Lifeboat Foundation: Safeguarding Humanity
Toggle light / dark theme

Blog

Category: chemistry – Page 59

Dr. Marcia McNutt — President, National Academy of Sciences — Shaping Culture & Conduct Of Science

Shaping The Culture & Conduct Of Science — Dr. Marcia McNutt Ph.D. — President, National Academy Of Sciences

Dr. Marcia McNutt, Ph.D. is President of the National Academy of Sciences (https://www.nasonline.org/directory-e…), where she also chairs the National Research Council, the operating arm of the National Academies of Sciences, Engineering, and Medicine, and serves a key role in advising our nation on various important issues pertaining to science, technology, and health.

From 2013 to 2016, Dr. McNutt served as editor-in-chief of the Science journals.

Dr. McNutt is a geophysicist who prior to joining Science, was director of the U.S. Geological Survey (USGS) and science adviser to the United States Secretary of the Interior from from 2009 to 2013. During her tenure, the USGS responded to a number of major disasters, including earthquakes in Haiti, Chile, and Japan, and the Deepwater Horizon oil spill.

Dr. McNutt led a team of government scientists and engineers at BP headquarters in Houston who helped contain the oil and cap the well. She directed the flow rate technical group that estimated the rate of oil discharge during the spill’s active phase. For her contributions, she was awarded the U.S. Coast Guard’s Meritorious Service Medal.

Continue reading “Dr. Marcia McNutt — President, National Academy of Sciences — Shaping Culture & Conduct Of Science” | >

Decoding 2D material growth: White graphene insights open doors to cleaner energy and more efficient electronics

A breakthrough in decoding the growth process of hexagonal boron nitride (hBN), a 2D material, and its nanostructures on metal substrates could pave the way for more efficient electronics, cleaner energy solutions and greener chemical manufacturing, according to new research from the University of Surrey published in the journal Small.

Only one atom thick, hBN—often nicknamed “white graphene”—is an ultra-thin, super-resilient material that blocks electrical currents, withstands extreme temperatures and resists chemical damage. Its unique versatility makes it an invaluable component in , where it can protect delicate microchips and enable the development of faster, more efficient transistors.

Going a step further, researchers have also demonstrated the formation of nanoporous hBN, a novel material with structured voids that allows for selective absorption, advanced catalysis and enhanced functionality, vastly expanding its potential environmental applications. This includes sensing and filtering pollutants—as well as enhancing advanced energy systems, including hydrogen storage and electrochemical catalysts for fuel cells.

Proximity effect enables non-ferroelectric materials to gain new properties

Ferroelectrics are special materials with polarized positive and negative charges—like a magnet has north and south poles—that can be reversed when external electricity is applied. The materials will remain in these reversed states until more power is applied, making them useful for data storage and wireless communication applications.

Now, turning a non-ferroelectric material into one may be possible simply by stacking it with another ferroelectric material, according to a team led by scientists from Penn State who demonstrated the phenomenon, called proximity ferroelectricity.

The discovery offers a new way to make without modifying their chemical formulation, which commonly degrades several useful properties. This has implications for next-generation processors, optoelectronics and quantum computing, the scientists said. The researchers published their findings in the journal Nature.

How a single nitrogen atom could transform the future of drug discovery

Researchers at the University of Oklahoma have developed a breakthrough method of adding a single nitrogen atom to molecules, unlocking new possibilities in drug research and development. Now published in the journal Science, this research is already gaining international attention from drug manufacturers.

Nitrogen atoms and nitrogen-containing chemical structures, called heterocycles, play a pivotal role in medicinal chemistry and . A team led by OU associate professor Indrajeet Sharma has demonstrated that by using a short-lived chemical called sulfenylnitrene, researchers can insert one nitrogen atom into bioactive molecules and transform them into new pharmacophores that are useful for making drugs.

This process is called skeletal editing and takes inspiration from Sir Derek Barton, the recipient of the 1969 Nobel Prize in Chemistry.

Polymer-based network gives artificial cells a life-like cytoskeleton

Just like your body has a skeleton, every cell in your body has a skeleton—a cytoskeleton to be precise. This provides cells with mechanical resilience, as well as assisting with cell division. To understand how real cells work, e.g. for drug and disease research, researchers create artificial cells in the laboratory.

However, many artificial cells to date cannot be used to study how cells respond to forces as they don’t have a . TU/e researchers have designed a polymer-based network for artificial cells that mimics a real cytoskeleton, thus making it possible to study with greater accuracy in artificial cells how cells respond to forces.

The research is published in the journal Nature Chemistry.

Jellyfish Protein Shines Bright in Quantum Sensor for Biomedical Applications

While most of us are familiar with magnets from childhood games of marveling at the power of their repulsion or attraction, fewer realize the magnetic fields that surround us—and the ones inside us. Magnetic fields are not just external curiosities; they play essential roles in our bodies and beyond, influencing biological processes and technological systems alike. A recent arXiv publication from the University of Chicago’s Pritzker School of Molecular Engineering and Argonne National Laboratory highlights how magnetic fields in the body may be analyzed using quantum-enabled fluorescent proteins, with hopes of applying to cell formation or early disease detection.

Detecting subtle changes in magnetic fields may equate to beyond subtle impacts in certain fields. For instance, quantum sensors could be applied to the detection of electromagnetic anomalies in data centers, potentially revealing evidence of malicious tampering. Similarly, they might be used to study changes in the brain’s electromagnetic signals, offering insights into neurological diseases such as the onset of dementia. However, these applications demand sensors that are not only sensitive but also capable of operating reliably in real-world conditions.

Spin qubits, known for their notable sensitivity to magnetic fields, are introduced in the study as a compelling solution. Traditionally, spin qubits have been formed from nitrogen-vacancy centers in diamonds. While these systems have demonstrated remarkable precision, the diamonds’ bulky size in relation to molecules and complex surface chemistry limit their usability in biological environments. This creates a need for a more adaptable and biologically compatible sensor.

Scientists identify 11 genes affected by PFAS, shedding light on neurotoxicity

Per-and polyfluorinated alkyl substances (PFAS) earn their “forever chemical” moniker by persisting in water, soil and even the human brain. This unique ability to cross the blood-brain barrier and accumulate in brain tissue makes PFAS particularly concerning, but the underlying mechanism of their neurotoxicity must be studied further.

To that end, a new study by University at Buffalo researchers has identified 11 genes that may hold the key to understanding the brain’s response to these pervasive chemicals commonly found in everyday items. The paper is published in the journal ACS Chemical Neuroscience.

These genes, some involved in processes vital for neuronal health, were found to be consistently affected by PFAS exposure, either expressing more or less, regardless of the type of PFAS compounds tested. For example, all compounds caused a gene key for neuronal cell survival to express less, and another gene linked to neuronal cell death to express more.

Unlocking the Potential of Platinum: New Catalyst Enhances CO2 Reduction Efficiency

A new study uncovers a molecular modification method for converting CO2 into valuable chemical resources using a platinum surface.

Copper-based (Cu) materials are widely recognized for their efficiency in converting CO2 into valuable hydrocarbons via the CO2 reduction reaction (CO2RR). However, their stability, particularly in acidic environments, needs significant improvement. In contrast, metallic platinum (Pt) demonstrates excellent stability under both acidic and alkaline conditions. However, its high activity in the hydrogen evolution reaction (HER) hinders its effectiveness in CO2RR applications.

To address these challenges, composite materials incorporating metal-doped molecules offer a promising solution. These modified molecules can be securely retained at the interface, forming a unique structure that enhances the metal interface properties. This configuration not only increases the contact between reactants and active sites but also optimizes the adsorption strength of critical intermediates, ultimately improving catalytic performance.

This Water-Resistant Paper Could Revolutionize Packaging and Replace Plastic

A groundbreaking study showcases the creation of sustainable hydrophobic paper, enhanced by cellulose nanofibres and peptides, presenting a biodegradable alternative to petroleum-based materials, with potential uses in packaging and biomedical devices.

Researchers aimed to develop hydrophobic paper by leveraging the strength and water resistance of cellulose nanofibers, creating a sustainable, high-performance material suitable for packaging and biomedical applications. This innovative approach involved integrating short protein chains, known as peptide sequences, without chemically altering the cellulose nanofibers. The result is a potential alternative to petroleum-based materials, with significant environmental benefits.

The study, titled “Nanocellulose-short peptide self-assembly for improved mechanical strength and barrier performance,” was recently featured on the cover of the Journal of Materials Chemistry B. The research was conducted by the “Giulio Natta” Department of Chemistry, Materials, and Chemical Engineering at Politecnico di Milano, in collaboration with Aalto University, the VTT-Technical Research Centre of Finland, and the SCITEC Institute of the CNR.

Building blocks of life can form long before stars

Early Formation of Life’s Building Blocks

A groundbreaking study published in Nature Astronomy has revealed that amino acids, essential for life, can form in dark interstellar clouds long before stars and planets emerge. Glycine, the simplest amino acid, was shown to form on the surface of icy dust grains in cold, energy-deprived environments through a process called “dark chemistry.” These findings challenge the long-standing belief that UV radiation was required to create glycine, significantly expanding our understanding of how life’s precursors emerge in space.