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Category: chemistry – Page 36

Physicists are getting closer to controlling single-molecule chemical reactions – could this shape the future of pharmaceutical research?

A groundbreaking study demonstrates control over atomic-level matter through nanotechnology. By leveraging the precision of scanning tunneling microscopy, researchers have shown how competing chemical reaction outcomes can be influenced by manipulating energy levels. This advancement allows for targeted reactions, such as those needed for drug synthesis, while reducing unwanted byproducts.

Controlling matter at the atomic level.

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These scenarios pose several new challenges, since the environmental and operational conditions of the mission will strongly differ than those on the International Space Station (ISS). One critical parameter will be the increased mission duration and further distance from Earth, requiring a Life Support System (LSS) as independent as possible from Earth’s resources. Current LSS physico-chemical technologies at the ISS can recycle 90% of water and regain 42% of O2 from the astronaut’s exhaled CO2, but they are not able to produce food, which can currently only be achieved using biology. A future LSS will most likely include some of these technologies currently in use, but will also need to include biological components. A potential biological candidate are microalgae, which compared to higher plants, offer a higher harvest index, higher biomass productivity and require less water. Several algal species have already been investigated for space applications in the last decades, being Chlorella vulgaris a promising and widely researched species. C. vulgaris is a spherical single cell organism, with a mean diameter of 6 µm. It can grow in a wide range of pH and temperature levels and CO2 concentrations and it shows a high resistance to cross contamination and to mechanical shear stress, making it an ideal organism for long-term LSS. In order to continuously and efficiently produce the oxygen and food required for the LSS, the microalgae need to grow in a well-controlled and stable environment. Therefore, besides the biological aspects, the design of the cultivation system, the Photobioreactor (PBR), is also crucial. Even if research both on C. vulgaris and in general about PBRs has been carried out for decades, several challenges both in the biological and technological aspects need to be solved, before a PBR can be used as part of the LSS in a Moon base. Those include: radiation effects on algae, operation under partial gravity, selection of the required hardware for cultivation and food processing, system automation and long-term performance and stability.

The International Space Station (ISS) has been continuously inhabited for over twenty years. The Life Support System (LSS) on board the station is in charge of providing the astronauts with oxygen, water and food. For that, Physico-Chemical (PC) technologies are used, recycling 90% of the water and recovering 42% of the oxygen (O2) from the carbon dioxide (CO2) that astronauts produce (Crusan and Gatens, 2017), while food is supplied from Earth.

Space agencies currently plan missions beyond Low Earth Orbit, with a Moon base or a mission to Mars as potential future scenarios (ESA Blog 2016; ISEGC 2018; NASA 2020). The higher distance from Earth of a lunar base, compared to the ISS, might require the production of food in-situ, to reduce the amount of resources required from Earth. PC technologies are not able to produce food, which can only be achieved using biological organisms. Several candidates are currently being investigated, with a main focus on higher plants (Kittang et al., 2014; Hamilton et al., 2020) and microalgae (Detrell et al., 2020b; Poughon et al., 2020).

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A new design principle has been identified that could eliminate the use of toxic chemicals in solar cell manufacturing.

The standard manufacturing process of organic cells involves toxic solvents. This environmental concern has hindered the widespread adoption of organic solar cells.

Researchers at Linköping University (LiU) have revealed a new design principle for eco-friendly, high-efficiency organic solar cells.

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For the study, the researchers conducted microscopy analyses of a zircon grain obtained from Black Beauty, which builds off a 2022 study involving the same zircon grain where researchers found the grain had experienced being “shocked” from a meteorite impact long ago. For this latest study, the researchers found that the zircon grain contained unique evidence regarding past liquid water on the Red Planet.

“We used nano-scale geochemistry to detect elemental evidence of hot water on Mars 4.45 billion years ago,” said Dr. Aaron Cavosie, who is a senior lecturer in the School of Earth and Planetary Sciences at Curtin University and a co-author on the study. “Hydrothermal systems were essential for the development of life on Earth and our findings suggest Mars also had water, a key ingredient for habitable environments, during the earliest history of crust formation. Through nano-scale imaging and spectroscopy, the team identified element patterns in this unique zircon, including iron, aluminum, yttrium and sodium. These elements were added as the zircon formed 4.45 billion years ago, suggesting water was present during early Martian magmatic activity.”

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Discovered in 1999 in Germany, the Nebra Sky Disc is the oldest known depiction of the cosmos. A recent examination of the Bronze Age artifact revealed the intricate methods used in its creation, which UNESCO described as “one of the most important archaeological finds of the twentieth century.”

The Nebra Sky Disc is a product of the Únětice culture, which originated in the Bronze Age of Central Europe. It reflects a sophisticated ancient understanding of both metalworking and astronomy and was created sometime between 1800 and 1,600 BCE. Clusters of stars, a sun, and a crescent moon are among the celestial bodies depicted by golden inlays covering the blue-green patina of the Nebra Sky Disc. The angle between the solstices is thought to be indicated by two golden arcs that run along the sides of the disc, one of which is now absent. It is thought that a boat is represented by another arc at the composition’s base. Only a few millimeters thick, the disc has a diameter of around 12 inches.

The Nebra Sky Disc is one of the best-investigated archaeological objects. The origin of the raw materials it is made of is well known The disc is made from copper, tin, and gold—materials whose origins have been traced to Cornwall, England. The rich blue-green patina of the disc’s bronze today results from chemical changes over time. Originally, it would have been a deep bronze hue.

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What do motion detectors, self-driving cars, chemical analyzers and satellites have in common? They all contain detectors for infrared (IR) light. At their core and besides readout electronics, such detectors usually consist of a crystalline semiconductor material.

Such materials are challenging to manufacture: They often require extreme conditions, such as a very high temperature, and a lot of energy. Empa researchers are convinced that there is an easier way. A team led by Ivan Shorubalko from the Transport at the Nanoscale Interfaces laboratory is working on miniaturized IR made of .

The words “quantum dots” do not sound like an easy concept to most people. Shorubalko explains, “The properties of a material depend not only on its chemical composition, but also on its dimensions.” If you produce tiny particles of a certain material, they may have different properties than larger pieces of the very same material. This is due to , hence the name “quantum dots.”

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Communities of microbes (microbiomes), particularly in soils, can be startlingly diverse, with as many as 10,000 species in just a cup of material. Scientists are working to understand how microbiomes and their members respond to their environments. These processes can profoundly shape the properties and composition of soils.

In a pair of studies published in The ISME Journal, researchers investigated how different species of interact with one another and exchange resources such as vitamins. The studies focused on corrinoids, the vitamin B12 family of nutrients. Many bacteria in the environment cannot produce these chemicals.

Focusing on a single type of nutrient enables the study of microbiomes in greater detail. The two studies further synergized by focusing on the same California grassland soil, allowing the researchers to generate a framework for understanding in this system.

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A new study from The Hospital for Sick Children (SickKids) and Institut Curie reveals how stem cells sense and respond to their environment, with implications for inflammatory bowel disease and colorectal cancer.

Stem cells constantly adapt to their environment to maintain organ and tissue health, informed by and physical forces. When they do not function as intended, stem cells can result in a number of health conditions including (IBD) and colorectal (bowel) cancer, where they continue to divide until a tumor forms.

Until now, how stem cells sense the physical forces around them has remained unclear, but novel findings published in Science led by Dr. Meryem Baghdadi, a former SickKids postdoctoral researcher, Dr. Tae-Hee Kim at SickKids and Dr. Danijela Vignjevic at Institut Curie, has revealed that stem cells depend on two , called PIEZO1 and PIEZO2, for their survival.

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