For over 20 years, the Ihara research group at Ehime University has specialized in developing innovative methods for polymer synthesis using diazocarbonyl compounds as monomers.
They discovered that diazoacetate can be polymerized using a palladium (Pd)-based initiator to produce carbon–carbon (C–C) main-chain polymers, with each carbon atom in the backbone bonded to an alkoxycarbonyl (ester) group. Unlike traditional vinyl polymerization—where the polymer backbone is built from two-carbon units of vinyl monomers like ethylene and styrene—diazoacetate polymerization creates the C–C main chain from single-carbon units. This unique process, known as C1 polymerization, is a distinctive and significant feature of this synthesis method.
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