{"id":195452,"date":"2024-08-30T14:24:25","date_gmt":"2024-08-30T19:24:25","guid":{"rendered":"https:\/\/lifeboat.com\/blog\/2024\/08\/electrochemical-meta-c-h-sulfonylation-of-pyridines-with-nucleophilic-sulfinates"},"modified":"2024-08-30T14:24:25","modified_gmt":"2024-08-30T19:24:25","slug":"electrochemical-meta-c-h-sulfonylation-of-pyridines-with-nucleophilic-sulfinates","status":"publish","type":"post","link":"https:\/\/lifeboat.com\/blog\/2024\/08\/electrochemical-meta-c-h-sulfonylation-of-pyridines-with-nucleophilic-sulfinates","title":{"rendered":"Electrochemical meta-C\u2013H sulfonylation of pyridines with nucleophilic sulfinates"},"content":{"rendered":"<p><a class=\"aligncenter blog-photo\" href=\"https:\/\/lifeboat.com\/blog.images\/electrochemical-meta-c-h-sulfonylation-of-pyridines-with-nucleophilic-sulfinates.jpg\"><\/a><\/p>\n<p>Direct meta-selective C\u2013H functionalization of pyridines is of paramount importance, but such reactions remain limited and highly challenging. Here, the authors report an electrochemical methodology in which nucleophilic sulfinates allow meta-sulfonylation of pyridines through a redox-neutral dearomatization-rearomatization strategy.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Direct meta-selective C\u2013H functionalization of pyridines is of paramount importance, but such reactions remain limited and highly challenging. Here, the authors report an electrochemical methodology in which nucleophilic sulfinates allow meta-sulfonylation of pyridines through a redox-neutral dearomatization-rearomatization strategy.<\/p>\n","protected":false},"author":661,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[19],"tags":[],"class_list":["post-195452","post","type-post","status-publish","format-standard","hentry","category-chemistry"],"_links":{"self":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts\/195452","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/users\/661"}],"replies":[{"embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/comments?post=195452"}],"version-history":[{"count":0,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts\/195452\/revisions"}],"wp:attachment":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/media?parent=195452"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/categories?post=195452"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/tags?post=195452"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}