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Category: chemistry – Page 111

Over centuries of painstaking laboratory work, chemists have synthesized several hundred thousand inorganic compounds — generally speaking, materials not based on the chains of carbon atoms that are characteristic of organic chemistry. Yet studies suggest that billions of relatively simple inorganic materials are still waiting to be discovered3. So where to start looking?

Many projects have tried to cut down on time spent in the lab tinkering with various materials by computationally simulating new inorganic materials and calculating properties such as how their atoms would pack together in a crystal. These efforts — including the Materials Project based at the Lawrence Berkeley National Laboratory (LBNL) in Berkeley, California — have collectively come up with about 48,000 materials that they predict will be stable.

Google DeepMind has now supersized this approach with an AI system called graph networks for materials exploration (GNoME). After training on data scraped from the Materials Project and similar databases, GNoME tweaked the composition of known materials to come up with 2.2 million potential compounds. After calculating whether these materials would be stable, and predicting their crystal structures, the system produced a final tally of 381,000 new inorganic compounds to add to the Materials Project database1.

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Electrocatalysis expands the ability to generate industrially relevant chemicals locally and on-demand with intermittent renewable energy, thereby improving grid resiliency and reducing supply logistics. Herein, we report the feasibility of using molecular copper boron-imidazolate cages, BIF-29(Cu), to enable coupling between the electroreduction reaction of CO2 (CO2RR) with NO3– reduction (NO3RR) to produce urea with high selectivity of 68.5% and activity of 424 μA cm–2. Remarkably, BIF-29(Cu) is among the most selective systems for this multistep C–N coupling to-date, despite possessing isolated single-metal sites. The mechanism for C–N bond formation was probed with a combination of electrochemical analysis, in situ spectroscopy, and atomic-scale simulations. We found that NO3RR and CO2RR occur in tandem at separate copper sites with the most favorable C–N coupling pathway following the condensation between *CO and NH2OH to produce urea. This work highlights the utility of supramolecular metal–organic cages with atomically discrete active sites to enable highly efficient coupling reactions.

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A new electrocatalyst made of nickel (Ni), iron (Fe) and silicon (Si) that decreases the amount of energy required to synthesize H2 from water has been manufactured in a simple and cost-effective way, increasing the practicality of H2 as a clean and renewable energy of the future.

Hydrogen is a highly combustible gas that can help the world achieve its clean energy goals if manufactured in an environmentally responsible way. The primary hurdle to creating hydrogen gas from water is the large amount of energy required for the electrolysis of water, or splitting into hydrogen gas (H2) and oxygen (O2).

Most H2 produced today is derived from fossil fuels, which contributes to global warming. Manufacturing H2 from water through the (HER) requires the use of a catalyst, or agent that lowers the amount of energy required for a chemical reaction. Until recently, these catalysts were made up of , like platinum, reducing the cost-efficiency and practicality of clean hydrogen production.

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European astronomers, co-led by researchers from the Institute of Astronomy, KU Leuven, used recent observations made with the James Webb Space Telescope to study the atmosphere of the nearby exoplanet WASP-107b. Peering deep into the fluffy atmosphere of WASP-107b they discovered not only water vapour and sulfur dioxide, but even silicate sand clouds. These particles reside within a dynamic atmosphere that exhibits vigorous transport of material.

Astronomers worldwide are harnessing the advanced capabilities of the Mid-Infrared Instrument (MIRI) aboard the James Webb Space Telescope (JWST) to conduct groundbreaking observations of exoplanets – planets orbiting stars other than our own Sun. One of these fascinating worlds is WASP-107b, a unique gaseous exoplanet that orbits a star slightly cooler and less massive than our Sun. The mass of the planet is similar to that of Neptune but its size is much larger than that of Neptune, almost approaching the size of Jupiter. This characteristic renders WASP-107b rather ‘fluffy’ when compared to the gas giant planets within our solar system. The fluffiness of this exoplanet enables astronomers to look roughly 50 times deeper into its atmosphere compared to the depth of exploration achieved for a solar-system giant like Jupiter.

The team of European astronomers took full advantage of the remarkable fluffiness of this exoplanet, enabling them to look deep into its atmosphere. This opportunity opened a window into unravelling the complex chemical composition of its atmosphere. The reason behind this is quite straightforward: the signals, or spectral features, are far more prominent in a less dense atmosphere compared to a more compact one. Their recent study, now published in Nature, reveals the presence of water vapour, sulfur dioxide (SO2), and silicate clouds, but notably, there is no trace of the greenhouse gas methane (CH4).

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A research team led by Professor Sei Kwang Hahn and Dr. Tae Yeon Kim from the Department of Materials Science and Engineering at Pohang University of Science and Technology (POSTECH) used gold nanowires to develop an integrated wearable sensor device that effectively measures and processes two bio-signals simultaneously. Their research findings were featured in Advanced Materials.

Wearable devices, available in various forms like attachments and patches, play a pivotal role in detecting physical, chemical, and electrophysiological signals for disease diagnosis and management. Recent strides in research focus on devising wearables capable of measuring multiple bio-signals concurrently.

However, a major challenge has been the disparate materials needed for each signal measurement, leading to interface damage, complex fabrication, and reduced device stability. Additionally, these varied signal analyses require further signal processing systems and algorithms.

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A research team led by Prof. Chen Wei from the University of Science and Technology of China (USTC) of the Chinese Academy of Sciences (CAS) designed a rechargeable hydrogen-chlorine (H2-Cl2) battery that can operate in temperatures ranging from −70°C to 40°C. The study was published in Journal of the American Chemical Society as the cover article.

Hydrogen fuel cells are a promising technology valuable for their sustainability and the abundance of hydrogen, among which H2-Cl2 fuel cells stand out due to fast electrochemical kinetics, high redox potential and high specific capacity of Cl2/Cl- redox couple. However, the volatile chlorine gas cannot be retained during the charging process, resulting in poor Coulombic efficiency (CE) and reversibility. There is an urgent need to develop aqueous chlorine batteries with and applicability at different temperatures.

The research team first discovered that due to the lack of binding sites with strong affinity to Cl2, traditional adsorptive cathodes have difficulty immobilizing Cl2, causing low reversibility. To tackle this problem, the team designed a hierarchically porous carbon composed of highly micro-/mesoporous carbon (HPC) and macroporous carbon felt (CF), effectively confining the Cl2 on the cathode and improving the reversibility.

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The technique represents an important step in engineering skin grafts, drug testing. A team led by scientists at Rensselaer Polytechnic Institute has 3D-printed hair follicles in human skin tissue cultured in the lab. This marks the first time researchers have used the technology to generate hair follicles, which play an important role in skin healing and function.

The finding, published in the journal Science Advances, has potential applications in regenerative medicine and drug testing, though engineering skin grafts that grow hair are still several years away.

“Our work is a proof-of-concept that hair follicle structures can be created in a highly precise, reproducible way using 3D-bioprinting. This kind of automated process is needed to make future biomanufacturing of skin possible,” said Pankaj Karande, Ph.D., an associate professor of chemical and biological engineering and a member of Rensselaer’s Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies, who led the study.

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