Researchers at the Department of Energy’s Oak Ridge National Laboratory are breathing new life into the scientific understanding of neptunium, a unique, radioactive, metallic element—and a key precursor for production of the plutonium-238, or Pu-238, that fuels exploratory spacecraft.
The ORNL team’s research arrives during a period of increased national interest in the use of Pu-238 in radioisotope thermoelectric generators, or RTGs. Often used in space missions such as NASA’s Perseverance Rover for long-term power, RTGs convert heat from radioactive decay into electricity. Advancing RTG knowledge and application possibilities also requires the same high-level evaluation of both chemical reactions and structural characterization, two key aspects of the materials science for which ORNL is known.
“When people want to do scientific experiments in space, they need something to power their instruments, and plutonium is typically the power source because things like solar and lithium ion batteries don’t withstand deep space,” said Kathryn Lawson, radiochemist in ORNL’s Fuel Cycle Chemical Technology Group and lead author of the new study.









