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Category: chemistry – Page 260

Hydrogen is already a key component of chemical industrial processes and in the steel industry. So making clean hydrogen to use in those industrial processes is critical to reducing carbon emissions, says Jake Stones at market research firm Independent Commodity Intelligence Services (ICIS).

But as an energy source itself, hydrogen’s big advantage is its versatility according to Sunita Satyapal, who oversees hydrogen fuel cell technology for the Department of Energy.

“It’s often called the Swiss Army knife of energy,” she says.

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The world’s first demonstration device to produce 1,000 tons of gasoline per year from carbon dioxide (CO2) hydrogenation has completed its technology evaluation and trial operation.

Located in the Zoucheng Industrial Park, Shandong province, China, the project has been jointly developed by the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) and the Zhuhai Futian Energy Technology company. The hydrogenation of CO2 into liquid fuels and chemicals can not only realize the resource utilization of CO2 but also facilitate the storage and transportation of renewable energy.

However, activation and selective conversion of CO2 are challenging. A technology that can selectively produce energy-dense, value-added hydrocarbon fuels will provide a new route to promote the clean, low-carbon energy revolution.

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One of the especially promising therapies to appear in the realm of anti-aging research involves a set of molecules known as Yamanaka factors, which scientists have deployed to rejuvenate aging cells, trigger muscle regeneration and tackle glaucoma. New research at the Salk Institute has sought to build on these short-term and specific use cases by demonstrating how these molecules can reverse signs of aging in middle-aged and elderly mice, with no evidence of health problems following the extended treatment.

The Yamanaka factors at the center of this study are a set of four reprogramming molecules that can reset the molecular clock found in the cells of the body. They do so by returning unique patterns of chemicals known as epigenetic markers, which evolve through aging, to their original states.

This approach has been used to convert adult cells back into stem cells, that can then differentiate into different cell types. The Salk Institute team has previously used the approach to reverse signs of aging in mice with a premature aging disease, and improve the function of tissues found in the heart and brain. Separately, Stanford University scientists last year used the technique to give elderly mice the muscle strength of younger mice.

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Drugs are polluting rivers and adding to the resistance crisis as well as affecting riverine ecosystems.

Pharmaceutical pollution in the world’s rivers is threatening environmental and human health and the attainment of UN goals on water quality, with developing countries the worst affected, a global study warns.

Active pharmaceutical ingredients (APIs) could be contributing to antimicrobial resistance in microorganisms, and may have unknown long-term effects on human health, as well as harming aquatic life, according to the report published in Proceedings of the National Academy of Sciences.

APIs – the chemicals used to make pharmaceutical drugs – can reach the natural environment during their manufacture, use and disposal, according to the study.

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Membrane filters don’t require much energy to purify water, making them popular for wastewater treatment. To keep these materials in tip-top condition, they’re commonly cleaned with large amounts of strong chemicals, but some of these agents destroy the membranes in the process. Now, researchers reporting in ACS Applied Materials & Interfaces have developed reusable nanoparticle catalysts that incorporate glucose to help efficiently break down contaminants inside these filters without damaging them.

Typically, dirty wastewater filters are unclogged with strong acids, bases or oxidants. Chlorine-containing oxidants such as bleach can break down the most stubborn organic debris. But they also damage polyamide membranes, which are in most commercial nanofiltration systems, and they produce toxic byproducts. A milder alternative to bleach is hydrogen peroxide, but it decomposes contaminants slowly.

Previously, scientists have combined hydrogen peroxide with iron oxide to form that improve hydrogen peroxide’s efficiency in a process known as the Fenton reaction. Yet in order for the Fenton reaction to clean filters, extra hydrogen peroxide and acid are needed, increasing financial and environmental costs. One way to avoid these additional chemicals is to use the enzyme glucose oxidase, which simultaneously forms and gluconic acid from glucose and oxygen. So, Jianquan Luo and colleagues wanted to combine glucose oxidase and into a system that catalyzes the Fenton-based breakdown of contaminants, creating an efficient and delicate cleaning system for .

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Circa 2020 o.o!

A team of physicists at a university in the Netherlands have 3D-printed a microscopic version of the USS Voyager, an Intrepid-class starship from Star Trek.

The miniature Voyager, which measures 15 micrometers (0.015 millimeters) long, is part of a project researchers at Leiden University conducted to understand how shape affects the motion and interactions of microswimmers.

Microswimmers are small particles that can move through liquid on their own by interacting with their environment through chemical reactions. The platinum coating on the microswimmers reacts to a hydrogen peroxide solution they are placed in, and that propels them through the liquid.

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Do two promising structural materials corrode at very high temperatures when in contact with “liquid metal fuel breeders” in fusion reactors? Researchers of Tokyo Institute of Technology (Tokyo Tech), National Institutes for Quantum Science and Technology (QST), and Yokohama National University (YNU) now have the answer. This high-temperature compatibility of reactor structural materials with the liquid breeder—a lining around the reactor core that absorbs and traps the high energy neutrons produced in the plasma inside the reactor—is key to the success of a fusion reactor design.

Fusion reactors could be a powerful means of generating clean electricity, and currently, several potential designs are being explored. In a fusion , the fusion of two nuclei releases massive amounts of energy. This energy is trapped as heat in a “breeding blanket” (BB), typically a liquid lithium alloy, surrounding the . This heat is then used to run a turbine and generate electricity. The BB also has an essential function of fusion fuel breeding, creating a closed fuel cycle for the endless operation of the reactors without fuel depletion.

The operation of a BB at extremely high temperatures over 1,173 K serves the attractive function of producing hydrogen from water, which is a promising technology for realizing a carbon-neutral society. This is possible because the BB heats up to over 1,173 K by absorbing the energy from the reaction. At such temperatures, there is the risk of structural materials in contact with the BB becoming corroded, compromising the safety and stability of the reactors. It is thus necessary to find structural materials that are chemically compatible with the BB material at these temperatures.

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Process achieved at industrial scale in 120 litre reactor.

Factory

The 120 litre LanzaTech pilot plant that can convert carbon dioxide into acetone and isopropanol.

Industrial scale carbon-negative production of two commodity chemicals has been achieved for the first time using a genetically modified bacterium that can turn waste carbon dioxide into acetone and isopropanol. The work, which offers a blueprint for making other chemicals, holds promise for a more sustainable, renewable and environmentally-friendly chemical industry as the world strives to shift from fossil fuels to a circular carbon economy.

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Engineers working to reverse the proliferation of greenhouse gases know that in addition to reducing carbon dioxide emissions we will also need to remove carbon dioxide from power plant fumes or from the skies. But, what do we do with all that captured carbon? Matteo Cargnello, a chemical engineer at Stanford University, is working to turn it into other useful chemicals, such as propane, butane or other hydrocarbon fuels that are made up of long chains of carbon and hydrogen.

“We can create gasoline, basically,” said Cargnello, who is an assistant professor of chemical engineering. “To capture as much as possible, you want the longest chain hydrocarbons. Chains with eight to 12 would be the ideal.”

A new catalyst, invented by Cargnello and colleagues, moves toward this goal by increasing the production of long-chain hydrocarbons in chemical reactions. It produced 1,000 times more butane—the longest hydrocarbon it could produce under its maximum pressure—than the standard catalyst given the same amounts of carbon , hydrogen, catalyst, pressure, heat and time. The new catalyst is composed of the element ruthenium—a rare transition metal belonging to the platinum group—coated in a thin layer of plastic. Like any catalyst, this invention speeds up chemical reactions without getting used up in the process. Ruthenium also has the advantage of being less expensive than other high-quality catalysts, like palladium and platinum.

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Pure lithium metal is a promising replacement for the graphite-based anodes currently used in electric vehicle batteries. It could tremendously reduce battery weights and dramatically extend the driving range of electric vehicles relative to existing technologies. But before lithium metal batteries can be used in cars, scientists must first figure out how to extend their lifetimes.

A new study led by Peter Khalifah—a chemist at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and Stony Brook University—tracked lithium deposition and removal from a while it was cycling to find clues as to how failure occurs. The work is published in a special issue of the Journal of the Electrochemical Society honoring the contributions of Nobel Prize-winning battery researcher John Goodenough, who like Khalifah is a member of the Battery 500 Consortium research team.

“In a good battery, the rate of lithium plating (deposition) and stripping (removal) will be the same at all positions on the surface of electrodes,” Khalifah said. “Our results show that it’s harder to remove lithium at certain places, which means there are problems there. By identifying the cause of the problems, we can figure out how to get rid of them and make better batteries with higher capacities and longer lifetimes.”

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