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Category: chemistry – Page 97

Now Flinders University researchers have discovered a light-responsive, inexpensive sulfur-derived receptive to low power, visible light lasers—which promises a more affordable and safer production method in nanotech, chemical science and patterning surfaces in biological applications.

Details of the novel system have just been published in Angewandte Chemie International Edition, featuring a laser-etched version of the famous “Mona Lisa” painting and micro-Braille printing even smaller than a pin head.

“This could be a way to reduce the need for expensive, specialized equipment, including high-power lasers with hazardous radiation risk, while also using more sustainable materials. For instance, the key polymer is made from low-cost elemental sulfur, an industrial byproduct, and either cyclopentadiene or dicyclopentadiene,” says Matthew Flinders Professor of Chemistry Justin Chalker, from the Flinders University.

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Anyone who wants to produce medication, plastics or fertilizer using conventional methods needs heat for chemical reactions – but not so with photochemistry, where light provides the energy. The process to achieve the desired product also often takes fewer intermediate steps.

Researchers from the University of Basel are now going one step further and are demonstrating how the energy efficiency of photochemical reactions can be increased tenfold. More sustainable and cost-effective applications are now tantalizingly close.

Industrial chemical reactions usually occur in several stages across various interim products. Photochemistry enables shortcuts, meaning fewer intermediate steps are required. Photochemistry also allows you to work with less hazardous substances than in conventional chemistry, as light produces a reaction in substances which do not react well under heat. However, to this point there have not been many industrial applications for photochemistry, partly because supplying energy with light is often inefficient or creates unwanted by-products.

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A recent study reveals how hydrogen gas, often touted as the energy source of tomorrow, provided energy in the past, at the origin of life 4 billion years ago. Hydrogen gas is clean fuel. It burns with oxygen in the air to provide energy with no CO2.

Hydrogen is a key to sustainable energy for the future. Though humans are just now coming to realize the benefits of hydrogen gas (H2 in chemical shorthand), microbes have known that H2 is a good fuel for as long as there has been life on Earth. Hydrogen is ancient energy.

The very first cells on Earth lived from H2 produced in hydrothermal vents, using the reaction of H2 with CO2 to make the molecules of life. Microbes that thrive from the reaction of H2 and CO2 can live in total darkness, inhabiting spooky, primordial habitats like deep-sea hydrothermal vents or hot rock formations deep within the Earth’s crust, environments where many scientists think that life itself arose.

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There are trillions of microbes in the human gastrointestinal tract, each of which expresses its own genome, and carries out a variety of biochemical processes. Gut microbes can generate a variety of molecules that can have a significant impact on human health, such as vitamins, specially modified bile acids, and short-chain fatty acids (SCFAs).

SCFAs have fewer than six carbon atoms, and are found in a few major forms, including acetate, propionate, and butyrate. When we eat fibers that are tough to digest, gut microbes metabolize them instead, and generate SCFAs. Many links have been found between butyrate and human health; it is thought to have roles in the maintainence of epithelial barriers, prevention of gut inflammation in the gut and colorectal cancer, and oxidative stress relief.

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Carbon nanotubes are cylindrical molecules that consist of rolled-up sheets of single-layer carbon atoms (graphene); they possess unique properties like high aspect ratio, mechanical strength, electrical and thermal conductivity, chemical stability, and a tip-surface area near the theoretical limit. They are one of the strongest materials known to man.

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Dr. Fan Liu: “Thanks to this very high precision analysis, we can see chemical differences between the twins. This provides very strong evidence that one of the stars has swallowed planets or planetary material and changed its composition.”

Can stars eat planets? This is what a recent study published in Nature hopes to address as a team of international researchers led by ASTRO 3D researchers investigated how some pairs of twin stars possess different compositions, which contradicts longstanding theories that they should possess similar compositions, hence the same twin stars. However, astronomers now hypothesize the compositional differences could be due to one of the twin stars devouring planets that orbit them. This study holds the potential to help astronomers better understand the formation and evolution of planetary systems and the mechanisms behind them, as well.

For the study, the team used a combination of the 6.5-meter Magellan Telescope, the European Southern Observatory’s Very Large Telescope, and the 10-meter Keck Telescope to collect data on 91 twin stars to ascertain their chemical compositions, and specifically the similarity of their compositions. In the end, the team discovered that approximately eight percent (7−8 twin stars) exhibited differences in their compositions, with the team hypothesizing that this was due to one of the stars ingesting one of their orbiting planets. Additionally, they found that the differing pairs were all main sequence stars, meaning they’re average-aged and conducting their fusion at their full potential. For context, our Sun is a main sequence star.

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Researchers report the birth of a ~2-billion-year-old orphan gene following #planetary #oxygenation, and how this humble beginning shaped the global planetary #ecosystem.

From so simple, a beginning: https://oup.silverchair-cdn.com/UI/app/svg/i.svg?versionId=192134

Abstract. Molecular innovations within key metabolisms can have profound impacts on element cycling and ecological distribution. Yet, much of the molecular foundations of early evolved enzymes and metabolisms are unknown. Here, we bring one such mystery to relief by probing the birth and evolution of the G-subunit protein, an integral component of certain members of the nitrogenase family, the only enzymes capable of biological nitrogen fixation. The G-subunit is a Paleoproterozoic-age orphan protein that appears more than 1 billion years after the origin of nitrogenases. We show that the G-subunit arose with novel nitrogenase metal dependence and the ecological expansion of nitrogen-fixing microbes following the transition in enviromental metal availabilities and atmospheric oxygenation that began ∼2.5 billion years ago. We identify molecular features that suggest early G-subunit proteins mediated cofactor or protein interactions required for novel metal dependency, priming ancient nitrogenases and their hosts to exploit these newly diversified geochemical environments. We further examined the degree of functional specialization in G-subunit evolution with extant and ancestral homologs using laboratory reconstruction experiments. Our results indicate that permanent recruitment of the orphan protein depended on the prior establishment of conserved molecular features and showcase how contingent evolutionary novelties might shape ecologically important microbial innovations.

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The future is going to be so lazy, yet so cut.

As next-generation weight-loss treatments like Wegovy and Zepbound continue to fly off the shelves, scientists are busy working on a medicine that could mimic the effects of exercise.

As explained in an American Chemical Society press release, trials thus far on SLU-PP-332, the potentially groundbreaking compound in question, show that it seems “capable of mimicking the physical boost of working out.”

“We cannot replace exercise; exercise is important on all levels,” Bahaa Elgendy, an anesthesiology professor at Washington University Medical School in St. Louis who serves as the principal investigator of the new compound, said in the press release. “If I can exercise, I should go ahead and get the physical activity. But there are so many cases in which a substitute is needed.”

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Four Lawrence Livermore National Laboratory (LLNL) researchers have partnered with Los Angeles-based SoCalGas and Munich, Germany-based Electrochaea to develop an electrobioreactor to allow excess renewable electricity from wind and solar sources to be stored in chemical bonds as renewable natural gas.

When renewable electricity supply exceeds demand, electric-utility operators intentionally curtail production of renewable electricity to avoid overloading the grid. In 2020, in California, more than 1.5 million megawatt hours of renewable electricity were curtailed, enough to power more than 100,000 households for a full year.

This practice also occurs in other countries. The team’s electrobioreactor uses the renewable electricity to convert water into hydrogen and oxygen. The microbes then use the hydrogen to convert carbon dioxide into methane, which is a major component of natural gas. Methane can then be moved around in natural gas pipelines and can be stored indefinitely, allowing the renewable energy to be recovered when it is most needed.

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For the first time, scientists have developed artificial nucleotides, the building blocks of DNA, with several additional properties in the laboratory. The DNA carries the genetic information of all living organisms and consists of only four different building blocks, the nucleotides. Nucleotides are composed of three distinctive parts: a sugar molecule, a phosphate group and one of the four nucleobases adenine, thymine, guanine and cytosine. The nucleotides are lined up millions of times and form the DNA double helix, similar to a spiral staircase. Scientists from the UoC’s Department of Chemistry have now shown that the structure of nucleotides can be modified to a great extent in the laboratory.

The researchers developed so-called threofuranosyl nucleic acid (TNA) with a new, additional base pair. These are the first steps on the way to fully artificial nucleic acids with enhanced chemical functionalities. The study ‘Expanding the Horizon of the Xeno Nucleic Acid Space: Threose Nucleic Acids with Increased Information Storage’ was published in the Journal of the American Chemical Society.

Artificial nucleic acids differ in structure from their originals.

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