{"id":123890,"date":"2021-06-16T17:23:28","date_gmt":"2021-06-17T00:23:28","guid":{"rendered":"https:\/\/lifeboat.com\/blog\/2021\/06\/bioinspired-roughness-induced-water-and-oil-super-philic-and-super-phobic-coatings-prepared"},"modified":"2021-06-16T17:23:28","modified_gmt":"2021-06-17T00:23:28","slug":"bioinspired-roughness-induced-water-and-oil-super-philic-and-super-phobic-coatings-prepared","status":"publish","type":"post","link":"https:\/\/lifeboat.com\/blog\/2021\/06\/bioinspired-roughness-induced-water-and-oil-super-philic-and-super-phobic-coatings-prepared","title":{"rendered":"Bioinspired, roughness-induced, water and oil super-philic and super-phobic coatings prepared"},"content":{"rendered":"<p><a class=\"aligncenter blog-photo\" href=\"https:\/\/lifeboat.com\/blog.images\/bioinspired-roughness-induced-water-and-oil-super-philic-and-super-phobic-coatings-prepared2.jpg\"><\/a><\/p>\n<p>Circa 2015<\/p>\n<hr>\n<p>Coatings that attract water (hydrophilic) are useful for anti-fogging applications<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 6\" title=\"Grosu, G., Andrzejewski, L., Veilleux, G. & Ross, G. G. Relation between the size of fog droplets and their contact angles with CR39 surfaces. J. Phys. D 37, 3350&ndash;3355 (2004).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR6\" id=\"ref-link-section-d55275e1157\">6<\/a><\/sup>; any liquid water spreads out into a thin film thereby maintaining transparency. This is more favorable than using hydrophobic surfaces for anti-fogging as this requires a surface to be tilted for the droplets to roll off and transparency be maintained. Hydrophilic surfaces can also be used for self-cleaning<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 7\" title=\"Nishimoto, S. & Bhushan, B. Bioinspired Self-cleaning Surfaces with Superhydrophobicity, Superoleophobicity and Superhydrophilicity. RSC Advances 3671&ndash;690 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR7\" id=\"ref-link-section-d55275e1161\">7<\/a><\/sup>. Previous examples of superhydrophilic surfaces include the use of polymer\u2013nanoparticle coatings<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 8\" title=\"Cebeci, F. \u00c7., Zhizhong, W., Zhai, L., Cohen, R. E., & Rubner, M. F. Nanoporosity-Driven Superhydrophilicity: A Means to Create Multifunctional Antifogging Coatings. Langmuir 22, 2856&ndash;2862 (2006).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR8\" id=\"ref-link-section-d55275e1165\">8<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 9\" title=\"Liu, X. & He, J. Superhydrophilic and Antireflective Properties of Silica Nanoparticle Coatings Fabricated via Layer-by-Layer Assembly and Postcalcination. J. Phys. Chem. C 113148&ndash;152 (2009).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR9\" id=\"ref-link-section-d55275e1168\">9<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 10\" title=\"Park, J. T., Seo, J. A., Ahn, S. H., Kim, J. H. & Kang, S. W. Surface modification of silica nanoparticles with hydrophilic polymers. J. Ind. Chem. Eng. 16517&ndash;522 (2010).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR10\" id=\"ref-link-section-d55275e1171\">10<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 11\" title=\"Lee, K. K. & Ahn, C. H. Superhydrophilic Multilayer Silica Nanoparticle Networks on a Polymer Microchannel Using a Spray Layer-by-Layer Nanoassembly Method. ACS Applied Mater. Interfaces 5, 8523&ndash;8530 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR11\" id=\"ref-link-section-d55275e1174\">11<\/a><\/sup> however mechanical durability was not investigated.<\/p>\n<p>Coatings with surface tensions lower than that of water (72 mN m<sup>\u20131<\/sup>) but higher than that of oils<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 12\" title=\"Haynes, W. M. Handbook of Chemistry and Physics, 95th ed., CRC Press, Boca Raton, FL (2014).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR12\" id=\"ref-link-section-d55275e1184\">12<\/a><\/sup> (20\u201330 mN m<sup>\u20131<\/sup>) will attract oils (oleophilic) but repel water and can be used to create oil\u2013water separators<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 13\" title=\"Feng, L. et al. A Super-Hydrophobic and Super-Oleophilic Coating Mesh Film for the Separation of Oil and Water. Angew. Chem., Int. Ed. 43, 2012&ndash;2014 (2004).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR13\" id=\"ref-link-section-d55275e1190\">13<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 14\" title=\"Wang, S., Li, M. & Lu, Q. Filter Paper with Selective Absorption and Separation of Liquids That Differ in Surface Tension. ACS Appl. Mater. Interfaces 2677&ndash;683 (2010).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR14\" id=\"ref-link-section-d55275e1193\">14<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 15\" title=\"Lee, C. H., Johnson, N., Drelich, J. & Yap, Y. K. The performance of superhydrophobic and superoleophilic carbon nanotube meshes in water\u2212oil filtration. Carbon 49669&ndash;676 (2011).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR15\" id=\"ref-link-section-d55275e1196\">15<\/a><\/sup>. When applied to a porous substrate, the coating will allow the passage of oil but block the passage of water, resulting in their separation. In addition, their water repellency also makes them ideal for self-cleaning<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 4\" title=\"Bhushan, B. Biomimetics: Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology. Springer-Verlag, Heidelberg, Germany (2012).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR4\" id=\"ref-link-section-d55275e1200\">4<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 16\" title=\"Bixler, G. D. & Bhushan, B. Rice-and Butterfly-Wing Effect Inspired Low Drag and Antifouling Surfaces: A Review. Crit. Rev. Solid State Mat. Sci. 40, 1&ndash;37 (2015).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR16\" id=\"ref-link-section-d55275e1203\">16<\/a><\/sup> and anti-icing<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 17\" title=\"Cao, L., Jones, A. K., Sikka, V. K., Wu, J. & Gao, D. Anti-Icing Superhydrophobic Coatings. Langmuir 25, 12444&ndash;12448 (2009).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR17\" id=\"ref-link-section-d55275e1208\">17<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 18\" title=\"Kulinich, S. A. & Farzaneh, M. Ice adhesion on super-hydrophobic surfaces. Appl. Surf. Sci. 255, 8153&ndash;8157 (2009).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR18\" id=\"ref-link-section-d55275e1211\">18<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 19\" title=\"Yang, S. et al. Research on the icephobic properties of fluoropolymer-based materials. Appl. Surf. Sci. 257, 4956&ndash;4962 (2011).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR19\" id=\"ref-link-section-d55275e1214\">19<\/a><\/sup> applications. Anti-icing surfaces are typically superhydrophobic as supercooled droplets of water are able to roll off the cold surface before freezing and any ice formed is weakly adhered compared to hydrophilic surfaces due to an air cushion<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 18\" title=\"Kulinich, S. A. & Farzaneh, M. Ice adhesion on super-hydrophobic surfaces. Appl. Surf. Sci. 255, 8153&ndash;8157 (2009).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR18\" id=\"ref-link-section-d55275e1218\">18<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 20\" title=\"Wang, Y., Xue, J., Wang, Q., Chen, Q. & Ding, J. Verification of Icephobic\/Anti-icing Properties of a Superhydrophobic Surface. ACS Appl. Mater. Interfaces 5, 3370&ndash;3381 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR20\" id=\"ref-link-section-d55275e1221\">20<\/a><\/sup>.<\/p>\n<p>Coatings with lower surface tensions (\u223c 20 mN m<sup>\u20131<\/sup> or less) will repel both oil (oleophobic) and water and are useful for anti-fouling such as in medical and transport applications, where both the oil-repellency and nanostructuring are of importance<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 21\" title=\"Hsieh, C.-T., Chen, J.-M., Kuo, R.-R., Lin, T.-S. & Wu, C.-F. Influence of surface roughness on water-and oil-repellent surfaces coated with nanoparticles. Appl. Surf. Sci. 240318&ndash;326 (2005).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR21\" id=\"ref-link-section-d55275e1230\">21<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 22\" title=\"Tuteja, A. et al. Designing Superoleophobic Surfaces. Science 318, 1618&ndash;1622 (2007).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR22\" id=\"ref-link-section-d55275e1233\">22<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 23\" title=\"Jung, Y. C. & Bhushan, B. Wetting behavior of water and oil droplets in three-phase interfaces for hydrophobicity\/philicity and oleophobicity\/philicity. Langmuir 25, 14165&ndash;14173 (2009).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR23\" id=\"ref-link-section-d55275e1236\">23<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 24\" title=\"Darmanin, T. et al. Superoleophobic behavior of fluorinated conductive polymer films combining electropolymerization and lithography. Soft Matter 7, 1053&ndash;1057 (2011).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR24\" id=\"ref-link-section-d55275e1239\">24<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 25\" title=\"He, Z. et al. Fabrication of a transparent superamphiphobic coating with improved stability. Soft Matter 7, 6435&ndash;6443 (2011).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR25\" id=\"ref-link-section-d55275e1242\">25<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 26\" title=\"Pan, S., Kota, A. K., Mabry, J. M. & Tuteja, A. Superomniphobic Surfaces for Effective Chemical Shielding. J. Am. Chem. Soc. 135578&ndash;581 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR26\" id=\"ref-link-section-d55275e1245\">26<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 27\" title=\"Bixler, G. D., Theiss, A., Bhushan, B. & Lee, S. C. Anti-fouling properties of microstructured surfaces bio-inspired by rice leaves and butterfly wings. J. Colloid Interf. Sci. 419114&ndash;133 (2014).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR27\" id=\"ref-link-section-d55275e1249\">27<\/a><\/sup>. Previous work was not suitable for such applications as either the durability<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 28\" title=\"Yang, J., Zhang, Z., Men, X., Xu, X. & Zhu, X. A simple approach to fabricate superoleophobic coatings. New J. Chem. 35576&ndash;580 (2011).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR28\" id=\"ref-link-section-d55275e1253\">28<\/a><\/sup> or oil-repellency<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 29\" title=\"Jin, H., Tian, X., Ikkala, O. & Ras, R. H. A. Preservation of superhydrophobic and superoleophobic properties upon wear damage. ACS Appl. Mater. Interfaces 5485&ndash;488 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR29\" id=\"ref-link-section-d55275e1257\">29<\/a><\/sup> was not optimal. The oil repellency also makes these surfaces ideal for anti-smudge applications<sup><a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 30\" title=\"Bhushan, B. & Muthiah, P. Anti-smudge screening apparatus for electronic touch screens. Microsyst. Technol. 19, 1261&ndash;1263 (2013).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR30\" id=\"ref-link-section-d55275e1261\">30<\/a>,<a data-track=\"click\" data-track-action=\"reference anchor\" data-track-label=\"link\" data-test=\"citation-ref\" aria-label=\"Reference 31\" title=\"Wang, Y. & Bhushan, B. Wear-Resistant and Antismudge Superoleophobic Coating on Polyethylene Terephthalate Substrate Using SiO2 Nanoparticles. ACS Appl. Mater. Interfaces 7743&ndash;755 (2015).\" href=\"https:\/\/www.nature.com\/articles\/srep14030#ref-CR31\" id=\"ref-link-section-d55275e1264\">31<\/a><\/sup> where the oils from fingers are not deposited onto the surface and the surface remains clear. The water repellency means these coatings can also be used in self-cleaning and anti-icing applications.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Circa 2015 Coatings that attract water (hydrophilic) are useful for anti-fogging applications6; any liquid water spreads out into a thin film thereby maintaining transparency. This is more favorable than using hydrophobic surfaces for anti-fogging as this requires a surface to be tilted for the droplets to roll off and transparency be maintained. Hydrophilic surfaces can [\u2026]<\/p>\n","protected":false},"author":513,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[11,4],"tags":[],"class_list":["post-123890","post","type-post","status-publish","format-standard","hentry","category-biotech-medical","category-nanotechnology"],"_links":{"self":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts\/123890","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/users\/513"}],"replies":[{"embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/comments?post=123890"}],"version-history":[{"count":0,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/posts\/123890\/revisions"}],"wp:attachment":[{"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/media?parent=123890"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/categories?post=123890"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lifeboat.com\/blog\/wp-json\/wp\/v2\/tags?post=123890"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}