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Category: chemistry – Page 398

Russia is getting closer in perfecting Quantum Processors.

A team of physicists including Russian researchers succeeded in conducting an experiment in which, for the first time in history, control over ultrafast motion of electrons down to three attoseconds (one attosecond refers to a second as one second refers to the lifetime of the Universe) was proved possible (“Coherent control with a short-wavelength free-electron laser”). This fact paves a way to new directions of research that seemed improbable before. The experiment was conducted with the help of the free-electron laser FERMI located at the “Elettra Sincrotrone” research center in Trieste, Italy.

The speed of chemical, physical and biological processes is extremely high, atomic bonds are broken and restored within femtoseconds (one millionth of one billionth of a second). The Egyptian-American chemist Ahmed Zewail was the first to succeed in observing the dynamics of chemical processes, which made him a winner of the 1999 Nobel Prize in Chemistry.

Nevertheless, nature can operate even faster. While atomic motions within a molecule can be measured with femtosecond resolution, the dynamics of electrons, which define the nature of chemical bonds, happens a thousand times faster — within tens and hundreds of attoseconds.

The only tools appropriate for studying such processes are so-called x-ray free-electron lasers. In “conventional” gas, liquid and solid-state lasers, excitation of electrons in the bound atomic state serves as the source of photons. In contrast, free-electron lasers operate with the help of a high-quality electron beam wiggling along a sinusoidal path under the effect of a ray of magnets. During that process electrons lose energy by producing radiation.

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As I said this morning; there is something definitely going with Quantum today. Maybe it’s the planet alignment (I saw there was something going on with the alignment with Aquaris today) — this is awesome news.

Rigetti Computing is working on designs for quantum-powered chips to perform previously impossible feats that advance chemistry and machine learning.

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Convert carbon dioxide from air (at low temp) to methanol fuel — why not!

The carbon dioxide-to-methanol process (credit: Surya Prakash)

Researchers at the University of Southern California (USC) Loker Hydrocarbon Research Institute have created fuel out of thin air — directly converting carbon dioxide from air into methanol at relatively low temperatures for the first time. While methanol can’t currently compete with oil, it will be there when we run out of oil, the researchers note.

The researchers bubbled air through an aqueous solution of pentaethylenehexamine (PEHA), adding a Ru-Macho-BH ruthenium catalyst to encourage hydrogen to latch onto the CO2 under pressure. They then heated the solution, converting 79 percent of the CO2 into methanol.

Though mixed with water, the resulting methanol can be easily distilled, said G.K. Surya Prakash, professor of chemistry and director of the Loker Hydrocarbon Research Institute.

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With a growing number of Earth-like exoplanets discovered in recent years, it is becoming increasingly frustrating that we can’t visit them. After all, our knowledge of the planets in our own solar system would be pretty limited if it weren’t for the space probes we’d sent to explore them.

The problem is that even the nearest stars are a very long way away, and enormous engineering efforts will be required to reach them on timescales that are relevant to us. But with research in areas such as nuclear fusion and nanotechnology advancing rapidly, we may not be as far away from constructing small, fast interstellar space probes as we think.

There’s a lot at stake. If we ever found evidence suggesting that life might exist on a planet orbiting a nearby star, we would most likely need to go there to get definitive proof and learn more about its underlying biochemistry and evolutionary history. This would require transporting sophisticated scientific instruments across interstellar space.

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This is an interesting conjecture.

We may be able to keep our gut in check after all. That’s the tantalizing finding from a new study published today that reveals a way that mice—and potentially humans—can control the makeup and behavior of their gut microbiome. Such a prospect upends the popular notion that the complex ecosystem of germs residing in our guts essentially acts as our puppet master, altering brain biochemistry even as it tends to our immune system, wards off infection and helps us break down our supersized burger and fries.

In a series of elaborate experiments researchers from Harvard Medical School and Brigham and Women’s Hospital discovered that mouse poop is chock full of tiny, noncoding RNAs called microRNAs from their gastrointestinal (GI) tracts and that these biomolecules appear to shape and regulate the microbiome. “We’ve known about how microbes can influence your health for a few years now and in a way we’ve always suspected it’s a two-way process, but never really pinned it down that well,” says Tim Spector, a professor of genetic epidemiology at King’s College London, not involved with the new study. “This [new work] explains quite nicely the two-way interaction between microbes and us, and it shows the relationship going the other way—which is fascinating,” says Spector, author of The Diet Myth: Why the Secret to Health and Weight Loss Is Already in Your Gut.

What’s more, human feces share 17 types of microRNAs with the mice, which may portend similar mechanisms in humans, the researchers found. It could also potentially open new treatment approaches involving microRNA transplantations. “Obviously that raises the immediate question: ‘Where do the microRNAs come from and why are they there?,’” says senior author Howard Weiner, a neurologist at both Harvard and Brigham. The work was published in the journal Cell Host & Microbe.

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Specifications:

Performance Power output: 1088 hp Torque: 1600 Nm from 0 to 6500 rpm Acceleration: 0–100 km/h (0−62 mph) 2,8 seconds Range: up to 600 km (realistic range — 500 km) Braking distance: 31.5m (100−0 km/h) Lateral g-force: 1.4 g Efficiency: 140–550 Wh/km 40 kW on-board charging 100 kW fast DC-charging Weight-to-power ratio: 1.79 kg/hp Weight distribution: 42% front, 58% rear

Dimensions Total length: 4548 mm Total width: 1997 mm Total height: 1198 mm Ground clearance: Rear: 115 mm, Front: 105 mm Wheelbase: 2750 mm. Dry weight: 1950 kg

Battery-Pack Lithium-Iron-Phosphate (LiFePO4) chemistry Configuration: 1400 cells — 200 series, 7 parallel Voltage: 650V nominal Capacity: 91 kWh Cooling: Freon (gas) with high-voltage heat pumps Milled aluminum and sheet aluminum housing Rimac Automobili Active Battery and Thermal Management Systems Several layers of redundant safety and protection systems.

Chassis Carbon fibre monocoque with integrated battery-pack Carbon fibre sub-frames (front and rear) Carbon fibre crash structure Front and rear suspension: Double wishbones, fully adjustable, pushrod operated. Electronically adjustable ride height. Fully machined aluminum uprights and wishbones.

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Glucosepane is one of the most significant mechanisms of aging and yet very few people are working on it!

As we age skin and blood vessels lose their elasticity. People care too much about the skin and too little about the blood vessels, but that is always the way of it. Appearance first and substance later, if at all. Yet you can live inside an aged skin; beyond the raised risk of skin cancer its damaged state arguably only makes life less pleasant, and the present state of medical science can ensure that the numerous age-related dermatological dysfunctions can be kept to a state of minor inconvenience. Loss of blood vessel elasticity, on the other hand, will steadily destroy your health and then kill you. Arterial stiffening causes remodeling of the cardiovascular system and hypertension. The biological systems that regulate blood pressure become dysfunctional as blood vessels depart from ideal youthful behavior, creating a downward spiral of increasing blood pressure and reactions to that increase. Small blood vessels fail under the strain in ever larger numbers, damaging surrounding tissue. In the brain this damage contributes to age-related cognitive decline by creating countless tiny, unnoticed strokes. Ultimately this process leads to dementia. More important parts of the cardiovascular system are likely to fail first, however, perhaps causing a stroke, or a heart attack, or the slower decline of congestive heart failure.

From what is known today, it is reasonable to propose that the two main culprits driving loss of tissue elasticity are sugary cross-links generated as a byproduct of the normal operation of cellular metabolism and growing numbers of senescent cells. Elasticity is a property of the extracellular matrix, an intricate structure of collagens and other proteins created by cells. Different arrangements of these molecules produce very different structures, ranging from load-bearing tissues such as bone and cartilage to elastic tissues such as skin and blood vessel walls. Disrupting the arrangement and interaction of molecules in the extracellular matrix also disrupts its properties. Persistent cross-links achieve this by linking proteins together and restricting their normal range of motion. Senescent cells, on the other hand, secrete a range of proteins capable of breaking down or remodeling portions of the surrounding extracellular matrix, and altering the behavior of nearby cells for the worse.

The most important cross-linking compound in humans is glucosepane. Our biochemistry cannot break down glucosepane cross-links, and as a result it accounts for more than 99% of cross-links in our tissues. This isn’t a big secret. Given this you might expect to find researchers working flat out in scores of laboratories to find a viable way to break it down. After all here we have one single target molecule, and any drug candidate capable of clearing even half of existing cross-links would provide a treatment that can both reverse skin aging and vascular aging to a much greater degree than any presently available therapy. The size of the resulting market is every human being, the potential for profit staggering. Yet search on PubMed, and this is all of relevance that you will see published on the topic in the past few years:

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Vivid holographic images and text can now be produced by means of an ordinary inkjet printer. This new method, developed by a team of scientists from ITMO University in Saint Petersburg, is expected to significantly reduce the cost and time needed to create the so-called rainbow holograms, commonly used for security purposes — to protect valuable items, such as credit cards and paper currency, from piracy and falsification. The results of the study were published 17 November in the scientific journal Advanced Functional Materials.

The team, led by Alexander Vinogradov, senior research associate at the International Laboratory of Solution Chemistry of Advanced Materials and Technologies (SCAMT) in ITMO University, developed colorless ink made of nanocrystalline titania, which can be loaded into an inkjet printer and then deposited on special microembossed paper, resulting in unique patterned images. The ink makes it possible to print custom holographic images on transparent film in a matter of minutes, instead of days as with the use of conventional methods.

Rainbow holograms are widely used to fight against the forgery of credit cards, money, documents and certain manufactured products that call for a high level of protection. Even though the technology of obtaining holographic images was already developed in the 1960s, there still exist numerous technical difficulties that impede its further spread and integration into polygraphic industry.

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Ray Kurzweil: https://en.wikipedia.org/wiki/Ray_Kurzweil#Health_and_aging

Raymond “Ray” Kurzweil is an American author, computer scientist, inventor and futurist. Aside from futurology, he is involved in fields such as optical character recognition (OCR), text-to-speech synthesis, speech recognition technology, and electronic keyboard instruments. He has written books on health, artificial intelligence (AI), transhumanism, the technological singularity, and futurism. Kurzweil is a public advocate for the futurist and transhumanist movements, and gives public talks to share his optimistic outlook on life extension technologies and the future of nanotechnology, robotics, and biotechnology.

Kurzweil admits that he cared little for his health until age 35, when he was found to suffer from a glucose intolerance, an early form of type II diabetes (a major risk factor for heart disease). Kurzweil then found a doctor (Terry Grossman, M.D.) who shares his non-conventional beliefs to develop an extreme regimen involving hundreds of pills, chemical intravenous treatments, red wine, and various other methods to attempt to live longer. Kurzweil was ingesting “250 supplements, eight to 10 glasses of alkaline water and 10 cups of green tea” every day and drinking several glasses of red wine a week in an effort to “reprogram” his biochemistry. Lately, he has cut down the number of supplement pills to 150.

Facebook: https://www.facebook.com/agingreversed

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The world of superconductivity is in uproar. Last year, Mikhail Eremets and a couple of pals from the Max Planck Institute for Chemistry in Mainz, Germany, made the extraordinary claim that they had seen hydrogen sulphide superconducting at −70 °C. That’s some 20 degrees hotter than any other material—a huge increase over the current record.

Eremets and co have worked hard to conjure up the final pieces of conclusive evidence. A few weeks ago, their paper was finally published in the peer reviewed journal Nature, giving it the rubber stamp of respectability that mainstream physics requires. Suddenly, superconductivity is back in the headlines.

Today, Antonio Bianconi and Thomas Jarlborg at the Rome International Center for Materials Science Superstripes in Italy provide a review of this exciting field. These guys give an overview of Eremet and co’s discovery and a treatment of the theoretical work that attempts to explain it.

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