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Category: chemistry – Page 90

Real-time analysis reveals a much higher proportion of harmful substances in particulate matter than assumed

People breathing contaminated air over the course of years are at greater risk of developing numerous diseases. This is thought to be due to highly reactive components in particulate matter, which affect biological processes in the body. However, researchers from the University of Basel, Switzerland, have now shown that precisely these components disappear within hours and that previous measurements therefore completely underestimate the quantities in which they are present.

From chronic respiratory problems to cardiovascular diseases, diabetes and dementia, health damage caused by air pollution is wide-ranging and serious. The World Health Organization (WHO) estimates that over six million deaths a year are caused by increased exposure to particulate matter.

The chemical composition of these tiny particles in the air, which come from a wide range of both anthropogenic and natural sources, is highly complex. Which particles trigger which reactions and long-term diseases in the body is the subject of intensive research.

Scientists Reveal the Hidden Chemistry of Air Pollution

The interactions between light and nitroaromatic hydrocarbon molecules have important implications for chemical processes in our atmosphere that can lead to smog and pollution. However, changes in molecular geometry due to interactions with light can be very difficult to measure because they occur at sub-Angstrom length scales (less than a tenth of a billionth of a meter) and femtosecond time scales (one millionth of a billionth of a second).

The relativistic ultrafast electron diffraction (UED) instrument at the Linac Coherent Light Source (LCLS) at SLAC National Accelerator Laboratory provides the necessary spatial and time resolution to observe these ultrasmall and ultrafast motions. The LCLS is a Department of Energy (DOE) Office of Science light source user facility.

In this research, scientists used UED to observe the relaxation of photoexcited o–nitrophenol. Then, they used a genetic structure fitting algorithm to extract new information about small changes in the molecular shape from the UED data that were imperceptible in previous studies. Specifically, the experiment resolved the key processes in the relaxation of o-nitrophenol: proton transfer and deplanarization (i.e., a rotation of part of the molecule out of the molecular plane). Ab-initio multiple spawning simulations confirmed the experimental findings. The results provide new insights into proton transfer-mediated relaxation and pave the way for studies of proton transfer in more complex systems.

Taking the ‘forever’ out of ‘forever chemicals’: Scientists work out how to destroy the PFAS in batteries

Lithium-ion batteries are part of everyday life. They power small rechargeable devices such as mobile phones and laptops. They enable electric vehicles. And larger versions store excess renewable energy for later use, supporting the clean energy transition.

Australia produces more than 3,000 metric tons of lithium-ion battery a year. Managing this waste is a technical, economic and social challenge. Opportunities exist for and creating a circular economy for batteries. But they come with risk.

That’s because contain manufactured chemicals such as PFAS, or per-and polyfluoroalkyl substances. The chemicals carry the lithium—along with electricity—through the battery. If released into the environment, they can linger for decades and likely longer. This is why they’ve been dubbed “forever chemicals”

Plants captured on video communicating with each other for the first time ever

This study builds on observations first made in 1983, which sparked debates and further research into plant communication.

Over the years, scientists have uncovered various ways plants interact, from chemical signals to underground networks formed by fungi.

“We have finally unveiled the intricate story of when, where, and how plants respond to airborne ‘warning messages’ from their threatened neighbors,” Dr. Toyota emphasized.

Palladium-liquid gallium catalyst transforms chemical manufacturing, boosting speed, safety and sustainability

A major breakthrough in liquid catalysis is transforming how essential products are made, making the chemical manufacturing process faster, safer and more sustainable than ever before.

Researchers from Monash University, the University of Sydney, and RMIT University have developed a liquid that could transform chemical production across a range of industries—from pharmaceuticals and sustainable products to advanced materials.

By dissolving palladium in liquid gallium the team, led by Associate Professor Md. Arifur Rahim from Monash University’s Department of Chemical and Biological Engineering, created a self-regenerating catalytic system with unprecedented efficiency.

Two new families of PFAS-free solvents for next-generation batteries

Chibueze Amanchukwu wants to fix batteries that haven’t been built yet. Demand for batteries is on the rise for EVs and the grid-level energy storage needed to transition Earth off fossil fuels. But more batteries will mean more of a dangerous suite of materials used to build them: PFAS, also known as “forever chemicals.”

“To address our needs as a society for electric vehicles and energy storage, we are coming up with more ,” said Amanchukwu, Neubauer Family Assistant Professor of Molecular Engineering in the UChicago Pritzker School of Molecular Engineering (UChicago PME). “You can see the dilemma.”

PFAS are a family of thousands of chemicals found in batteries but also everything from fast food wrappers and shampoo to firefighting foam and yoga pants. They keep scrambled eggs from sticking to pans and rain from soaking into jackets and paint, but the same water resistance that makes them useful also make them difficult to remove when they get into the water supply. This earned them the nickname “forever chemicals.”

Beyond RGB: A new image file format efficiently stores invisible light data

Why would anyone need this level of wavelength detail in an image? There are many reasons. Car manufacturers want to predict exactly how paint will look under different lighting. Scientists use spectral imaging to identify materials by their unique light signatures. And rendering specialists need it to accurately simulate real-world optical effects like dispersion (rainbows from prisms, for example) and fluorescence.

For instance, past Ars Technica coverage has highlighted how astronomers analyzed spectral emission lines from a gamma-ray burst to identify chemicals in the explosion, how physicists reconstructed original colors in pioneering 19th century photographs, and how multispectral imaging revealed hidden, centuries-old text and annotations on medieval manuscripts like the Voynich Manuscript, sometimes even uncovering the identities of past readers or scribes through faint surface etchings.

The current standard format for storing this kind of data, OpenEXR, wasn’t designed with these massive spectral requirements in mind. Even with built-in lossless compression methods like ZIP, the files remain unwieldy for practical work as these methods struggle with the large number of spectral channels.

Active compounds in Piper longum fruits show potential for functional foods and medicine

Mature or nearly mature fruits of Piper longum are used as a spice, valued for their commercial and industrial applications, as well as in traditional Chinese medicine for their multiple effects, such as dispelling cold and relieving pain.

Given their long history of medicinal use, the fruits of P. longum present an opportunity to explore their therapeutic constituents. However, the chemical components of traditional Chinese medicines are often complex, making the efficient discovery of novel active compounds a challenging task in natural product research.

To address this challenge, a research team led by Prof. Haji Akber Aisa from the Xinjiang Technical Institute of Physics & Chemistry of the Chinese Academy of Sciences isolated 12 dimeric amide alkaloid enantiomers with anti-inflammatory and antidiabetic effects from P. longum fruits using a molecular network-based dereplication strategy. This study was published in the Journal of Agricultural and Food Chemistry.

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