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May 6, 2024

A Single Atom Layer of Gold: Researchers Create Goldene

Posted by in categories: chemistry, particle physics

For the first time, scientists have managed to create sheets of gold only a single atom layer thick. The material has been termed goldene. According to researchers from Linköping University, Sweden, this has given the gold new properties that can make it suitable for use in applications such as carbon dioxide conversion, hydrogen production, and production of value-added chemicals. Their findings are published in the journal Nature Synthesis.

Scientists have long tried to make single-atom-thick sheets of gold but failed because the metal’s tendency to lump together. But researchers from Linköping University have now succeeded thanks to a hundred-year-old method used by Japanese smiths.

“If you make a material extremely thin, something extraordinary happens — as with graphene. The same thing happens with gold. As you know, gold is usually a metal, but if single-atom-layer thick, the gold can become a semiconductor instead,” says Shun Kashiwaya, researcher at the Materials Design Division at Linköping University.

May 6, 2024

At the Edge of Explosion: How New Science Is Making Old Reactions Safer

Posted by in categories: chemistry, science

The chemical industry has been using a reaction with explosive chemicals for over 100 years — now Mülheim scientists have discovered a safer alternative.

Explosions and poisoning. Serious injuries and even deaths. In the history of the chemical industry, there have been repeated accidents, sometimes fatal, often caused by dangerous and explosive chemicals that are required for certain reactions.

Aryldiazonium salts, which have been used for 140 years, are such chemicals. They are very reactive and therefore extremely useful for producing other compounds – dyes, for example. However, the high reactivity means that isolated aryldiazonium salts are not very stable and can therefore react unintentionally and sometimes explosively. On December 23, 1969, there was a particularly serious explosion involving these chemicals at Ciba AG in Basel. A building was destroyed and heavy pieces of the reactor flew through the air. Three workers lost their lives and 31 were seriously injured. Despite such horrific reports, work continues with aryldiazonium salts.

May 5, 2024

Researchers repurpose commonplace chemical with incredible properties in new battery design: ‘Exhibited remarkable cycling stability’

Posted by in category: chemistry

The research team plans to scale up production of the flow batteries.first appeared on The Cool Down.

May 5, 2024

Unleashing Disordered Rocksalt Oxides as Cathodes for Rechargeable Magnesium Batteries

Posted by in categories: chemistry, particle physics, sustainability

Researchers at Tohoku University have made a groundbreaking advancement in battery technology, developing a novel cathode material for rechargeable magnesium batteries (RMBs) that enables efficient charging and discharging even at low temperatures. This innovative material, leveraging an enhanced rock-salt structure, promises to usher in a new era of energy storage solutions that are more affordable, safer, and higher in capacity.

Details of the findings were published in the Journal of Materials Chemistry A on March 15, 2024.

The study showcases a considerable improvement in magnesium (Mg) diffusion within a rock-salt structure, a critical advancement since the denseness of atoms in this configuration had previously impeded Mg migration.

May 5, 2024

Genetically targeted chemical assembly of functional materials in living cells, tissues, and animals

Posted by in categories: chemistry, genetics, neuroscience

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Engineered enzymes employed in neurons enable synthesis of electroactive polymers for behavior remodeling in living animals.

May 5, 2024

Unlocking High Energy: New Aqueous Batteries Surpass Traditional Limits

Posted by in categories: chemistry, energy, physics

Traditional lithium-ion batteries, while offering high energy density, have compromised safety because they use flammable organic electrolytes.

Aqueous batteries use water as the solvent for electrolytes, significantly enhancing the safety of the batteries. However, due to the limited solubility of the electrolyte and low battery voltage, aqueous batteries typically have a lower energy density. This means that the amount of electricity stored per unit volume of aqueous battery is relatively low.

In a new study published in Nature Energy, a research group led by Prof. Li Xianfeng from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS), in collaboration with Prof. Fu Qiang’s group also from DICP, developed a multi-electron transfer cathode based on bromine and iodine, realizing a specific capacity of more than 840 Ah/L, and achieving an energy density of up to 1,200 Wh/L based on catholyte in full battery testing.

May 4, 2024

China touts ‘water battery’ with more energy capacity than lithium cells: study

Posted by in categories: chemistry, energy, physics

Their findings “may expand aqueous battery applications in the power battery field”, said corresponding author Li Xianfeng, a professor at the CAS Dalian Institute of Chemical Physics, who was quoted in a statement from the academy.

Lithium batteries are the standard used across the world because of their high energy density. Traditional lithium batteries contained a non-aqueous electrolyte – a component that allowed the battery to charge and discharge – which was flammable, the paper said.

Aqueous batteries are made up of a water-based electrolyte which does not present the same safety risks.

May 3, 2024

Chemist explores the real-world science of Star Wars

Posted by in categories: chemistry, science, space travel, weapons

A professor at the University of Warwick is exploring the chemistry of the galaxy far, far away this Star Wars Day, May the 4th.

Science fiction is meeting science fact, as Professor Alex Baker discusses the captivating inspiration real-world reactions have had on the Star Wars universe.

The chemist from the University of Warwick explores what may underpin the freezing of Han Solo, the colors of lightsabers, the reactions that power star ships and much more.

May 3, 2024

Bioelectronic interfaces of organic electrochemical transistors

Posted by in categories: biological, chemistry, computing

The organic electrochemical transistor stands out as a tool for constructing powerful biosensors owing to its high signal transduction ability and adaptability to various geometrical forms. However, the performance of organic electrochemical transistors relies on stable and seamless interfaces with biological systems. This Review examines strategies to improve and optimize interfaces between organic electrochemical transistors and various biological components.

May 3, 2024

Tweaking isotopes sheds light on promising approach to engineer semiconductors

Posted by in categories: chemistry, engineering, particle physics

Partly because of semiconductors, electronic devices and systems become more advanced and sophisticated every day. That’s why for decades researchers have studied ways to improve semiconductor compounds to influence how they carry electrical current. One approach is to use isotopes to change the physical, chemical and technological properties of materials.

Isotopes are members of a family of an element that all have the same number of protons but different numbers of neutrons and thus different masses. Isotope engineering has traditionally focused on enhancing so-called bulk materials that have uniform properties in three dimensions, or 3D.

But new research led by ORNL has advanced the frontier of isotope engineering where current is confined in two dimensions, or 2D, inside flat crystals and where a layer is only a few atoms thick. The 2D materials are promising because their ultrathin nature could allow for precise control over their .

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