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Harnessing Quantum Properties to Create Single-Molecule Devices

Columbia team discovers 6-nanometer-long single-molecule circuit with enormous on/off ratio due to quantum interference; finding could enable faster, smaller, and more energy-efficient devices.

Researchers, led by Columbia Engineering Professor Latha Venkataraman, report today that they have discovered a new chemical design principle for exploiting destructive quantum interference. They used their approach to create a six-nanometer single-molecule switch where the on-state current is more than 10,000 times greater than the off-state current–the largest change in current achieved for a single-molecule circuit to date.

This new switch relies on a type of quantum interference that has not, up to now, been explored. The researchers used long molecules with a special central unit to enhance destructive quantum interference between different electronic energy levels. They demonstrated that their approach can be used to produce very stable and reproducible single-molecule switches at room temperature that can carry currents exceeding 0.1 microamps in the on-state. The length of the switch is similar to the size of the smallest computer chips currently on the market and its properties approach those of commercial switches. The study is published today in Nature Nanotechnology.

Magnetism Does the Twist: Skyrmions 10,000 Times Thinner Than a Human Hair Could Advance High-Density Data Storage

Scientists discovered a strategy for layering dissimilar crystals with atomic precision to control the size of resulting magnetic quasi-particles called skyrmions. This approach could advance high-density data storage and quantum magnets for quantum information science.

In typical ferromagnets, magnetic spins align up or down. Yet in skyrmions, they twist and swirl, forming unique shapes like petite porcupines or tiny tornadoes.

The tiny intertwined magnetic structures could innovate high-density data storage, for which size does matter and must be small. The Oak Ridge National Laboratory-led project produced skyrmions as small as 10 nanometers – 10,000 times thinner than a human hair.

A machine learning solution for designing materials with desired optical properties

Understanding how matter interacts with light—its optical properties—is critical in a myriad of energy and biomedical technologies, such as targeted drug delivery, quantum dots, fuel combustion, and cracking of biomass. But calculating these properties is computationally intensive, and the inverse problem—designing a structure with desired optical properties—is even harder.

Now Berkeley Lab scientists have developed a machine learning model that can be used for both problems—calculating of a known structure and, inversely, designing a structure with desired optical properties. Their study was published in Cell Reports Physical Science.

“Our model performs bi-directionally with high accuracy and its interpretation qualitatively recovers physics of how metal and dielectric materials interact with light,” said corresponding author Sean Lubner.

Mapping quantum structures with light to unlock their capabilities

A new tool that uses light to map out the electronic structures of crystals could reveal the capabilities of emerging quantum materials and pave the way for advanced energy technologies and quantum computers, according to researchers at the University of Michigan, University of Regensburg and University of Marburg.

A paper on the work is published in Science.

Applications include LED lights, solar cells and artificial photosynthesis.

New platform generates hybrid light-matter excitations in highly charged graphene

Graphene, an atomically thin carbon layer through which electrons can travel virtually unimpeded, has been extensively studied since its first successful isolation more than 15 years ago. Among its many unique properties is the ability to support highly confined electromagnetic waves coupled to oscillations of electronic charge—plasmon polaritons—that have potentially broad applications in nanotechnology, including biosensing, quantum information, and solar energy.

However, in order to support , must be charged by applying a voltage to a nearby metal gate, which greatly increases the size and complexity of nanoscale devices. Columbia University researchers report that they have achieved plasmonically active graphene with record-high charge density without an external gate. They accomplished this by exploiting novel interlayer charge transfer with a two-dimensional electron-acceptor known as α-RuCl3. The study is available now online as an open access article and will appear in the December 9th issue of Nano Letters.

“This work allows us to use graphene as a plasmonic material without metal gates or voltage sources, making it possible to create stand-alone graphene plasmonic structures for the first time” said co-PI James Hone, Wang Fong-Jen Professor of Mechanical Engineering at Columbia Engineering.

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