This study investigates CaCu3−xSrxTi4O12 (CCSTO) systems synthesized using the solid-state method, with x compositions of 0.00, 0.15, and 3.00. The samples were modified using 6 wt% graphene oxide (GO) and reduced GO (rGO) prepared via Hummer’s method to evaluate their performance as electrodes in supercapacitors. The results indicate that the addition of 6wt% rGO to CCTO (CCTO-6rGO) led to an improvement in specific capacitance, reaching 237.76 mF·g−1 at a scan rate of 10 mV/s, compared to 29.86 mF·g−1 for pure CCTO and only 7.83 mF·g−1 for CCTO-6GO, suggesting that rGO enhances charge storage. For the CCTO15Sr samples, CCTO15Sr-6rGO exhibited the highest specific capacitance, with 321.63 mF·g−1 at 10 mV/s, surpassing both pure CCTO15Sr (80.19 mF·g−1) and CCTO15Sr-6GO (25.73 mF·g−1). These results stem from oxygen and metal vacancies, which aid charge accumulation and ion diffusion.








