Perovskite solar cells are attracting attention as next-generation solar cells. These cells have high efficiency, are flexible, and can be printed, among other features. However, lead was initially used in their manufacture, and its toxicity has become an environmental issue.
Therefore, a method for replacing lead with tin, which has a low environmental impact, has been proposed. Nevertheless, tin is easily oxidized; consequently, the efficiency and durability of tin perovskite solar cells are lower than those of lead perovskite solar cells.
To improve the durability of tin perovskite by suppressing tin oxidation, a method that introduces large organic cations into tin perovskite crystals to form a two-dimensional layered structure called Ruddlesden-Popper (RP) tin-based perovskites has been proposed. However, the internal state of this structure and the mechanism by which it improves performance have not been fully elucidated.