Lifeboat Foundation

In the periodic table of elements there is one golden rule for carbon, oxygen and other light elements: Under high pressures, they have similar structures to heavier elements in the same group of elements. But nitrogen always seemed unwilling to toe the line. However, high-pressure chemistry researchers of the University of Bayreuth have disproved this special status. Out of nitrogen, they created a crystalline structure which, under normal conditions, occurs in black phosphorus and arsenic. The structure contains two-dimensional atomic layers, and is therefore of great interest for high-tech electronics. The scientists have presented this “black nitrogen” in Physical Review Letters.

Nitrogen—an exception in the periodic system?

When you arrange the chemical elements in ascending order according to their number of protons and look at their properties, it soon becomes obvious that certain properties recur at large intervals (periods). The periodic table of elements brings these repetitions into focus. Elements with similar properties are placed one below the other in the same column, and thus form a group of elements. At the top of a column is the element that has the fewest protons and the lowest weight compared to the other group members. Nitrogen heads element group 15, but was previously considered the “black sheep” of the group. The reason: In earlier high-pressure experiments, nitrogen showed no structures similar to those exhibited under normal conditions by the heavier elements of this group—specifically, phosphorus, arsenic and antimony. Instead, such similarities are observed at high pressures in the neighboring groups headed by carbon and oxygen.

Study co-led by Berkeley Lab reveals how wavelike plasmons could power up a new class of sensing and photochemical technologies at the nanoscale.

Wavelike, collective oscillations of electrons known as “plasmons” are very important for determining the optical and electronic properties of metals.

In atomically thin 2D materials, plasmons have an energy that is more useful for applications, including sensors and communication devices, than plasmons found in bulk metals. But determining how long plasmons live and whether their energy and other properties can be controlled at the nanoscale (billionths of a meter) has eluded many.

Circa 2007

This chapter describes detection of explosives by terahertz Imaging ™. There has been an amplified interest in terahertz (THz) detection for imaging of covered weapons, explosives, chemical and biological agents. THz radiation is readily transmitted through most nonmetallic and nonpolar mediums. This process enables the THz systems to see through concealing barriers, which includes packaging, corrugated cardboard, clothing, shoes, book bags, and such others to find potentially dangerous materials concealed within. Apart from many materials of interest for security applications, which include explosives, chemical agents, and other such biological agents that have characteristic THz spectra which can be used for fingerprint testing and identify concealed materials. The Terahertz radiation poses either no or minimal health risk to either a suspect being scanned by a THz system or the system’s operator. As plastic explosives, fertilizer bombs, and chemical and biological agents increasingly become weapons of war and terrorism, and the trafficking of illegal drugs increasingly develops as a systemic threat, effective means for rapid detection, and an identification of these threats are required. One proposed solution for locating, detecting, and characterizing concealed threats is to use THz electromagnetic waves to spectroscopically detect and identify concealed materials through their characteristic transmission or reflectivity spectra in the range of 0.5–10 THz.

VICE.

What do a frying pan, an LED light, and the most cutting edge camouflage in the world have in common? Well, that largely depends on who you ask. Most people would struggle to find the link, but for University of Michigan chemical engineers Sharon Glotzer and Michael Engel, there is a substantial connection, indeed one that has flipped the world of materials science on its head since its discovery over 30 years ago.

The magic ingredient common to all three items is the quasiperiodic crystal, the “impossible” atomic arrangement discovered by Dan Shechtman in 1982. Basically, a quasicrystal is a crystalline structure that breaks the periodicity (meaning it has translational symmetry, or the ability to shift the crystal one unit cell without changing the pattern) of a normal crystal for an ordered, yet aperiodic arrangement. This means that quasicrystalline patterns will fill all available space, but in such a way that the pattern of its atomic arrangement never repeats. Glotzer and Engel recently managed to simulate the most complex quasicrystal ever, a discovery which may revolutionize the field of crystallography by blowing open the door for a whole host of applications that were previously inconceivable outside of science-fiction, like making yourself invisible or shape-shifting robots.

Continue reading “Quasicrystals Are Nature’s Impossible Matter” »

The strongest permanent magnets today contain a mix of the elements neodymium and iron. However, neodymium on its own does not behave like any known magnet, confounding researchers for more than half a century. Physicists at Radboud University and Uppsala University have shown that neodymium behaves like a so-called ‘self-induced spin glass,’ meaning that it is composed of a rippled sea of many tiny whirling magnets circulating at different speeds and constantly evolving over time. Understanding this new type of magnetic behavior refines our understanding of elements on the periodic table and eventually could pave the way for new materials for artificial intelligence. The results will be published in Science on May 29, 2020.

“In a jar of honey, you may think that the once clear areas that turned milky yellow have gone bad. But rather, the jar of honey starts to crystallize. That’s how you could perceive the ‘aging’ process in neodymium.” Alexander Khajetoorians, professor in Scanning probe microscopy, together with professor Mikhail Katsnelson and assistant professor Daniel Wegner, found that the material neodymium behaves in a complex magnetic way that no one ever saw before in an element on the periodic table.

There has been plenty of empirical evidence which shows that the single-particle picture holds to a good approximation in atomic nuclei. In this picture, protons and neutrons move independently inside a mean-field potential generated by an interaction among the nucleons. This leads to the concept of nuclear shells, similar to the electronic shells in atoms. In particular, the magic numbers due to closures of the nucleonic shells, corresponding to noble gases in elements, have been known to play an important role in nuclear physics. Here we propose a periodic table for atomic nuclei, in which the elements are arranged according to the known nucleonic shells. The nuclear periodic table clearly indicates that nuclei in the vicinity of the magic numbers can be understood in terms of a shell closure with one or two additional nucleons or nucleon holes, while nuclei far from the magic numbers are characterized by nuclear deformation.

A machine-learning algorithm has been developed by scientists in Japan to breathe new life into old molecules. Called BoundLess Objective-free eXploration, or Blox, it allows researchers to search chemical databases for molecules with the right properties to see them repurposed. The team demonstrated the power of their technique by finding molecules that could work in solar cells from a database designed for drug discovery.

Chemical repurposing involves taking a molecule or material and finding an entirely new use for it. Suitable molecules for chemical repurposing tend to stand apart from the larger group when considering one property against another. These materials are said to be out-of-trend and can display previously undiscovered yet exceptional characteristics.

‘In public databases there are a lot of molecules, but each molecule’s properties are mostly unknown. These molecules have been synthesised for a particular purpose, for example drug development, so unrelated properties were not measured,’ explains Koji Tsuda of the Riken Centre for Advanced Intelligence and who led the development of Blox. ‘There are a lot of hidden treasures in databases.’

Nanoparticle superlattice films that form at the solid-liquid interface are important for mesoscale materials but are challenging to analyze on the onset of formation at a solid-liquid interface. In a new report on Science Advances, E. Cepeda-Perez and a research team in materials, physics and chemistry in Germany studied the early stages of nanoparticle assembly at solid-liquid interfaces using liquid-phase electron microscopy. They observed oleylamine-stabilized gold nanoparticles to spontaneously form thin layers on a silicon nitride membrane window of the liquid enclosure. In the first monolayer, the assembly maintained dense packings of hexagonal symmetry independent of the nonpolar solvent type. The second layer displayed geometries ranging from dense packing in a hexagonal honeycomb structure to quasi-crystalline particle arrangements—based on the dielectric constant of the liquid. The complex structures made of weaker interactions remained preserved, while the surface remained immersed in liquid. By fine-tuning the properties of materials involved in nanoparticle superlattice formation, Cepeda-Perez et al. controlled the three-dimensional (3D) geometry of a superlattice, including quasi-crystals (a new state of matter).

Nanoparticles that are densely packed into two or three dimensions can form regular arrays of nanoparticle superlattices. For example, semiconductor particle superlattices can act as “meta” semiconductors when doped with particles to form new mesoscale materials, while plasmonic particles in dense superlattices can couple to form collective modes with angle-dependent and tunable wavelength responses. Large electric fields can occur between such particles for surface-enhanced Raman spectroscopy. Superlattices can be developed at liquid-liquid, gas-liquid and solid-liquid interfaces, where static and dynamic interactions between particle-substrate, particle-particle and particle-liquid interactions can dictate the structure of superlattices. However, it remains difficult to predict such structures in advance. For example, simulating the assembly of superlattices at multiple stages is not yet possible, with very little in-lab real-space data available for modeling.

Meticulously organised fatty acids are responsible for the bacteria-killing, superhydrophobic nanostructures on cicada wings. The team behind the discovery hopes that its work will inspire antimicrobial surfaces that mimic cicada wings for use in settings such as hospitals.

When in contact with dust, pollen and – importantly – water, the cicadas’ superhydrophobic wings repel matter to self-clean. These extraordinary properties are down to fatty acid nanopillars, periodically spaced and of nearly uniform height, that cover the wings.

Past work has generally only described cicadas’ wings as ‘waxy’ and not explained how these fatty acids nanopillars give rise to unique traits. Nor is it known exactly why cicada wings evolved antibacterial nanostructures. These gaps in our knowledge exist, in part, because of how diverse the cicada family is. But Marianne Alleyne’s group at the University of Illinois, Urbana–Champaign, along with colleagues at Sandia National Labs, set out to understand what role chemistry plays in the wings of two evolutionarily divergent species.