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A new machine learning approach offers important insights into catalysis, a fundamental process that makes it possible to reduce the emission of toxic exhaust gases or produce essential materials like fabric.

In a report published in Nature Communications, Hongliang Xin, associate professor of chemical engineering at Virginia Tech, and his team of researchers developed a Bayesian learning model of chemisorption, or Bayeschem for short, aiming to use artificial intelligence to unlock the nature of chemical bonding at catalyst surfaces.

“It all comes down to how catalysts bind with molecules,” said Xin. “The interaction has to be strong enough to break some chemical bonds at reasonably low temperatures, but not too strong that catalysts would be poisoned by reaction intermediates. This rule is known as the Sabatier principle in catalysis.”

**Peroxisomes are compartments where cells turn fatty molecules into energy and useful materials, like the myelin sheaths that protect nerve cells. In humans, peroxisome dysfunction has been linked to severe metabolic disorders, and peroxisomes may have wider significance for neurodegeneration, obesity, cancer and age-related disorders.**

Peroxisomes are also highly conserved, from plants to yeast to humans, and Bartel said there are hints that these structures may be general features of peroxisomes.

“Peroxisomes are a basic organelle that has been with eukaryotes for a very long time, and there have been observations across eukaryotes, often in particular mutants, where the peroxisomes are either bigger or less packed with proteins, and thus easier to visualize,” she said. But people didn’t necessarily pay attention to those observations because the enlarged peroxisomes resulted from known mutations.

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Exploring the frontiers of neuromodulation, neurostimulation, and neural interfaces.

Neuromodulation is defined as “the alteration of nerve activity through targeted delivery of a stimulus, such as electrical stimulation or chemical agents, to specific neurological sites in the body”. It is carried out to normalize – or modulate – nervous tissue function.

Continue reading “Dr. Amilcar dos Santos MD — Exploring Far Frontiers of Neural, Spinal, and Brain-Computer Interfaces” »

Maybe you’ve felt a certain chemistry with 2019 but don’t know why? Maybe it’s because this year marks the 150th anniversary of the Periodic Table of the Elements. It’s considered the founding document of modern chemistry, one you may have studied in school.

UW-Madison professor of chemistry Bassam Shakhashiri knows both the history of the table, and its modern relevance. He says the table came about through a collaboration of a few scientists but that Dmitri Mendeleev properly gets much of the credit.

“Dimitri Mendeleev, the Russian chemist, he proposed — sometimes people say he discovered — the pattern of similar behavior [of certain elements] and arranged them,” Shakhashiri explains.

Don’t worry, they aren’t immune to a good slipper…for now.

The rise of the superbug cockroach is upon us. A new study has found that German cockroaches (Blattella germanica) are rapidly evolving to become resistant to many widely used bug sprays and insecticides, as well as chemicals they’ve never been directly exposed to, making them near-impossible to eliminate and one step closer to taking over the world.

Remarkably, the study published in Scientific Reports revealed these scuttling pests could even develop resistance within a single generation. Others also developed cross-resistance, meaning they gained a tolerance to a usually toxic substance just through contact with a similar type of insecticide.

Continue reading “Cockroaches Are Rapidly Evolving To Become ‘Almost Impossible’ To Kill” »

Warrior for our planet!

Commissioner Virginijus Sinkevicius:

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There are several ways to generate power from that mixing. And a couple of blue energy power plants have been built. But their high cost has prevented widespread adoption. All blue energy approaches rely on the fact that salts are composed of ions, or chemicals that harbor a positive or negative charge. In solids, the positive and negative charges attract one another, binding the ions together. (Table salt, for example, is a compound made from positively charged sodium ions bound to negatively charged chloride ions.) In water, these ions detach and can move independently.

By pumping the positive ions—like sodium or potassium—to the other side of a semipermeable membrane, researchers can create two pools of water: one with a positive charge, and one with a negative charge. If they then dunk electrodes in the pools and connect them with a wire, electrons will flow from the negatively charged to the positively charged side, generating electricity.

In 2013, French researchers made just such a membrane. They used a ceramic film of silicon nitride—commonly used in industry for electronics, cutting tools, and other uses—pierced by a single pore lined with a boron nitride nanotube (BNNT), a material being investigated for use in high-strength composites, among other things. Because BNNTs are highly negatively charged, the French team suspected they would prevent negatively charged ions in water from passing through the membrane (because similar electric charges repel one another). Their hunch was right. They found that when a membrane with a single BNNT was placed between fresh- and saltwater, the positive ions zipped from the salty side to the fresh side, but the negatively charged ions were mostly blocked.

The oxygen evolution reaction (OER) is a chemical process that leads to the generation of molecular oxygen. This reaction is of key importance for the development of clean energy technologies, including water electrolyzers, regenerative fuel cells and rechargeable metal-air batteries.

The extent to which this reaction occurs has so far been limited in many materials, which has restricted the conversion efficiency of some types of energy technologies. Materials scientists have thus been trying to identify alternative materials, including metals, metal oxides and hydroxides, that could be used as electrocatalysts to fuel this reaction. The materials identified so far, however, are far from ideal for large-scale implementation, as they are either not particularly resistant or too expensive.

A class of materials widely investigated as possible electrocatalysts for the OER are metal-organic frameworks (MOFs), hybrid and crystalline compounds that consist of a regular array of positively charged metal ions surrounded by organic molecules. While these materials have promising catalytic properties, scientists have yet to identify optimal strategies to enhance their performance.

Researchers identify Brown-Zak fermions in superlattices made from the carbon sheet.

Researchers at the University of Manchester in the UK have identified a new family of quasiparticles in superlattices made from graphene sandwiched between two slabs of boron nitride. The work is important for fundamental studies of condensed-matter physics and could also lead to the development of improved transistors capable of operating at higher frequencies.

In recent years, physicists and materials scientists have been studying ways to use the weak (van der Waals) coupling between atomically thin layers of different crystals to create new materials in which electronic properties can be manipulated without chemical doping. The most famous example is graphene (a sheet of carbon just one atom thick) encapsulated between another 2D material, hexagonal boron nitride (hBN), which has a similar lattice constant. Since both materials also have similar hexagonal structures, regular moiré patterns (or “superlattices”) form when the two lattices are overlaid.

Continue reading “New family of quasiparticles appears in graphene” »