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Category: chemistry – Page 282

Discovered: An easier way to create ‘flexible diamonds’

As hard as diamond and as flexible as plastic, highly sought-after diamond nanothreads would be poised to revolutionize our world—if they weren’t so difficult to make.

Recently, a team of scientists led by Carnegie’s Samuel Dunning and Timothy Strobel developed an original technique that predicts and guides the ordered creation of strong, yet flexible, , surmounting several existing challenges. The innovation will make it easier for scientists to synthesize the nanothreads—an important step toward applying the material to practical problems in the future. The work was recently published in the Journal of the American Chemical Society.

Diamond nanothreads are ultra-thin, one-dimensional carbon chains, tens of thousands of times thinner than a human hair. They are often created by compressing smaller carbon-based rings together to form the same type of bond that makes the hardest mineral on our planet.

Entirely New, Inexpensive Catalyst Speeds the Production of Oxygen From Water

The material could replace rare metals and lead to more economical production of carbon-neutral fuels.

An electrochemical reaction that splits apart water molecules to produce oxygen is at the heart of multiple approaches aiming to produce alternative fuels for transportation. But this reaction has to be facilitated by a catalyst material, and today’s versions require the use of rare and expensive elements such as iridium, limiting the potential of such fuel production.

Now, researchers at MIT and elsewhere have developed an entirely new type of catalyst material, called a metal hydroxide-organic framework (MHOF), which is made of inexpensive and abundant components. The family of materials allows engineers to precisely tune the catalyst’s structure and composition to the needs of a particular chemical process, and it can then match or exceed the performance of conventional, more expensive catalysts.

AeroSHARK thin film reduces drag on airplanes

A collaboration between engineers at Lufthansa Technik and chemicals and coatings manufacturer BASF has resulted in the creation of AeroSHARK—a thin film coating that can be applied to an aircraft’s outer skin to reduce drag and thus fuel consumption and carbon emissions. Swiss International Airlines has posted a blog entry on their website describing the film and the benefits the company expects to get from it. Lufthansa Technik has also posted a blog entry detailing the development of AeroSHARK.

The thin film was developed as part of an effort kicked off by engineers at Lufthansa looking for ways to reduce the cost of fuel for their planes. To that end, they looked to nature, and more specifically, sharks—creatures who have been streamlined over millions of years of evolution. The researchers found that shark skin is covered with millions of “riblets,” which are protrusions that run the length of their bodies. The engineers then teamed up with a group at BASF to create a similar type of skin for aircraft. The result was the creation of AeroSHARK, a clear, thin skin with millions of riblets, each just 50 micrometers high. Testing showed that the material reduces drag.

The researchers found that by applying the skin to the entire fuselage and engines of a Boeing 777, they could reduce fuel consumption by 1.1%. Swiss estimates that the skin will result in reductions in across its fleet by 4,800 metric tons a year, which, in turn, will result in reducing by 15,200 metric tons. They suggest that amount is equivalent to 87 long-haul flights from Zurich to Mumbai. Swiss plans to coat all 12 of its 777-300ER airplanes with AeroSHARK starting this summer. Meanwhile, Lufthansa has begun coating all of its large cargo aircraft with the new skin.

New model may improve Bay Area seismic hazard maps

The Santa Cruz Mountains define the geography of the Bay Area south of San Francisco, protecting the peninsula from the Pacific Ocean’s cold marine layer and forming the region’s notorious microclimates. The range also represents the perils of living in Silicon Valley: earthquakes along the San Andreas fault.

In bursts that last seconds to minutes, earthquakes have moved the region’s surface meters at a time. But researchers have never been able to reconcile the quick release of the Earth’s stress and the bending of the Earth’s crust over years with the formation of mountain ranges over millions of years. Now, by combining geological, geophysical, geochemical and , geologists have created a 3D tectonic model that resolves these timescales.

The research, which appears in Science Advances Feb. 25, reveals that more mountain building happens in the period between along the San Andreas Fault, rather than during the quakes themselves. The findings may be used to improve local seismic hazard maps.

A new, inexpensive catalyst speeds the production of oxygen from water

An electrochemical reaction that splits apart water molecules to produce oxygen is at the heart of multiple approaches aiming to produce alternative fuels for transportation. But this reaction has to be facilitated by a catalyst material, and today’s versions require the use of rare and expensive elements such as iridium, limiting the potential of such fuel production.

Now, researchers at MIT and elsewhere have developed an entirely new type of catalyst material, called a metal hydroxide-organic framework (MHOF), which is made of inexpensive and abundant components. The family of materials allows engineers to precisely tune the ’s structure and composition to the needs of a particular chemical process, and it can then match or exceed the performance of conventional, more expensive catalysts.

The findings are described today in the journal Nature Materials, in a paper by MIT postdoc Shuai Yuan, graduate student Jiayu Peng, Professor Yang Shao-Horn, Professor Yuriy Román-Leshkov, and nine others.

Artificial neurons connect to biological ones to control living plants

Nature is a never-ending source of inspiration for scientists, but our artificial devices usually don’t communicate well with the real thing. Now, researchers at Linköping University have created artificial organic neurons and synapses that can integrate with natural biological systems, and demonstrated this by making a Venus flytrap close on demand.

The new artificial neurons build on the team’s earlier versions, which were organic electrochemical circuits printed onto thin plastic film. Since they’re made out of polymers that can conduct either positive or negative ions, these circuits form the basis of transistors. In the new study, the team optimized these transistors and used them to build artificial neurons and synapses, and connect them to biological systems.

When the transistors detect concentrations of ions with certain charges, they switch, producing a signal that can then be picked up by other neurons. Importantly, biological neurons operate on these same ion signals, meaning artificial and natural nerve cells can be connected.

A step closer to biodegradable household batteries

Fully organic rechargeable household batteries are an ideal alternative to traditional metal-based batteries, in particular for reducing pollution to landfill and the environment.

Now researchers at Flinders University, with Australian and Chinese collaborators, are developing an all-organic polymer battery that can deliver a cell voltage of 2.8V—a big leap in improving the energy storage capability of organic batteries.

“While starting with small household batteries, we already know organic redox-active materials are typical electroactive alternatives due to their inherently safe, lightweight and structure-tunable features and, most importantly, their sustainable and environmentally friendly,” says senior lecturer in chemistry Dr. Zhongfan Jia, a research leader at Flinders University’s Institute for Nanoscale Science and Technology.

Fluidic device finds novel way to make oil and water attract

Imagine making some liquids mix that do not mix, then unmixing them.

In one of the grand challenges of science, a Flinders University device which previously ’unboiled’ egg protein is now unraveling the mystery of incompatible fluids; a development that could enhance many future products, and even the food we eat.

Using the highly advanced rapid fluidic flow techniques possible in the Flinders vortex fluidic device (VFD), the Australian research team has capped off 10 years of research to find a way to use clean chemistry to unlock the mystery of ‘mixing immiscibles’.