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Category: chemistry – Page 110

Color-changing fluorescent dyes enable precise temperature measurements within living cells

Temperature is a critical variable that influences countless biological processes at the cellular level. However, precisely measuring temperatures within living cells remains challenging. Conventional temperature measurement techniques often lack the spatial resolution needed to detect subtle temperature variations in complex microscopic environments. Additionally, many existing molecular thermometers have significant limitations in terms of their sensitivity, resolution, and applicable targets, highlighting the need for innovative approaches and versatile tools.

Against this backdrop, a research team led by Associate Professor Gen-ichi Konishi from the Institute of Science Tokyo, Japan, has developed a molecular thermometer using a novel solvatochromic fluorescent dye. Their findings, published online in the Journal of the American Chemical Society on March 5, 2025, demonstrate that this new compound enables high-precision temperature measurements through changes in fluorescence properties.

The researchers designed a series of donor−π–acceptor (D−π–A) fluorophores based on a π-extended fluorene structure. These molecules are specially engineered to change their fluorescence properties in response to their surrounding environment’s polarity. When the temperature increases, the polarity of the solvent slightly decreases, which causes these dyes to emit light at different wavelengths and intensities.

Scientists Just Discovered a Shockingly Simple Formula for Quantum Entanglement

Physicists in Japan have developed streamlined formulas to measure quantum entanglement, revealing surprising quantum interactions in nanoscale.

The term “nanoscale” refers to dimensions that are measured in nanometers (nm), with one nanometer equaling one-billionth of a meter. This scale encompasses sizes from approximately 1 to 100 nanometers, where unique physical, chemical, and biological properties emerge that are not present in bulk materials. At the nanoscale, materials exhibit phenomena such as quantum effects and increased surface area to volume ratios, which can significantly alter their optical, electrical, and magnetic behaviors. These characteristics make nanoscale materials highly valuable for a wide range of applications, including electronics, medicine, and materials science.

Geysers on Saturn’s icy moon Enceladus may form from a ‘mushy zone’

Searching for life on other celestial bodies, or at the very least the necessary components to support it, has been fascinating scientists and enthusiasts for centuries. While planets are the obvious choice, their moons can also harbor the chemical ingredients for life.

Saturn is orbited by 146 moons, with Enceladus being the sixth largest at approximately 500km in diameter. This small, icy moon is characterized by its highly reflective white surface and geyser-like jets releasing ice and water vapor hundreds of kilometers into space from its south pole.

NASA’s Cassini spacecraft identified these jets in 2005, before going on to sample them in 2008, 2009 and 2015. Consequently, scientists found that the hot mineral-rich waters possess the necessary components for life, despite the moon’s surface reaching extreme temperatures of −201°C.

Serendipitous discovery reveals how stress and chemistry etch mysterious spiral patterns

UCLA doctoral student Yilin Wong noticed that some tiny dots had appeared on one of her samples, which had been accidentally left out overnight. The layered sample consisted of a germanium wafer topped with evaporated metal films in contact with a drop of water. On a whim, she looked at the dots under a microscope and couldn’t believe her eyes. Beautiful spiral patterns had been etched into the germanium surface by a chemical reaction.

Wong’s curiosity led her on a journey to discover what no one had seen before: Hundreds of near-identical spiral patterns can spontaneously form on a centimeter square germanium chip. Moreover, small changes in experiment parameters, such as the thickness of the metal film, generated different patterns, including Archimedean spirals, logarithmic spirals, lotus flower shapes, radially symmetric patterns and more.

The discovery, published in Physical Review Materials, occurred fortuitously when Wong made a small mistake while attempting to bind DNA to the metal film.

Artificial photosynthesis converts organic waste into useful pharmaceuticals and energy

A research team led by Assistant Professor Shogo Mori and Professor Susumu Saito at Nagoya University has developed a method of artificial photosynthesis that uses sunlight and water to produce energy and valuable organic compounds, including pharmaceutical materials, from waste organic compounds. This achievement represents a significant step toward sustainable energy and chemical production.

The findings were published in Nature Communications.

“Artificial photosynthesis involves that mimic the way plants convert sunlight, water, and carbon dioxide into energy-rich glucose,” Saito explained. “Waste products, which are often produced by other processes, were not formed; instead, only energy and useful chemicals were created.”

Artificial enzyme splits water more efficiently

Mankind is facing a central challenge: It must manage the transition to a sustainable and carbon dioxide-neutral energy economy.

Hydrogen is considered a promising alternative to fossil fuels. It can be produced from water using electricity. If the electricity comes from , it is called green . But it would be even more sustainable if hydrogen could be produced directly with the energy of sunlight.

In nature, light-driven water splitting takes place during photosynthesis in plants. Plants use a complex molecular apparatus for this, the so-called photosystem II. Mimicking its active center is a promising strategy for realizing the sustainable production of hydrogen. A team led by Professor Frank Würthner at the Institute of Organic Chemistry and the Center for Nanosystems Chemistry at Julius-Maximilians-Universität Würzburg (JMU) is working on this.

Discarding a long-standing pessimistic hypothesis to rescue next-generation lithium-ion battery technology

In a megascience-scale collaboration with French researchers from College de France and the University of Montpellier, Skoltech scientists have shown a much-publicized problem with next-generation lithium-ion batteries to have been induced by the very experiments that sought to investigate it. Published in Nature Materials, the team’s findings suggest that the issue of lithium-rich cathode material deterioration should be approached from a different angle, giving hope for more efficient lithium-ion batteries that would store some 30% more energy.

Efficient energy storage is critical for the transition to a low-carbon economy, whether in grid-scale applications, electric vehicles, or portable devices. Lithium-ion batteries remain the best-developed electrochemical storage technology and promise further improvements. In particular, next-generation batteries with so-called lithium-rich cathodes could store about one-third more energy than their state-of-the-art counterparts with cathodes made of lithium nickel manganese cobalt oxide, or NMC.

A key challenge hindering the commercialization of lithium-rich batteries is voltage fade and capacity drop. As the battery is repeatedly charged and discharged in the course of normal use, its cathode material undergoes degradation of unclear nature, causing gradual voltage and capacity loss. The problem is known to be associated with the reduction and oxidation of the in NMC, but the precise nature of this redox process is not understood. This theoretical gap undermines the attempts to overcome voltage fade and bring next-generation batteries to the market.

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