What if a complex material could reshape itself in response to a simple chemical signal? A team of physicists from the University of Vienna and the University of Edinburgh has shown that even small changes in pH value and thus in electric charge can shift the spatial arrangement of closed ring-shaped polymers (molecular chains)—by altering the balance between twist and writhe, two distinct modes of spatial deformation.
Their findings, published in Physical Review Letters, demonstrate how electric charge can be used to reshape polymers in a reversible and controllable way—opening up new possibilities for programmable, responsive materials.
With such materials, permeability and mechanical properties such as elasticity, yield stress and viscosity could be better controlled and precisely “programmed.”