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For the first time, lasers have successfully excited the “thorium transition,” a process long pursued by researchers. This breakthrough sets the stage for groundbreaking advancements in high-precision technologies, such as nuclear clocks.

Physicists have eagerly anticipated this breakthrough: scientists globally have spent years searching for a specific state of thorium atomic nuclei that could lead to groundbreaking technological advancements.

It could be used, for example, to build an nuclear clock that could measure time more precisely than the best atomic clocks available today. It could also be used to answer completely new fundamental questions in physics – for example, the question of whether the constants of nature are actually constant or whether they change in space and time.

Researchers use a laser to excite and precisely measure a long-sought exotic nuclear state, paving the way for precise timekeeping and ultrasensitive quantum sensing.

Any reliably produced, periodic phenomenon—from the swing of a pendulum to the vibrations of a single atom—can form the basis of a clock. Today’s most precise timekeeping is based on extremely narrow electronic transitions in atoms, which resonate at optical frequencies. These stupendously precise optical atomic clocks lose just 1 second (s) in about 30 billion years. However, they could potentially be outperformed by a nuclear clock, which would instead “tick” to the resonant frequency of a transition that occurs in the atomic nucleus instead of in the electronic shell. The most promising candidate for this nuclear standard is an exceptionally low-energy and long-lived excited state, or isomer, of the isotope thorium-229 (229 Th). Researchers have now achieved the long-sought goal of exciting this transition with ultraviolet light.

A research team at the University of Pittsburgh led by Alexander Star, a chemistry professor in the Kenneth P. Dietrich School of Arts and Sciences, has developed a fentanyl sensor that is six orders of magnitude more sensitive than any electrochemical sensor for the drug reported in the past five years. The portable sensor can also tell the difference between fentanyl and other opioids.

Precisely measuring the energy states of individual atoms has been a historical challenge for physicists due to atomic recoil. When an atom interacts with a photon, the atom “recoils” in the opposite direction, making it difficult to measure the position and momentum of the atom precisely. This recoil can have big implications for quantum sensing, which detects minute changes in parameters, for example, using changes in gravitational waves to determine the shape of the Earth or even detect dark matter.