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Category: chemistry – Page 2

Harnessing moisture from air, Northwestern University chemists have developed a simple new method for breaking down plastic waste.

The non-toxic, environmentally friendly, solvent-free process first uses an inexpensive catalyst to break apart the bonds in polyethylene terephthalate (PET), the most common plastic in the polyester family. Then, the researchers merely expose the broken pieces to ambient air. Leveraging the trace amounts of moisture in air, the broken-down PET is converted into monomers—the crucial building blocks for plastics. From there, the researchers envision the monomers could be recycled into new PET products or other, more valuable materials.

Safer, cleaner, cheaper and more sustainable than current plastic recycling methods, the new technique offers a promising path toward creating a circular economy for plastics. The study was recently published in Green Chemistry.

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Unlike conventional silicon-based solar cells, perovskite solar cells (PSCs) are not only thin and lightweight, but can also be seamlessly applied to curved surfaces, like building facades and vehicle roofs. What’s more, they can be easily manufactured at room temperature using a solution process, leading to significantly reduced production costs.

However, for PSCs to achieve commercialization, it is crucial to develop technologies that maintain high efficiency over extended periods. A research team affiliated with UNIST has successfully made strides in this area. Their work is published in the journal Joule.

Professor Sang Il Seok of the School of Energy and Chemical Engineering at UNIST, along with researchers Jongbeom Kim and Jaewang Park, has developed an interlayer that leverages the specificity of organic cations on the surface of PSCs, simultaneously achieving and durability.

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People breathing contaminated air over the course of years are at greater risk of developing numerous diseases. This is thought to be due to highly reactive components in particulate matter, which affect biological processes in the body. However, researchers from the University of Basel, Switzerland, have now shown that precisely these components disappear within hours and that previous measurements therefore completely underestimate the quantities in which they are present.

From chronic respiratory problems to cardiovascular diseases, diabetes and dementia, health damage caused by air pollution is wide-ranging and serious. The World Health Organization (WHO) estimates that over six million deaths a year are caused by increased exposure to particulate matter.

The chemical composition of these tiny particles in the air, which come from a wide range of both anthropogenic and natural sources, is highly complex. Which particles trigger which reactions and long-term diseases in the body is the subject of intensive research.

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The interactions between light and nitroaromatic hydrocarbon molecules have important implications for chemical processes in our atmosphere that can lead to smog and pollution. However, changes in molecular geometry due to interactions with light can be very difficult to measure because they occur at sub-Angstrom length scales (less than a tenth of a billionth of a meter) and femtosecond time scales (one millionth of a billionth of a second).

The relativistic ultrafast electron diffraction (UED) instrument at the Linac Coherent Light Source (LCLS) at SLAC National Accelerator Laboratory provides the necessary spatial and time resolution to observe these ultrasmall and ultrafast motions. The LCLS is a Department of Energy (DOE) Office of Science light source user facility.

In this research, scientists used UED to observe the relaxation of photoexcited o–nitrophenol. Then, they used a genetic structure fitting algorithm to extract new information about small changes in the molecular shape from the UED data that were imperceptible in previous studies. Specifically, the experiment resolved the key processes in the relaxation of o-nitrophenol: proton transfer and deplanarization (i.e., a rotation of part of the molecule out of the molecular plane). Ab-initio multiple spawning simulations confirmed the experimental findings. The results provide new insights into proton transfer-mediated relaxation and pave the way for studies of proton transfer in more complex systems.

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Lithium-ion batteries are part of everyday life. They power small rechargeable devices such as mobile phones and laptops. They enable electric vehicles. And larger versions store excess renewable energy for later use, supporting the clean energy transition.

Australia produces more than 3,000 metric tons of lithium-ion battery a year. Managing this waste is a technical, economic and social challenge. Opportunities exist for and creating a circular economy for batteries. But they come with risk.

That’s because contain manufactured chemicals such as PFAS, or per-and polyfluoroalkyl substances. The chemicals carry the lithium—along with electricity—through the battery. If released into the environment, they can linger for decades and likely longer. This is why they’ve been dubbed “forever chemicals”

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This study builds on observations first made in 1983, which sparked debates and further research into plant communication.

Over the years, scientists have uncovered various ways plants interact, from chemical signals to underground networks formed by fungi.

“We have finally unveiled the intricate story of when, where, and how plants respond to airborne ‘warning messages’ from their threatened neighbors,” Dr. Toyota emphasized.

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A major breakthrough in liquid catalysis is transforming how essential products are made, making the chemical manufacturing process faster, safer and more sustainable than ever before.

Researchers from Monash University, the University of Sydney, and RMIT University have developed a liquid that could transform chemical production across a range of industries—from pharmaceuticals and sustainable products to advanced materials.

By dissolving palladium in liquid gallium the team, led by Associate Professor Md. Arifur Rahim from Monash University’s Department of Chemical and Biological Engineering, created a self-regenerating catalytic system with unprecedented efficiency.

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Chibueze Amanchukwu wants to fix batteries that haven’t been built yet. Demand for batteries is on the rise for EVs and the grid-level energy storage needed to transition Earth off fossil fuels. But more batteries will mean more of a dangerous suite of materials used to build them: PFAS, also known as “forever chemicals.”

“To address our needs as a society for electric vehicles and energy storage, we are coming up with more ,” said Amanchukwu, Neubauer Family Assistant Professor of Molecular Engineering in the UChicago Pritzker School of Molecular Engineering (UChicago PME). “You can see the dilemma.”

PFAS are a family of thousands of chemicals found in batteries but also everything from fast food wrappers and shampoo to firefighting foam and yoga pants. They keep scrambled eggs from sticking to pans and rain from soaking into jackets and paint, but the same water resistance that makes them useful also make them difficult to remove when they get into the water supply. This earned them the nickname “forever chemicals.”

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Why would anyone need this level of wavelength detail in an image? There are many reasons. Car manufacturers want to predict exactly how paint will look under different lighting. Scientists use spectral imaging to identify materials by their unique light signatures. And rendering specialists need it to accurately simulate real-world optical effects like dispersion (rainbows from prisms, for example) and fluorescence.

For instance, past Ars Technica coverage has highlighted how astronomers analyzed spectral emission lines from a gamma-ray burst to identify chemicals in the explosion, how physicists reconstructed original colors in pioneering 19th century photographs, and how multispectral imaging revealed hidden, centuries-old text and annotations on medieval manuscripts like the Voynich Manuscript, sometimes even uncovering the identities of past readers or scribes through faint surface etchings.

The current standard format for storing this kind of data, OpenEXR, wasn’t designed with these massive spectral requirements in mind. Even with built-in lossless compression methods like ZIP, the files remain unwieldy for practical work as these methods struggle with the large number of spectral channels.

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