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Category: chemistry – Page 63

Study reveals controlled proton tunneling in water trimers

A research team led by Professor Hyung-Joon Shin from the Department of Materials Science and Engineering at UNIST has succeeded in elucidating the quantum phenomenon occurring within a triangular cluster of three water molecules. The work is published in the journal Nano Letters.

Their findings demonstrate that the collective rotational motion of water molecules enhances proton tunneling, a quantum mechanical effect where protons (H+) bypass energy barriers instead of overcoming them. This phenomenon has implications for and the stability of biomolecules such as DNA.

The study reveals that when the rotational motion of water molecules is activated, the distances between the molecules adjust, resulting in increased cooperativity and facilitating proton tunneling. This process allows the three protons from the water molecules to collectively surmount the energy barrier.

Artificial nerve with organic transistor design shows promise for brain-machine interfaces

In recent years, many engineers have been trying to develop hardware components that could emulate the functions of various biological systems, including synapses, the human skin and nerves. These bio-inspired systems include what are referred to as artificial nerves, systems designed to emulate the role of nerves in the body of humans and other animals.

Artificial nerves could be useful for a wide range of applications, ranging from systems for repairing damaged nerves to brain-computer interfaces, highly precise sensors and other advanced electronics. So far, however, the engineering of nerve-inspired systems that operate at biologically compatible frequencies and realistically replicate the function of nerves has proved challenging.

Researchers at Xi’an Jiaotong University in China and Technical University of Munich recently developed a new high-frequency artificial nerve with a unique design that optimizes the transport of ions and electrons, while also rapidly responding to signals and retaining charge-related information. This nerve-inspired system, introduced in a paper published in Nature Electronics, is based on homogenously integrated organic electrochemical transistors.

Gemini South Observes Ultra-Hot Nova Erupting With Surprising Chemical Signature

Astronomers uncover extremely hot and violent eruption from first ever near-infrared analysis of a recurrent nova outside of the Milky Way Galaxy. Using the Gemini South telescope, one half of the International Gemini Observatory, partly funded by the U.S. National Science Foundation and operated by NSF NOIRLab, and the Magellan Baade Telescope, astronomers have for the first time observed a recurring nova outside of the Milky Way in near-infrared light. The data revealed highly unusual chemical emissions as well as one of the hottest temperatures ever reported for a nova, both indicative of an extremely violent eruption.

Nova explosions occur in binary star systems in which a white dwarf — the dense remnant of a dead star — continually siphons stellar material from a nearby companion star. As the outer atmosphere of the companion gathers onto the surface of the white dwarf it reaches temperatures hot enough to spark an eruption.

Almost all novae discovered to-date have been observed to erupt only once. But a few have been observed to erupt more than once, and are classified as recurrent novae. The span between eruptions for these novae can vary from as little as one year to many decades [1].

Carbon-negative construction: New method turns CO₂ into strong, fire-resistant building materials

A new method inspired by coral reefs can capture carbon dioxide from the atmosphere and transform it into durable, fire-resistant building materials, offering a promising solution for carbon-negative construction.

The approach, developed by USC researchers and detailed in a study published in npj Advanced Manufacturing, draws inspiration from the ocean’s ’ natural ability to create robust structures by sequestering carbon dioxide. The resulting mineral-polymer composites demonstrate extraordinary mechanical strength, fracture toughness and fire-resistance capabilities.

“This is a pivotal step in the evolution of converting carbon dioxide,” said Qiming Wang, associate professor of civil and environmental engineering at the USC Viterbi School of Engineering. “Unlike traditional technologies that focus on storing carbon dioxide or converting it into liquid substances, we found this new electrochemical manufacturing process converts the chemical compound into calcium carbonate minerals in 3D-printed polymer scaffolds.”

Researchers pioneer groundbreaking light-driven method to create key drug compounds

Researchers at Indiana University and Wuhan University in China have unveiled a groundbreaking chemical process that could streamline the development of pharmaceutical compounds, chemical building blocks that influence how drugs interact with the body. Their study, published in Chem, describes a novel light-driven reaction that efficiently produces tetrahydroisoquinolines, a group of chemicals that play a crucial role in medicinal chemistry.

Tetrahydroisoquinolines serve as the foundation for treatments targeting Parkinson’s disease, cancer, and cardiovascular disorders. These compounds are commonly found in medications such as painkillers and drugs for , as well as in natural sources like certain plants and marine organisms.

Traditionally, chemists have relied on well-established but limiting methods to synthesize these . The new research, co-authored by Kevin Brown, the James F. Jackson Professor of Chemistry in the College of Arts and Sciences at Indiana University Bloomington, and Professors Xiaotian Qi, Wang Wang, and Bodi Zhao of Wuhan University, presents a fundamentally different approach.

Eco-friendly detergent made from wood and corn shows promise

From laundry detergent to dishwasher tablets, cleaning products are an indispensable part of life. Yet the chemicals that make these products so effective can be difficult to break down or could even trigger ecosystem-altering algal blooms. Now, researchers reporting in ACS’ Langmuir have addressed those challenges with an environmentally compatible detergent made of tiny wood fibers and corn protein that removes stains on clothes and dishes just as well as commercial products.

Increased about household products’ impact on the environment has spurred interest in replacing traditional cleaners containing ingredients such as alkylphenol polyethoxylates and phosphates with natural alternatives. Efforts to date have produced mixed results because these cleaners are difficult to make and hard to rinse off, resulting in high manufacturing and retail costs, as well as potential damage to surfaces and fabrics. Therefore, there is a desire for low-cost, easily produced, effective alternatives that are gentle on the environment and the items they are designed to clean. To address this need, Pengtao Liu and colleagues developed an eco-friendly detergent from ingredients found in abundant renewable sources.

The researchers combined from wood with zein protein from corn to create an emulsion. Cellulose can attract and repel water, so it is effective at forming such emulsions and attracting different types of stains. The zein protein, on the other hand, helps stabilize the emulsion and trap oils. Liu and colleagues then tested the cleaning capacity of the cellulose/zein detergent on cotton fabrics and dishes stained with ink, chili oil and tomato paste. They compared the performance of their new detergent to laundry powder and commercial dish soap solutions with deionized water.

Innovative technology enables rapid thin film manufacturing in one minute using only water and oil

A new technology has been developed that enables the manufacturing of thin films, which typically require complex processes, using only water and oil in just one minute. Professor Kang Hee Ku and her research team from the School of Energy and Chemical Engineering at UNIST announced their novel process for creating catalytic thin films using oil droplets dispersed in water.

The developed technology involves a process in which nanomaterial precursors attached to the surface of oil droplets float to the surface of the water, where they assemble into a thin film. When is added, it decomposes due to the thin film precursors, producing gas bubbles that cause the precursors to be lifted and assembled on the water surface within one minute.

This process allows for precise control of the thin film thickness, adjustable from 350 μm, and enables the synthesis of thin films covering an area of up to 100 cm² using various raw materials. The resulting thin films exhibit a porous structure with a , featuring exceptional mechanical strength and flexibility.

Biodiesel wastewater treatment: Capturing carbon and valuable chemicals

While biodiesel provides a cleaner-burning alternative to petroleum diesel, it produces CO2 and hazardous wastewater during manufacturing, requiring extra steps to achieve sustainability. A diagnostic study led by University of Michigan researchers works to improve a process that captures CO2 while treating biodiesel wastewater and produces valuable co-products like fuels and green chemicals.

During biodiesel production, fats—like , or recycled restaurant grease—are transformed into fuel through a process called transesterification. With the help of a , an alcohol (typically methanol) breaks the bonds in the fat molecules to create glycerol and long, chain-like molecules called fatty acid esters.

The fatty acid esters, which resemble petroleum diesel’s molecular structure, become biodiesel while the glycerol goes into the wastewater as a byproduct. If left untreated, glycerol can pollute natural water resources by depleting , suffocating fish and other organisms.

High-pressure method can differentiate proton-coupled electron transfer mechanisms

Redox reactions form the basis of many fundamental processes of life. Without them, neither cellular respiration nor photosynthesis could take place. Redox reactions also play a crucial role in applications in the domains of chemistry, biochemistry, and the use of light for energy generation. Understanding the fundamental principles of these reactions is therefore important for driving forward new technologies.

Using an innovative method based on high pressures, a team led by LMU chemist Professor Ivana Ivanović-Burmazović and Professor Dirk Guldi from FAU Erlangen-Nürnberg has managed for the first time to differentiate two related reaction mechanisms. The research is published in the journal Nature Chemistry.

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