In the tug-of-war between order and chaos within multielemental carbides, entropy eventually claims victory over enthalpy by pushing the system toward complete disorder as the diversity of elements in the material increases, as revealed in a study published in Science.
Researchers synthesized 40 layered carbide phases with composition MAlX materials (M is a transition metal, Al is for aluminum, and X is either C or N), where the number of M was between 2 and 9.
Their goal was to uncover the trends in short-range ordering and compositional disorder in so-called high–entropy systems. They found that in carbides with fewer constituent elements, short-range order driven by enthalpy dominated. However, as the number of elements increased, entropy took control, randomizing the metal configurations.