Muon spin rotation (µSR) spectroscopy is a powerful technique that helps to study the behavior of materials at the atomic level. It involves using muons—subatomic particles similar to protons but with a lighter mass. When introduced into a material, muons interact with local magnetic fields, providing unique insights into the material’s structure and dynamics, especially for highly reactive species such as radicals.
In a new study, a team of researchers led by Associate Professor Shigekazu Ito, from the School of Materials and Chemical Technology, Institute of Science Tokyo, Japan, utilized µSR spectroscopy to investigate the regioselective muoniation of peri-trifluoromethylated 12-phosphatetraphene 1. This compound is a phosphorus congener (a variant of a common chemical structure).
The process of µSR spectroscopy initially involves the formation of a muonium (Mu), which is formed when a positively charged muon (µ+) captures an electron (e–). This process continues as the reaction of a muonium (Mu = [µ+e–]) with the phosphorus-containing compound, resulting in the formation of a muoniated radical at the phosphorus site.