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Category: chemistry – Page 281

The oil industry, pharmaceutical companies and bioreactor manufacturers all face one common enemy: bubbles. Bubbles can form during the manufacturing or transport of various liquids, and their formation and rupture can cause significant issues in product quality.

Inspired by these issues and the puzzling physics behind , an international scientific collaboration was born. Stanford University chemical engineer Gerald Fuller along with his Ph.D. students Aadithya Kannan and Vinny Chandran Suja, as well as visiting Ph.D. student Daniele Tammaro from the University of Naples, teamed up to study how different kinds of bubbles pop.

The researchers were particularly interested in bubbles with proteins embedded on their surfaces, which is a common occurrence in the pharmaceutical industry and in bioreactors used for cell culture. In an unanticipated result, the researchers discovered that the protein bubbles they were studying opened up like flowers when popped with a needle. Their findings are detailed in a study published in the journal of the Proceedings of the National Academy of Sciences on July 19.

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A team led by a researcher from the University of Sydney has developed a low-cost, sustainable, and readily available technology that can dim the screens of electronic devices, anti-reflection automobile mirrors, and smart architectural windows at a fraction of the cost of current technology.

It would replace one of the world’s scarcest—yet highly ubiquitous in use—modern materials: indium. A rare chemical element, that it is widely used in devices such as smartphones and computers, windscreen glass and self-dimming windows.

Although small amounts are used to manufacture smart screens, indium is expensive as it is hard to source; it naturally occurs only in small deposits. Industrial indium is often made as a byproduct of zinc mining, which means a shortage could occur if demand for optoelectronic devices—such as LCDs and touch panels—ramps up.

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CHINA’S NEW THORIUM-BASED NUCLEAR REACTOR is well situated for being adopted for Space applications.

China is slowly but steadily positioning itself to leap ahead of the US Space program. It is doing this without pomp and fanfare, and without the idea of a “space race,” simply based upon what it requires for its future.

1) Recent noteworthy progress on molten salt thorium reactors could be a key component of future Chinese space-worthiness. Originally designed by the USA’s Oak Ridge National Laboratory in the 1960’s, they were planned to be used for nuclear powered strategic bomber planes, before the nuclear submarine concept became adopted as more feasible. They were chosen because they can be miniaturized to the size of an aircraft. By the same token, they could conceivably be used in advanced atmospheric or space propulsion.

2) Recently, China announced successful tests on a new type of aircraft that takes in air from the surrounding atmosphere, ionizes it with electricity, and expels it as exhaust. The only thing needed would be a strong enough on-board electrical supply to supply the huge amount of power required. Only a nuclear power plant could supply that power unless it were to be beamed from ground stations. Such a plane would require no fuel for its entire lifetime. It could also function in any atmosphere, not only Earth’s atmosphere, since it is not based on burning fuel chemically, which requires oxygen. Versions of such air-plasma-breathing thrust could be used as part of the boosting phase of a rocket launch system.

3) A few days ago, China tested part of its fully reusable space plane, which is a vastly superior system to SpaceX’s “Starship” rocket. While Starship uses old-fashioned ballistic rocket technology, the Chinese spaceplane, according to reports that have come out, involves something similar to the Sanger space plane design. An early version of the Space Shuttle design also had this configuration. Instead of the Space Shuttle’s dangerous solid rocket boosters on the side, and its external fuel tank, which is dumped once the fuel is used up, such systems have a second “booster aircraft” which glides to a runway after boosting the upper stage orbiter into its atmospheric launch position. So, there are two vehicles which land on a runway, with only the orbiter going into space. In addition to this, the Chinese are adding “combined cycle” technologies, where more than one type of propulsion is being used on the aircraft. So, perhaps turbojets, and scramjets, and rocket engines will be used as one example of such a configuration.

The new molten salt reactors, part of a program developed under the leadership of former Chinese President Zemin’s son, and with collaboration from the US’s Oakridge National Laboratory, is now close to implementation stage. Such reactors could be integrated into a space plane, allowing “single-stage-to-orbit” concepts to become within reach. Such systems would not need a booster phase, but would use a combination of air-plasma-breathing and rocket engines to get to orbit with only a single vehicle, while landing like the Space Shuttle did or perhaps landing with powered flight instead of gliding without fuel as did the Shuttle.

All of this makes China’s plan for “nuclear-powered space shuttles” in the 2040’s very possible. If fusion power is obtained before then, this will all proceed even faster, and all the technical and engineering skills will be immediately brought to bear.

Continue reading “China unveils design for first waterless nuclear reactor” | >

Nick Saraev is 25 years old, far too young, it would seem, to be thinking about death. And yet, since he turned 21, he has taken steps to prevent the infirmities of old age. Every day, he takes 2000 mg of fish oil and 4000 IU of vitamin D to help prevent heart disease and other ailments. He steams or pressure-cooks most of his meals because, he says, charring meats creates chemicals that may increase the risk of cancer. And in the winter, he keeps the humidity of his home at 35 percent, because dry air chaps his skin and makes him cough, both of which he considers manifestations of chronic inflammation, which may be bad for longevity.

Based on the life expectancies of young men in North America, Saraev, a freelance software engineer based near Vancouver, believes he has about 55 years before he really has to think about aging. Given the exponential advances in microprocessors and smartphones in his lifetime, he insists the biotech industry will figure out a solution by then. For this reason, Saraev, like any number of young, optimistic, tech-associated men, believes that if he takes the correct preventative steps now, he might well live forever. Saraev’s plan is to keep his body in good enough shape to hit “Longevity Escape Velocity,” a term coined by English gerontologist Aubrey de Grey to denote slowing down your aging enough to reach each new medical advance as it arrives. If you delay your death by 10 years, for example, that’s 10 more years scientists have to come up with a drug, computer program, or robot assist that can make you live even longer. Keep up this game of reverse leapfrog, and eventually death can’t catch you. The term is reminiscent of “planetary escape velocity,” the speed an object needs to move in order to break free of gravity.

The science required to break free of death, unfortunately, is still at ground level. According to Nir Barzilai, M.D., director of the Institute for Aging Research at Albert Einstein College of Medicine in New York City, scientists currently understand aging as a function of seven to nine biological hallmarks, factors that change as we grow older and seem to have an anti-aging effect when reversed. You can imagine these as knobs you can turn up or down to increase or decrease the likelihood of illness and frailty. Some of these you may have heard of, including how well cells remove waste, called proteostasis; how well cells create energy, or mitochondrial function; how well cells implement their genetic instructions, or epigenetics; and how well cells maintain their DNA’s integrity, called DNA repair or telomere erosion.

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A new way of producing coherent light in the ultra-violet spectral region, which points the way to developing brilliant table-top x-ray sources, has been produced in research led at the University of Strathclyde.

The scientists have developed a type of ultra-short wavelength coherent light source that does not require laser action to produce coherence. Common electron-beam based light sources, known as fourth-generation light sources, are based on the free-electron laser (FEL), which uses an undulator to convert electron beam energy into X-rays.

Coherent light sources are powerful tools that enable research in many areas of medicine, biology, material sciences, chemistry, and physics.

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Soldiers and Marines teamed up to test new tactical biological detection and chemical contamination systems that aim to keep service members safe. The systems indicate when chemical agents are present so decontamination can take place.

DUGWAY PROVING GROUND, Utah — Soldiers from Fort Drum and Joint Base Lewis-McChord teamed with Marines from Camp Pendleton to test new tactical biological detection and chemical contamination indicator systems here.

Soldiers with the 59th Hazard Response Company and 13th Combat Sustainment Support Battalion along with Marines from the 3rd Marine Air Wing went hands-on with the Joint Biological Tactical Detection System (JBTDS) and the Contamination Indication Disclosure Assurance System (CIDAS), which indicates chemical agent contaminants so proper decontamination can take place.

“These two operational tests have given my company the opportunity to focus on our critical war-time collective tasks of site assessment and decontamination and refine our tactics, techniques, and procedures,” said Capt. Ryan Oatman, company commander of 59th Chemical, Biological, Radiological and Nuclear (CBRN) Hazard Response Company.

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Recently, we found dramatic mitochondrial DNA divergence of Israeli Chamaeleo chamaeleon populations into two geographically distinct groups. We aimed to examine whether the same pattern of divergence could be found in nuclear genes. However, no genomic resource is available for any chameleon species. Here we present the first chameleon transcriptome, obtained using deep sequencing (SOLiD). Our analysis identified 164000 sequence contigs of which 19000 yielded unique BlastX hits. To test the efficacy of our sequencing effort, we examined whether the chameleon and other available reptilian transcriptomes harbored complete sets of genes comprising known biochemical pathways, focusing on the nDNA-encoded oxidative phosphorylation (OXPHOS) genes as a model. As a reference for the screen, we used the human 86 (including isoforms) known structural nDNA-encoded OXPHOS subunits. Analysis of 34 publicly available vertebrate transcriptomes revealed orthologs for most human OXPHOS genes. However, OXPHOS subunit COX8 (Cytochrome C oxidase subunit 8), including all its known isoforms, was consistently absent in transcriptomes of iguanian lizards, implying loss of this subunit during the radiation of this suborder. The lack of COX8 in the suborder Iguania is intriguing, since it is important for cellular respiration and ATP production. Our sequencing effort added a new resource for comparative genomic studies, and shed new light on the evolutionary dynamics of the OXPHOS system.

Keywords: chameleon, oxidative phosphorylation, transcriptome.

Massive parallel sequencing (MPS) enables identifying the entire set of transcribed genes (transcriptome) of understudied organisms, thus providing novel genomic resources. However, because there is no genomic reference to those organisms, the short reads generated by MPS must be de novo assembled in order to form sequence contigs, which in turn could be annotated (Kusumi et al. 2011), thus creating reference sequences for further analyses.

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Most plastic persists in the environment. A recently developed polymer degrades in a week and doesn’t leave microplastics behind. Image credit: Larina Marina/ Shutterstock.

Plastic trash chokes shorelines and oceans, in part because plastic polymers do not easily decompose. But a new kind of environmentally degradable plastic could help change that: It breaks down in about a week in sunlight and air, according to a recent study in the Journal of the American Chemical Society (JACS). Chemical characterization using nuclear magnetic resonance (NMR) and mass spectroscopy, among other techniques, revealed that the plastic decomposed rapidly in sunlight from a petroleum-based polymer into succinic acid, a naturally occurring nontoxic small molecule that doesn’t leave microplastic fragments in the environment.

Although a sun-sensitive plastic might not be a good choice for bottles or bags that need to last more than a week on shelves, integrating the environmentally degradable polymer as a minor ingredient, or with other biodegradable polymers, could help speed breakdown of these materials in landfills, says coauthor Liang Luo, an organic materials scientist at Huazhong University of Science and Technology in Wuhan, China. The flexible and degradable material would be potentially useful inside electronics, he says. Sealed inside a cell phone or other flexible electronic device, the polymer could last for years isolated from light and oxygen, Luo notes, while making smartphones easier to dispose of at the end of their service life. And the byproduct succinic acid could be upcycled for commercial uses in the pharmaceutical and food industries, Luo adds.

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