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Category: chemistry – Page 248

The previously elusive methanediol molecule of importance to the organic, atmospheric science and astrochemistry communities has been synthetically produced for the first time by University of Hawaiʻi at Mānoa researchers. Their discovery and methods were published in Proceedings of the National Academy of Sciences on December 30.

Methanediol is also known as formaldehyde monohydrate or methylene glycol. With the chemical formula CH2(OH)2, it is the simplest geminal diol, a molecule which carries two hydroxyl groups (OH) at a single carbon atom. These are suggested as key intermediates in the formation of aerosols and reactions in the ozone layer of the atmosphere.

The research team—consisting of Department of Chemistry Professor Ralf Kaiser, postdoctoral researchers Cheng Zhu, N. Fabian Kleimeier and Santosh Singh, and W.M. Keck Laboratory in Astrochemistry Assistant Director Andrew Turner—prepared methanediol via energetic processing of extremely low temperature ices and observed the molecule through a high-tech mass spectrometry tool exploiting tunable vacuum photoionization (the process in which an ion is formed from the interaction of a photon with an atom or molecule) in the W.M. Keck Laboratory in Astrochemistry. Electronic structure calculations by University of Mississippi Associate Professor Ryan Fortenberry confirmed the gas phase stability of this molecule and demonstrated a pathway via reaction of electronically excited oxygen atoms with methanol.

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The idea of a human-made device that can process solar energy to make usable fuels has been tantalizing researchers since the 1970s. There being no such thing as a free lunch, it is not so easy to engineer a device that mimics photosynthesis, which Mother Nature perfected a long time ago. Nevertheless, researchers at the Department of Energy’s Lawrence Berkeley Lab in California appear to have solved an important piece of the “artificial leaf” challenge.

Solar Energy & The Artificial Leaf Of The Future

The concept of the artificial leaf first crossed the CleanTechnica radar in the form of a card-sized photoelectrochemical cell, back in 2011. Instead of converting sunlight into electricity, the cell acts as a catalyst that deploys solar energy to break water into oxygen and hydrogen.

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Circa 2018

Digitization results in a high energy consumption. In industrialized countries, information technology presently has a share of more than 10% in total power consumption. The transistor is the central element of digital data processing in computing centers, PCs, smartphones, or in embedded systems for many applications from the washing machine to the airplane. A commercially available low-cost USB memory stick already contains several billion . In the future, the single-atom transistor developed by Professor Thomas Schimmel and his team at the Institute of Applied Physics (APH) of KIT might considerably enhance energy efficiency in . “This element enables switching energies smaller than those of conventional silicon technologies by a factor of 10,000,” says physicist and nanotechnology expert Schimmel, who conducts research at the APH, the Institute of Nanotechnology (INT), and the Material Research Center for Energy Systems (MZE) of KIT. Earlier this year, Professor Schimmel, who is considered the pioneer of single-atom electronics, was appointed Co-Director of the Center for Single-Atom Electronics and Photonics established jointly by KIT and ETH Zurich.

In Advanced Materials, the KIT researchers present the transistor that reaches the limits of miniaturization. The scientists produced two minute metallic contacts. Between them, there is a gap as wide as a single metal atom. “By an electric control pulse, we position a single silver atom into this gap and close the circuit,” Professor Thomas Schimmel explains. “When the silver atom is removed again, the circuit is interrupted.” The world’s smallest transistor switches current through the controlled reversible movement of a single atom. Contrary to conventional quantum electronics components, the single-atom transistor does not only work at extremely low temperatures near absolute zero, i.e.-273°C, but already at room temperature. This is a big advantage for future applications.

The single-atom transistor is based on an entirely new technical approach. The transistor exclusively consists of metal, no semiconductors are used. This results in extremely low electric voltages and, hence, an extremely low consumption. So far, KIT’s single-atom transistor has applied a liquid electrolyte. Now, Thomas Schimmel and his team have designed a transistor that works in a solid electrolyte. The gel electrolyte produced by gelling an aqueous silver electrolyte with pyrogenic silicon dioxide combines the advantages of a solid with the electrochemical properties of a liquid. In this way, both safety and handling of the single-atom transistor are improved.

Continue reading “Smallest transistor worldwide switches current with a single atom in solid electrolyte” | >

Researchers at Aalto University have shown that a nanoparticle suspension can serve as a simple model for studying the formation of patterns and structures in more complicated non-equilibrium systems, such as living cells. The new system will not only be a valuable tool for studying patterning processes but also has a wide range of potential technological applications.

The mixture consists of an oily liquid carrying of iron oxide, which become magnetized in a magnetic field. Under the right conditions, applying a voltage across this ferrofluid causes the nanoparticles to migrate, forming a concentration gradient in the mixture. For this to work, the ferrofluid has to also include docusate, a waxy chemical that can carry charge through the fluid.

The researchers discovered that the presence of docusate and a voltage across the ferrofluid resulted in a separation of electric charges, with the iron oxide nanoparticles becoming negatively charged. “We didn’t expect that at all,” says Carlo Rigoni, a postdoctoral researcher at Aalto. “We still don’t know why it happens. In fact, we don’t even know whether the charges already get split when the docusate is added or if it happens as soon as voltage is turned on.”

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Continue reading “This Boiling Liquid goes in your MONITOR — Facility Tour!” | >

Demonstrating that a material thought to be always chemically inert, hexagonal boron nitride (hBN), can be turned chemically active holds potential for a new class of catalysts with a wide range of applications, according to an international team of researchers.

HBN is a layered material and monolayers can be exfoliated like in graphene 0, another two-dimensional material. However, there is a key difference between the two.

“While hBN shares similar structure as graphene, the strong polar bonds between the boron and nitride atoms makes hBN unlike graphene in that it is chemically inert and thermally stable at high temperature,” said Yu Lei, postdoctoral scholar in physics at Penn State and first co-author in the study published in Materials Today.

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Drug-target interaction is a prominent research area in drug discovery, which refers to the recognition of interactions between chemical compounds and the protein targets. Chemists estimate that 1,060 compounds with drug-like properties could be made—that’s more than the total number of atoms in the Solar System, as an article reported in the journal Nature in 2017.

Drug development, on average, takes about 14 years and costs up to 1.5 billion dollars. During the journey of in this vast “galaxy,” it is apparent that traditional biological experiments for DTI detection are normally costly and time-consuming.

Prof. Hou Tingjun is an expert in computer-aided drug design (CADD) at the Zhejiang University College of Pharmaceutical Sciences. In the past decades, he has been committed to developing drugs using computer technology. “The biggest challenge lies in the interactions between unknown targets and drug molecules. How can we discover them more efficiently? This involves a new breakthrough in method.”

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A new study finds the magnetic field generated by a tsunami can be detected a few minutes earlier than changes in sea level and could improve warnings of these giant waves.

Tsunamis generate magnetic fields as they move conductive seawater through the Earth’s magnetic field. Researchers previously predicted that the tsunami’s magnetic field would arrive before a change in sea level, but they lacked simultaneous measurements of magnetics and sea level that are necessary to demonstrate the phenomenon.

The new study provides real-world evidence for using tsunamis’ magnetic fields to predict the height of tsunami waves using data from two real events—a 2009 tsunami in Samoa and a 2010 tsunami in Chile—that have both sets of necessary data. The new study was published in AGU’s Journal of Geophysical Research: Solid Earth, which focuses on the physics and chemistry of the solid Earth.

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Method combines quantum mechanics with machine learning to accurately predict oxide reactions at high temperatures when no experimental data is available; could be used to design clean carbon-neutral processes for steel production and metal recycling.

Extracting metals from oxides at high temperatures is essential not only for producing metals such as steel but also for recycling. Because current extraction processes are very carbon-intensive, emitting large quantities of greenhouse gases, researchers have been exploring new approaches to developing “greener” processes. This work has been especially challenging to do in the lab because it requires costly reactors. Building and running computer simulations would be an alternative, but currently there is no computational method that can accurately predict oxide reactions at high temperatures when no experimental data is available.

A Columbia Engineering team reports that they have developed a new computation technique that, through combining quantum mechanics and machine learning, can accurately predict the reduction temperature of metal oxides to their base metals. Their approach is computationally as efficient as conventional calculations at zero temperature and, in their tests, more accurate than computationally demanding simulations of temperature effects using quantum chemistry methods. The study, led by Alexander Urban, assistant professor of chemical engineering, was published on December 1, 2021 by Nature Communications.

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