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Magnetic Covalent Organic Frameworks (MCOFs): A Sustainable Solution for Emerging Organic Contaminants (EOCs) from the River

Phthalates (PAEs) and bisphenol A (BPA) are significant components in plastic and its derivative industries. They are omnipresent in water sources owing to intensive industrialization and rapid urbanization, hence posing adverse effects on humans and significant environmental issues. Researchers have developed a new magnetic material, called magnetic covalent organic frameworks (MCOFs), that can effectively remove harmful chemicals like PAEs and BPA from water. Made using a special method that prevents clumping, these materials are highly porous, magnetic and reusable up to 15 times. They showed excellent removal efficiency, even at very low pollutant levels found in real river water. The study also revealed that the removal process involves strong chemical bonding. This breakthrough offers a promising, eco-friendly solution for cleaning water contaminated by plastics and industrial waste.

Read the article in Royal Society Open Science.

Abstract. The synthesis and characterization of effective magnetic covalent organic frameworks (MCOFs) are presented for the highly efficient adsorption of dimethyl phthalate (DMP), dibutyl phthalate (DBP) and bisphenol A (BPA) from the aqueous environment. The novelty of this research lies in the development of MCOFs through a coprecipitation method that incorporates an innovative silica inner shell. This crucial feature not only prevents aggregation of the magnetic core, which is a significant limitation of conventional adsorbents, but also enables robust interactions between the core and the outer covalent organic framework (COF). The synthesized MCOFs were comprehensively characterised using a variety of techniques. Fourier-transform infrared spectroscopy (FTIR) and vibrating sample magnetometry (VSM) analyses confirmed successful synthesis and strong magnetic properties, while field-emission scanning electron microscopy (FESEM) revealed the presence of spherical, porous structures with small granules. Energy-dispursive X-ray (EDX) spectrometry analysis further confirmed the successful synthesis, showing a material composition of 58.2% Fe, 33.4% O, 4.8% C, and 3.2% Si. Brunauer–Emmett–Teller (BET) analysis showed the MCOFs possess a high surface area of 128.1 m2 g–1 and a pore diameter of 16.8 nm, indicating abundant active sites for adsorption. Under optimal conditions (pH 7,100 mg adsorbent dosage, and 25-minute contact time) the MCOFs exhibited exceptional adsorption performance, with removal efficiencies of 90.0% for DMP, 86.0% for DBP, and 92.0% for BPA. The kinetic study revealed that the adsorption mechanism follows the pseudo-second-order model, suggesting a significant chemisorption process. Crucially, in situ FTIR analysis provided spectroscopic validation that hydrogen bonding and π–π stacking are the predominant interactions between the MCOFs and the organic contaminants. The developed analytical method achieved low detection limits of 0.0058 mg l−1 for DMP, 0.0079 mg l−1 for DBP and 0.0063 mg l−1 for BPA, indicating high sensitivity for trace-level contaminant detection in real water samples. Furthermore, the adsorbent demonstrated exceptional reusability, maintaining high performance after 15 adsorption–desorption cycles, which is a significant improvement over conventional adsorbents. This study demonstrates that MCOFs with a silica inner shell are a highly promising, stable and sustainable solution for the removal of emerging organic contaminants (EOCs).

A forgotten battery design from Thomas Edison—how scientists helped reimagine it

A little-known fact: In the year 1900, electric cars outnumbered gas-powered ones on the American road. The lead-acid auto battery of the time, courtesy of Thomas Edison, was expensive and had a range of only about 30 miles. Seeking to improve on this, Edison believed the nickel-iron battery was the future, with the promise of a 100-mile range, a long life and a recharge time of seven hours, fast for that era.

Alas, that promise never reached fruition. Early electric car batteries still suffered from serious limitations, and advances in the internal combustion engine won the day.

Now, an international research collaboration co-led by UCLA has taken a page from Edison’s book, developing nickel-iron battery technology that may be well-suited for storing energy generated at solar farms. The prototype was able to recharge in only seconds, instead of hours, and achieved over 12,000 cycles of draining and recharging—the equivalent of more than 30 years of daily recharges.

When water meets rock: Exploring water quality impacts from legacy lithium mining in North Carolina

Starting just outside Charlotte, North Carolina, a vast underground deposit of lithium stretches south for 25 miles. A key component of rechargeable batteries and energy grid storage systems, the soft, silvery metal is a global commodity, making this subterranean cache a geopolitically important and potentially lucrative resource.

Here, lithium primarily occurs within granite-like rocks called pegmatite, bound to a green-tinged mineral called spodumene. Two large lithium mines once operated in this region—called the Carolina Tin-Spodumene Belt—but closed decades ago. As demand for renewable energy climbs, mining companies have growing interest in the area.

The presence of historic, or legacy, lithium mines and the prospect of new lithium mining activity have led nearby residents to wonder about the possibility of drinking water contamination. Over the past several years, a team led by Avner Vengosh, Distinguished Professor and Nicholas Chair of Environmental Quality at Duke University’s Nicholas School of the Environment, has been working to address those concerns.

Stable high-energy pulses achieved with low-stress electro-optic switch

A research team led by Prof. Zhang Tianshu from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences has developed a low-stress electro-optic switch based on large-aperture β-barium borate (BBO) slab crystals and integrated it into an Nd:YAG hybrid-cavity Innoslab laser system. Their study, published in Optics Express on January 13, addresses long-standing challenges in high-energy laser systems, particularly those related to switching modulation consistency and operational stability.

Hair-thin silica fiber microphone detects ultrasound from 40 kHz to 1.6 MHz

Researchers have fabricated a hair-thin microphone made entirely of silica fiber that can detect a large range of ultrasound frequencies beyond the reach of the human ear. Able to withstand temperatures up to 1,000°C, the device could eventually be used inside high-voltage transformers to detect early signs of failure before power outages occur.

“Conventional electronic sensors often fail under thermal stress or suffer from severe signal interference,” said Xiaobei Zhang, a member of the research team from Shanghai University. “Our all-fiber microphone can survive in hazardous environments and is completely immune to electromagnetic interference while remaining sensitive enough to hear the subtle early warning signals of equipment failure.”

In an article published in Optics Express, the researchers describe their new microphone, which is sensitive to frequencies from 40 kHz to 1.6 MHz. Unlike traditional microphones that rely on bulky housing, the new microphone is entirely integrated within a fiber just 125 microns in diameter.

Humidity-resistant hydrogen sensor can improve safety in large-scale clean energy

Wherever hydrogen is present, safety sensors are required to detect leaks and prevent the formation of flammable oxyhydrogen gas when hydrogen is mixed with air. It is therefore a challenge that today’s sensors do not work optimally in humid environments—because where there is hydrogen, there is very often humidity. Now, researchers at Chalmers University of Technology, Sweden, are presenting a new sensor that is well suited to humid environments—and actually performs better the more humid it gets.

“The performance of a hydrogen gas sensor can vary dramatically from environment to environment, and humidity is an important factor. An issue today is that many sensors become slower or perform less effectively in humid environments. When we tested our new sensor concept, we discovered that the more we increased the humidity, the stronger the response to hydrogen became. It took us a while to really understand how this could be possible,” says Chalmers doctoral student Athanasios Theodoridis, who is the lead author of the article published in the journal ACS Sensors.

Hydrogen is an increasingly important energy carrier in the transport sector and is used as a raw material in the chemical industry or for green steel manufacturing. In addition to water being constantly present in ambient air, it is also formed when hydrogen reacts with oxygen to generate energy, for example, in a fuel cell that can be used in hydrogen-powered vehicles and ships. Furthermore, fuel cells themselves require water to prevent the membranes that separate oxygen and hydrogen inside them from drying out.

Stabilized iron catalyst could replace platinum in hydrogen fuel cells

Japan and California have embraced hydrogen fuel-cell technologies, a form of renewable energy that can be used in vehicles and for supplying clean energy to manufacturing sectors. But the technology remains expensive due to its reliance on precious metals such as platinum. Engineers at Washington University in St. Louis are working on this challenge, finding ways to stabilize ubiquitous iron components for use in fuel cells to replace the expensive platinum metals, which would make hydrogen fuel-cell vehicles more affordable.

Cost challenges for fuel-cell vehicles

“The hydrogen fuel cell has been successfully commercialized in Japan and California in the U.S.,” said Gang Wu, a professor of energy, environmental and chemical engineering at the McKelvey School of Engineering. “But these vehicles struggle to compete with the battery vehicle and combustion engine vehicle, with cost being the main issue.”

Scientists Announce a Real Warp Drive Is Now Possible

Scientists say a real warp drive may no longer be pure science fiction, thanks to new breakthroughs in theoretical physics. Recent studies suggest space itself could be compressed and expanded, allowing faster-than-light travel without breaking known laws of physics. Unlike sci-fi engines, this concept wouldn’t move a ship through space — it would move space around the ship. Researchers are now exploring how energy, gravity, and exotic matter could make this possible. In this video, we explain how a warp drive could work and how close science really is.

Credit:
Star Wars: Episode VIII — The Last Jedi / Lucasfilm https://www.imdb.com/title/tt2527336/.… Trek Beyond / Paramount Pictures https://www.imdb.com/title/tt2660888/.… Lost in Space / New Line Cinema https://www.imdb.com/title/tt0120738/.… Parker Solar Probe touches the Sun: By NASA/Johns Hopkins APL/Ben Smith — https://svs.gsfc.nasa.gov/14036, https://commons.wikimedia.org/wiki/Fi… Parker Solar Probe: By NASA’s Scientific Visualization Studio — Johns Hopkins University/APL/Betsy Congdon, Johns Hopkins Applied Physics Laboratory/Yanping Guo, Johns Hopkins Applied Physics Laboratory/John Wirzburger, NASA/Nicola Fox, NASA/Kelly Korreck, Johns Hopkins University/APL/Nour Raouafi, NASA/Joseph Westlake, eMITS/Joy Ng, eMITS/Beth Anthony, eMITS/Lacey Young, ADNET Systems, Inc./Aaron E. Lepsch — https://svs.gsfc.nasa.gov/14741, https://commons.wikimedia.org/wiki/Fi… Parker Solar Probe: By NASA/Johns Hopkins APL/Steve Gribben — http://parkersolarprobe.jhuapl.edu/Mu…, https://commons.wikimedia.org/w/index… Vertical Testbed Rocket: By NASA Armstrong Flight Research Center — https://www.nasa.gov/armstrong/, https://commons.wikimedia.org/wiki/Fi… […]cket_(AFRC-2017–11349-1_Masten-COBALT-UnTetheredFLT1).webm Interstellar / Paramount Pictures Stargate / Canal+ CC BY-SA 3.0 https://creativecommons.org/licenses/.… Alcubierre: By AllenMcC., https://commons.wikimedia.org/w/index… Miguel alcubierre: By Jpablo.romero, https://commons.wikimedia.org/w/index… Water wave analogue of Casimir effect: By Denysbondar, https://commons.wikimedia.org/wiki/Fi… Casimir plates: By Emok, https://commons.wikimedia.org/w/index… CC BY-SA 4.0 https://creativecommons.org/licenses/.… Proxima Centauri b: By ESO/Konstantino Polizois/Nico Bartmann — http://www.eso.org/public/unitedkingd…, https://commons.wikimedia.org/wiki/Fi… WARP Reactor Concept Movie: By WarpingSpacetime, https://commons.wikimedia.org/wiki/Fi… Ag Micromirrors: By Simpik, https://commons.wikimedia.org/wiki/Fi… Animation is created by Bright Side.
Star Trek Beyond / Paramount Pictures https://www.imdb.com/title/tt2660888/.…
Lost in Space / New Line Cinema https://www.imdb.com/title/tt0120738/.…
Parker Solar Probe touches the Sun: By NASA/Johns Hopkins APL/Ben Smith — https://svs.gsfc.nasa.gov/14036, https://commons.wikimedia.org/wiki/Fi…
Parker Solar Probe: By NASA’s Scientific Visualization Studio — Johns Hopkins University/APL/Betsy Congdon, Johns Hopkins Applied Physics Laboratory/Yanping Guo, Johns Hopkins Applied Physics Laboratory/John Wirzburger, NASA/Nicola Fox, NASA/Kelly Korreck, Johns Hopkins University/APL/Nour Raouafi, NASA/Joseph Westlake, eMITS/Joy Ng, eMITS/Beth Anthony, eMITS/Lacey Young, ADNET Systems, Inc./Aaron E. Lepsch — https://svs.gsfc.nasa.gov/14741, https://commons.wikimedia.org/wiki/Fi…
Parker Solar Probe: By NASA/Johns Hopkins APL/Steve Gribben — http://parkersolarprobe.jhuapl.edu/Mu…, https://commons.wikimedia.org/w/index…
Vertical Testbed Rocket: By NASA Armstrong Flight Research Center — https://www.nasa.gov/armstrong/, https://commons.wikimedia.org/wiki/Fi… […]cket_(AFRC-2017–11349-1_Masten-COBALT-UnTetheredFLT1).webm.
Interstellar / Paramount Pictures.
Stargate / Canal+
CC BY-SA 3.0 https://creativecommons.org/licenses/.…
Alcubierre: By AllenMcC., https://commons.wikimedia.org/w/index…
Miguel alcubierre: By Jpablo.romero, https://commons.wikimedia.org/w/index…
Water wave analogue of Casimir effect: By Denysbondar, https://commons.wikimedia.org/wiki/Fi…
Casimir plates: By Emok, https://commons.wikimedia.org/w/index…
CC BY-SA 4.0 https://creativecommons.org/licenses/.…
Proxima Centauri b: By ESO/Konstantino Polizois/Nico Bartmann — http://www.eso.org/public/unitedkingd…, https://commons.wikimedia.org/wiki/Fi…
WARP Reactor Concept Movie: By WarpingSpacetime, https://commons.wikimedia.org/wiki/Fi…
Ag Micromirrors: By Simpik, https://commons.wikimedia.org/wiki/Fi…
Animation is created by Bright Side.

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