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Category: chemistry – Page 227

This article reports a highly integrated watch for noninvasive continual blood glucose monitoring. The watch employs a Nafion-coated flexible electrochemical sensor patch fixed on the watchband to obtain interstitial fluid (ISF) transdermally at the wrist. This reverse iontophoresis-based extraction method eliminates the pain and inconvenience that traditional fingerstick blood tests pose in diabetic patients’ lives, making continual blood glucose monitoring practical and easy. All electronic modules, including a rechargeable power source and other modules for signal processing and wireless transmission, are integrated onto a watch face-sized printed circuit board (PCB), enabling comfortable wearing of this continual glucose monitor. Real-time blood glucose levels are displayed on the LED screen of the watch and can also be checked with the smartphone user interface.

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Scientists from the Dutch Institute for Fundamental Energy Research (DIFFER) have created a database of 31,618 molecules that could potentially be used in future redox-flow batteries. These batteries hold great promise for energy storage. Among other things, the researchers used artificial intelligence and supercomputers to identify the molecules’ properties. Today, they publish their findings in the journal Scientific Data.

In recent years, chemists have designed hundreds of molecules that could potentially be useful in flow batteries for energy storage. It would be wonderful, researchers from DIFFER in Eindhoven (the Netherlands) imagined, if the properties of these molecules were quickly and easily accessible in a database. The problem, however, is that for many molecules the properties are not known. Examples of molecular properties are redox potential and water solubility. Those are important since they are related to the power generation capability and energy density of redox flow batteries.

To find out the still-unknown properties of molecules, the researchers performed four steps. First, they used a and smart algorithms to create thousands of virtual variants of two types of molecules. These molecule families, the quinones and aza aromatics, are good at reversibly accepting and donating electrons. That is important for batteries. The researchers fed the computer with backbone structures of 24 quinones and 28 aza-aromatics plus five different chemically relevant side groups. From that, the computer created 31,618 different molecules.

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Physicists have discovered a new quantum state in a material with the chemical formula Mn3SiTe6. The new state forms due to long-theorized but never previously observed internal currents that flow in loops around the material’s honeycomb-like structure. According to its discoverers, this new state could have applications for quantum sensors and memory storage devices for quantum computers.

Mn3SiTe6 is a ferrimagnet, meaning that its component atoms have opposing but unequal magnetic moments. It usually behaves like an insulator, but when physicists led by Gang Cao of the University of Colorado, Boulder, US, exposed it to a magnetic field applied along a certain direction, they found that it became dramatically more conducting – almost like it had morphed from being a rubber to a metal.

This effect, known as colossal magnetoresistance (CMR), is not itself new. Indeed, physicists have known about it since the 1950s, and it is now employed in computer disk drives and many other electronic devices, where it helps electric currents shuttle across along distinct trajectories in a controlled way.

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The latest data improves our understanding of how clouds in “hot Jupiter” exoplanets like this might appear up close. They are likely to be broken up, rather than a single, uniform blanket over the planet.

Photochemistry is the result of light triggering chemical reactions. This process is fundamental to life on Earth: it makes ozone, for example, which protects us from harsh ultraviolet (UV) rays.

New observations of WASP-39 b, a Jupiter-sized planet orbiting a Sun-like star found 700 light years away, confirm the presence of a never-before-seen molecule in the atmosphere – sulfur dioxide – among other details.

The James Webb Space Telescope has previously studied WASP-39 b. In August, it captured the first clear evidence for carbon dioxide. Now, it has focused its array of highly sensitive instruments on the planet once again, revealing not just an isolated ingredient, but a full menu of atoms, molecules, and even signs of active chemistry and clouds in the broiling atmosphere. This latest data, far more detailed than any previous telescope, shows the amazing capabilities of Webb, and hints at the potential for future discoveries that may reveal biosignatures.

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Could psychedelics make you more creative? Shift your mind, connect you to others, and help you access a younger, more malleable version of yourself? Activist Rick Doblin, neuroscientist Gül Dölen, and musician Reggie Watts join Brian Greene for a mind-bending and multidisciplinary conversation about the promises and pitfalls of these “magic” molecules and their impact on creativity, connection, and consciousness.

This program is part of the Big Ideas series, supported by the John Templeton Foundation.

Participants:
Rick Doblin.
Gül Dölen.
Reggie Watts.

Moderator:
Brian Greene.

Thumbnail image courtesy of: William Horton Photography.

Share your thoughts on this program through a short survey:

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Observations of Exoplanet WASP-39b show fingerprints of atoms and molecules, as well as signs of active chemistry and clouds.

WASP-39 b is a planet unlike any in our solar system – a Saturn.

Saturn is the sixth planet from the sun and has the second-largest mass in the Solar System. It has a much lower density than Earth but has a much greater volume. Saturn’s name comes from the Roman god of wealth and agriculture.

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Magnetic fields are all around us. They exist whenever there is electric current and have been used in various aspects of medicine for decades. Today, magnetic fields are used in applications including magnetic resonance imaging (MRI), bone fracture repair, wound healing and pain reduction.

Taking things a step further, US startup EMulate Therapeutics has developed a unique magnetic field technology that has been shown to replicate the effect of drugs in humans and animal models – all without the presence of chemicals. Having spun-out companies in cancer, pain management and beyond, the company is seeking partners for longevity applications of its technology.

Longevity. Technology: The concept behind EMulate’s approach is mind-boggling. The company “records” the electromagnetic signature of specific molecules and is then able to use those recordings to effect changes in cellular behaviour, without using chemicals. In its most advanced programme, EMulate’s technology has completed feasibility clinical trials for adults and children with terminal brain cancer, using a recording derived from chemotherapy drug paclitaxel. We caught up with EMulate’s CEO Chris Rivera to find out more.

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The James Webb Space Telescope has captured a detailed molecular and chemical portrait of a faraway planet’s skies, scoring another first for the exoplanet science community.

WASP-39b, otherwise known as Bocaprins, can be found orbiting a star some 700 light-years away. It is an exoplanet — a planet outside our solar system — as massive as Saturn but much closer to its host star, making for an estimated temperature of 1,600 degrees Fahrenheit (871 degrees Celsius) emitting from its gases, according to NASA. This “hot Saturn” was one of the first exoplanets that the Webb telescope examined when it first began its regular science operations.

The new readings provide a full breakdown of Bocaprins’ atmosphere, including atoms, molecules, cloud formations (which appear to be broken up, rather than a single, uniform blanket as scientists previously expected) and even signs of photochemistry caused by its host star.

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