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Ultrafast core-level spectroscopy reveals elusive precursors of exciton condensation in quantum materials

Many fascinating phases in quantum materials emerge when electrons, atoms and other microscopic components begin to act collectively. But these phases do not necessarily appear out of nowhere when a material crosses a transition temperature. Before long-range order develops, microscopic fluctuations can already be present.

Understanding these precursor fluctuations is important because they can tell us which interactions are responsible for driving a material toward an emergent phase. However, the difficulty is seeing them.

Most experimental signatures of phase transitions are easiest to recognize once long-range order has already formed. For example, we can look for a new periodic structure in a diffraction experiment. However, fluctuations that precede this order are transient and lack the same well-defined spatial pattern, making them much harder to measure directly.

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