A team led by Prof. Yan Lu, HZB, and Prof. Arne Thomas, Technical University of Berlin, has developed a material that enhances the capacity and stability of lithium-sulfur batteries. The material is based on polymers that form a framework with open pores (known as radical-cationic covalent organic frameworks or COFs). Catalytically accelerated reactions take place in these pores, firmly trapping polysulfides, which would shorten the battery life.
Some of the experimental analyses were conducted at the BAMline at BESSY II. The research is published in the Journal of the American Chemical Society.
Crystalline framework structures made of organic polymers are a particularly interesting class of materials. They are characterized by their high porosity, comparable to a sponge, but with pores measuring only a few micrometers at most. These materials can exhibit special functionalities, which make them interesting for certain applications in electrochemical energy storage devices.