Engineering (PME) at the University of Chicago.

The findings appear in the journal Advanced Materials.

Scientists Confirm The Existence Of Element 117

The official Periodic Table of the Elements is one step closer to adding element 117 to its ranks. That’s thanks to an international team of scientists that was able to successfully create several atoms of element 117, which is currently known as Ununseptium until it’s given an official name.

The paper for this experiment has been published in Physical Review Letters.

Element 117 was first created in a joint collaboration between American and Russian scientists back in 2010. However, before an element can be officially added to the Periodic Table of Elements, its discovery must be independently confirmed.

Wristband sensor provides all-in-one monitoring for diabetes and cardiovascular care

A new wearable wristband could significantly improve diabetes management by continuously tracking not only glucose but also other chemical and cardiovascular signals that influence disease progression and overall health. The technology was published in Nature Biomedical Engineering.

The flexible wristband consists of a microneedle array that painlessly samples interstitial fluid under the skin to measure glucose, lactate and alcohol in real time using three different enzymes embedded within the tiny needles. Designed for easy replacement, the microneedle array can be swapped out to tailor wear periods. This reduces the risk of allergic reactions or infection while supporting longer-term use.

Simultaneously, the wristband uses an ultrasonic sensor array to measure and arterial stiffness, while ECG sensors measure heart rate directly from wrist pulses. These physiological signals are key indicators of cardiovascular risk, which is often elevated in people with diabetes but is rarely monitored continuously outside of a clinical setting.

AI-assisted technique can measure and track aging cells

A combination of high-resolution imaging and machine learning, also known as artificial intelligence (AI), can track cells damaged from injury, aging, or disease, and that no longer grow and reproduce normally, a new study shows.

These senescent cells are known to play a key role in wound repair and aging-related diseases, such as cancer and heart disease, so tracking their progress, researchers say, could lead to a better understanding of how tissues gradually lose their ability to regenerate over time or how they fuel disease. The tool could also provide insight into therapies for reversing the damage.

The study included training a computer system to help analyze animal cells damaged by increasing concentrations of chemicals over time to replicate human aging. Cells continuously confronted with environmental or biological stress are known to senesce, meaning they stop reproducing and start to release telltale molecules indicating that they have suffered injury.

Inflammasome Molecular Insights in Autoimmune Diseases

Autoimmune diseases (AIDs) emerge due to an irregular immune response towards self- and non-self-antigens. Inflammation commonly accompanies these conditions, with inflammatory factors and inflammasomes playing pivotal roles in their progression. Key concepts in molecular biology, inflammation, and molecular mimicry are crucial to understanding AID development. Exposure to foreign antigens can cause inflammation, potentially leading to AIDs through molecular mimicry triggered by cross-reactive epitopes. Molecular mimicry emerges as a key mechanism by which infectious or chemical agents trigger autoimmunity. In certain susceptible individuals, autoreactive T or B cells may be activated by a foreign antigen due to resemblances between foreign and self-peptides. Chronic inflammation, typically driven by abnormal immune responses, is strongly associated with AID pathogenesis. Inflammasomes, which are vital cytosolic multiprotein complexes assembled in response to infections and stress, are crucial to activating inflammatory processes in macrophages. Chronic inflammation, characterized by prolonged tissue injury and repair cycles, can significantly damage tissues, thereby increasing the risk of AIDs. Inhibiting inflammasomes, particularly in autoinflammatory disorders, has garnered significant interest, with pharmaceutical advancements targeting cytokines and inflammasomes showing promise in AID management.

Caltech’s New Smart Pill Can Read Your Gut Like Never Before

Researchers are gaining a deeper appreciation for the critical role the gastrointestinal (GI) tract plays in maintaining overall health. Beyond its primary responsibilities in digestion, the GI system contributes to the production of hormones, immune cells, and neurotransmitters that influence brain function and emotional well-being.

Because of this, the GI tract contains a wide array of biomarkers that are valuable for diagnosing, tracking, and managing disease—from short-chain fatty acids associated with metabolic syndrome to cytokines linked to inflammation.

However, current technologies fall short when it comes to capturing this biochemical information directly from the GI tract. Existing methods, such as fecal sampling and tissue biopsies, are often invasive, costly, and unable to deliver continuous or comprehensive real-time data throughout the length of the digestive system.

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