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Category: chemistry – Page 288

Meteorites older than the solar system contain key ingredients for life

I believe that these microbes are not just simple organisms but are some sorta biological singularity seeds that activate over millions of years developing life slowly and may be exterrestial in origin.

Researchers from Hokkaido University in Japan have found new evidence that the chemical components necessary to build DNA may have been carried to Earth by carbonaceous meteorites, some of the earliest matter in the solar system, as they report in a study published Tuesday in Nature Communications. Although these kinds of materials make up about 75 percent of all asteroids, they rarely fall to Earth, limiting how often scientists can study them. Yet they are troves of information: Scrutinizing these space rocks can tell stories about unique cosmic locations. Their contents may also help reveal the ancient chemical reactions that made our world a living planet.

Specifically, several meteorites have been found to contain nucleobases. These chemicals, called the building blocks of life, make up the nucleic acids inside DNA and RNA. Of the five major nucleobases, previous meteorite studies detected only three of them, named adenine, guanine, and uracil. But the present research proves for the first time that two more—cytosine and thymine—can exist within space rocks.

“The detection of all primary DNA and RNA nucleobases in meteorites indicates that these molecules have been supplied to the early Earth before the onset of life,” says Yasuhiro Oba, lead author of the study and an associate professor at Hokkaido University. ” In other words, we got information about the inventory of organic molecules related to DNA and RNA before any life arose on the Earth.” One of the oldest specimens in the study clocks in at about 4.6 billion years old, which is even older than the solar system.

Optical Vortex Sizes Up Nanoparticles

A novel method for measuring nanoparticle size could have applications in industry and basic materials science research.

Nanoparticles are present in everything from paints to pharmaceutical products. While nanoparticles have many important characteristics, such as molecular composition and shape, it is their size that determines many chemical and physical properties. A new technique relying on an optical vortex—a laser beam whose wave fronts twist around a dark central region—allows researchers to characterize nanoparticle size rapidly and continuously [1]. This light-based size probe might one day find applications in numerous industrial settings and aid fundamental materials science research.

It is difficult to precisely synthesize nanoparticles with the desired dimensions, so manufacturers must often validate that their nanoparticles have the right size to comply with regulations and to ensure product quality. There are many ways of determining nanoparticle size, but one popular approach, dynamic light scattering (DLS), is based on measurements of Brownian motion, the random particle movement caused by jostling from the surrounding liquid medium. In DLS, the Brownian motion is determined by measuring fluctuations in laser light scattering from the nanoparticles. In general, the faster the Brownian motion, the smaller the particles. But current techniques are generally not capable of characterizing the largest particles and measuring them continuously.

New heat-tolerant, high-capacity capacitor created with solid electrolytes borrowed from all-solid-state batteries

Capacitors are energy storage devices—consisting of two electrodes and an electrolyte—that are capable of rapid charging and discharging because of charge adsorption and desorption properties at the electrode-electrolyte interface. Because capacitors’ energy storage does not involve chemical reactions, their storage capacity is lower than that of lithium-ion batteries, but they are useful for power leveling for renewable energy that requires repeated charging at high currents, regenerative braking energy for trains and electric or hybrid cars, as well as instantaneous voltage drop compensation devices that prevent equipment failure due to lightning strikes. They are also expected to be used to store energy for wearable devices in the near future.

Most capacitors use a liquid electrolyte with a low boiling point, which can only be used at temperatures below 80℃. Ceramic capacitors that use solid inorganic materials as a dielectric can be used at temperatures above 80℃, but their is much lower than liquid electrolyte capacitors, which limits their use to electronic circuits.

To increase the energy storage of capacitors, it is necessary to have a large contact area at the interface between the electrode and the electrolyte. Making a large contact area is difficult using ; so, the creation of a capacitor with high storage capacity that can also operate at high temperatures has been desired for a long time.

New Research Shows How Dopamine Plays a Key Role in Consciousness

The Brain Chemical Involved in Consciousness

So how do we help these people? The brain is more than just a congregation of different areas. Brain cells also rely on a number of chemicals to communicate with other cells, enabling a number of brain functions. Before our study, there was already some evidence that dopamine, well known for its role in reward, also plays a role in disorders of consciousness.

For example, one study showed that dopamine release in the brain is impaired in minimally conscious patients. Moreover, a number of small-scale studies have shown that patients’ consciousness can improve by giving them drugs that act through dopamine.

Scientists design new inks for 3D-printable wearable bioelectronics

Flexible electronics have enabled the design of sensors, actuators, microfluidics and electronics on flexible, conformal and/or stretchable sublayers for wearable, implantable or ingestible applications. However, these devices have very different mechanical and biological properties when compared to human tissue and thus cannot be integrated with the human body.

A team of researchers at Texas A&M University has developed a new class of biomaterial inks that mimic native characteristics of highly conductive , much like skin, which are essential for the ink to be used in 3D printing.

This biomaterial ink leverages a new class of 2D nanomaterials known as molybdenum disulfide (MoS2). The thin-layered structure of MoS2 contains defect centers to make it chemically active and, combined with modified gelatin to obtain a flexible hydrogel, comparable to the structure of Jell-O.

New supramolecular plastic heals itself in an instant

Scientists experimenting with next-generation plastics at Finland’s University of Turku have developed a form of the material with some impressive capabilities, most notably an ability to quickly break down after use. The eco-friendly “supramolecular” plastic is therefore highly recyclable and, with careful tuning of its water content, can be turned into an adhesive or even instantly self-heal when damaged.

The reason conventional plastics persist in the environment for so long is the incredibly strong chemical connections between the monomers within them. These particles link up to form polymers through what are known as covalent bonds, but scientists hope to fashion more environmentally forms of the material based on non-covalent bonds instead.

These weaker connections are better suited to degradation and recycling of the material, but do come at a cost in terms of mechanical performance. We have looked at some interesting examples of these “supramolecular” materials in the form of hybrid polymers for drug delivery, self-assembling plastics and adhesives that work at extreme temperatures.

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