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Category: chemistry – Page 346

This publication suggests that wax could be carried on vehicles and used to create hydrogen gas in situ, the waste carbon being used to make more wax via syngas production and the Fischer-Tropsch process, where carbon monoxide and hydrogen is converted into hydrocarbons as a potential source of petro-chemicals that does not involve releasing fossil carbon into the atmosphere. While this publication is still a long way from a working industrial-scale process, it offers a very hopeful potential avenue for less-polluting technology.

Philip recently attended an event for other Oxford University chemistry alumni, and one of the speakers drew attention to a recent publication from, among others, Oxford chemists, regarding the production of hydrogen from paraffin waxes by microwave degradation using a ruthenium catalyst.

Hydrogen has often been suggested as an environmentally-friendly replacement energy source for fossil fuels in transport vehicles and other applications requiring high energy density. (Note that hydrogen is not a “fuel”, as it must be made using energy from other sources, which can be environmentally-friendly or not.) However, there are significant problems with this, notably involving the safe storage of a highly-inflammable and explosive gas which is much lighter than air.

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It’s the stuff of Chemistry 101: carbon can only form four bonds because it only has four shareable electrons.

But this rule no longer applies, because scientists have confirmed the existence of an exotic carbon molecule that can form six bonds, meaning the most classic example of tetravalence in our high school chemistry textbooks now comes with a hefty caveat.

If all of this is kinda giving you conniptions, we’re right there with you.

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Very cool.

A few nanoscale adjustments may be all that is required to make graphene-nanotube junctions excel at transferring heat, according to Rice University scientists.

The Rice lab of theoretical physicist Boris Yakobson found that putting a cone-like “chimney” between the graphene and nanotube all but eliminates a barrier that blocks heat from escaping.

The research appears in the American Chemical Society’s Journal of Physical Chemistry C.

Continue reading “Nano-chimneys can cool circuits” | >

Scientists at The Rockefeller University have created the most detailed three-dimensional images to date of an important step in the process by which cells make the nano-machines responsible for producing all-important protein. The results, described December 15 in Science, are prompting the researchers to re-evaluate how they envision this early phase in the construction of ribosomes.

“The structure they determined, shown above, belongs to a particle formally called the “small subunit processome.” Before this particle can fulfill its destiny to become the smaller half of a complete ribosome, the RNA within it needs to be folded, tweaked, and cut.

“Initially, we thought of the small subunit processome as a product on an assembly line, with molecular workers arriving from outside, much like the robots that would put together a car. But that analogy no longer appears apt,” says senior author Sebastian Klinge, head of the Laboratory of Protein and Nucleic Acid Chemistry.

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Ukrainian scientist Vladislav Kiselev claims that he has developed a type of battery that can power gadgets like smartphones and even cars for up to 12 years, without having to be recharged.

Kiselev, a senior researcher at the Institute of Bioorganic Chemistry and Petrochemistry in Kiev, and professor at Ukraine’s National Academy of Sciences, unveiled his intriguing battery prototype during the 2016 edition of Sikorsky Challenge, a prestigious international competition for research projects. The matchbox-like device looks fairly unimpressive, but the Ukrainian scientist claims that it has been continuously powering electrical devices for a year and four months without a single recharge, and will continue to do so for the next 11 years. That’s because his “battery” produces energy instead of simply storing it.

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Move over, chemists. Thanks to proteins from Icelandic bacteria, scientists at Caltech have managed to coax microbes into making silicon-carbon bonds, a feat that until now has been achieved only by humans in the lab.

The findings, published last week in the journal Science, could open the door to new avenues in organic chemistry and drug development — and could help scientists investigate essential mysteries, such as whether life could be based on silicon instead of carbon on other planets.

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A team of researchers from the University of Manchester announced Monday they had taken a significant step forward in the creation of viable quantum computers. In a study published in the latest edition of the journal Chem, the researchers provided evidence that large molecules made of nickel and chromium could be used as qubits — the quantum computing equivalent of the bits used to store and process information in conventional computers.

According to the study, it is possible, at least in theory, to use molecular chemistry to connect these molecules, thereby creating several stable qubits that can then be used to create two-qubit logic gates.

“We have shown that the chemistry is achievable for bringing together two-qubit gates — the molecules can be made and the gates can be assembled,” lead author Richard Winpenny said in a statement. “The next step is to show that they work.”

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Quantum computing is about to get more complex. Researchers have evidence that large molecules made of nickel and chromium can store and process information in the same way bytes do for digital computers. The researchers present algorithms proving it’s possible to use supramolecular chemistry to connect “qubits,” the basic units for quantum information processing, in Chem on November 10. This approach would generate several kinds of stable qubits that could be connected together into structures called “two-qubit gates.”

“We have shown that the chemistry is achievable for bringing together two-qubit gates,” says senior author Richard Winpenny, Head of the University of Manchester School of Chemistry. “The molecules can be made and the two-qubit gates assembled. The next step is to show that these two-qubit gates work.”

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Scientists from the University of Basel have succeeded in organizing spherical compartments into clusters mimicking the way natural organelles would create complex structures. They managed to connect the synthetic compartments by creating bridges made of DNA between them. This represents an important step towards the realization of so-called molecular factories. The journal Nano Letters has published their results.

Within a cell there are specialized compartments called organelles, as for example nucleus, mitochondria, peroxisomes and vacuoles that are responsible for specific functions of the cell. Almost all sophisticated biological functions of cells are realized by self-organization, a process by which molecules adopt a defined arrangement based on their specific conformations and properties, without outside guidance.

Using self-organization of nano-objects into complex architectures is a major strategy to produce new materials with improved properties or functionalities in fields such as chemistry, electronics and technology. For example, this strategy has already been applied to create networks of inorganic solid nanoparticles. However, so far, these networks were not able to mimic sophisticated structures that have biological functions within the cells and thus have potential application in medicine or biology.

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